Panpan Cao^1,2, Xiulin Huang^1,3,*, Shenxu Bao⁴, Jin Yang^5,*

FDMP-Fluid Dynamics & Materials Processing, Vol.19, No.8, pp. 2041-2051, 2023, DOI:10.32604/fdmp.2023.027399

Abstract Using ethylene glycol monovinyl polyoxyethylene ether, 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and acrylic acid as the main synthetic monomers, a high robustness polycarboxylate superplasticizer was prepared. The effects of initial temperature, ratio of acid to ether, amount of chain transfer agent, and synthesis process on the properties of the superplasticizer were studied. The molecular structure was characterized by GPC (Gel Permeation Chromatography) and IR (Infrared Spectrometer). As shown by the results, when the initial reaction temperature is 15°C, the ratio of acid to ether is 3.4:1 and the acrylic acid pre-neutralization is 15%, The AMPS substitution is 10%, the amount of… More > Graphic Abstract

Dalong Liao, Dongxu Li^*, Shun Zhou, Xiaotao Zhang, Ying Fang^*

Journal of Renewable Materials, Vol.11, No.2, pp. 625-641, 2023, DOI:10.32604/jrm.2022.022501

Abstract Graphene oxide (GO) as a new nano-enhancer in cement-based materials has gained wide attention. However, GO is easy to aggregate in alkaline cement mortar with poor dispersibility. This hinders its application in practical infrastructure construction. In this work, GO-M18 polycarboxylate compound superplasticizer (GM) were obtained by compounding the M18 polycarboxylate superplasticizer with GO solution at different mass ratios. The dispersion of GM in alkaline solution was systematically studied. The phases and functional groups of GM were characterized by XRD and FTIR. The effects of GM on the cement mortar hydration and the formation of microstructure were investigated by measuring the… More > Graphic Abstract