Dan Wang, Jihuan Song, Qiyuan Wang, Chenmeng Cui, Ying Yang^*

Journal of Renewable Materials, Vol.13, No.1, pp. 49-78, 2025, DOI:10.32604/jrm.2024.056644 - 20 January 2025

Abstract Upgrading of abundant cellulosic biomass to isosorbide can reduce the dependence on limited fossil resources and provide a sustainable way to produce isosorbide, utilized for polymers, medicine and health care product synthesis. This review comprehensively examines the key steps and catalytic systems involved in the conversion of cellulose to isosorbide. Initially, the reaction pathway from cellulose to isosorbide is elucidated, emphasizing three critical steps: cellulose hydrolysis, glucose hydrogenation, and the two-step dehydration of sorbitol to produce isosorbide. Additionally, the activation energy and acidic sites during cellulose hydrolysis, the impact of metal particle size and catalyst More > Graphic Abstract

Junjie Chen^* , Baofang Liu, Longfei Yan, Deguang Xu

Frontiers in Heat and Mass Transfer, Vol.11, pp. 1-15, 2018, DOI:10.5098/hmt.11.2

Abstract The combustion and emissions characteristics of methane-air mixtures in high-temperature catalytic micro-combustors were studied numerically. Both the heterogeneous and homogeneous chemistry were modeled simultaneously using detailed reaction mechanisms in order to better understand the role of each pathway in determining the product distributions. Computational fluid dynamics simulations were performed at a variety of pressures, temperatures, compositions, and combustor dimensions to determine their effects on the combustion and emissions characteristics. Comparisons were made between the results obtained for a purely heterogeneous case, a purely homogeneous case, and a coupled homogeneousheterogeneous case. It was shown that homogeneous More >