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  • Open Access

    ARTICLE

    Functionalized 2-(hydroxyethyl) methacrylate (HEMA)- co-acrylamide (AAm) hydrogels: Kinetic and Isotherm Modelling Analysis on the Removal of Cu(II) Ions

    AYÇA BAL ÖZTÜRK1,2,*, ZEHRA ÖZBAŞ3, BENGİ ÖZKAHRAMAN4, SERKAN EMİK5

    Journal of Polymer Materials, Vol.36, No.2, pp. 161-173, 2019, DOI:10.32381/JPM.2019.36.02.5

    Abstract A functionalized hydrogel composed of 2-(hydroxyethyl) methacrylate (HEMA) and acrylamide (AAm) was synthesized by amination and saponification reactions, respectively, and its functionality was examined for the elimination of copper(II) ions. The maximum adsorption capacity for copper(II) ions was 0.617 mmol g-1 before saponification, whereas it was 1.2225 mmol g-1 after saponification. The adsorption data was analyzed with pseudo-first-order (r2 =0.8867), intra-particle diffusion (r2 =0.9453), Elovich (r2=0.9489) and pseudo-secondorder(r2 =0.9999) kinetic models. Based on the adsorption equilibrium experimental data Freundlich(r2 =0.9964), Langmuir(r2=0.998) and Dubinin–Radushkevich (D-R) (r2 =0.9960) adsorption isotherms provided good fits for all of experimental results. Finally, the datas of… More >

  • Open Access

    ARTICLE

    The Influence of Two Natural Reinforcement Fibers on the Hygrothermal Properties of Earthen Plasters in Mogao Grottoes of China

    Wenbei Bi1, Zengfeng Yan1,*, Huan Zhao1, Lixin Sun2, Xudong Wang3,4, Zhengmo Zhang3

    Journal of Renewable Materials, Vol.8, No.12, pp. 1691-1710, 2020, DOI:10.32604/jrm.2020.012808

    Abstract Murals in Mogao Grottoes consist of three parts: support layer, earthen plasters and paint layer. The earthen plasters play a key role in the preservation of murals. It is a mixture of Dengban soil, sand, and plant fiber. Two different natural fibers, hemp fiber and cotton fiber, were reinforced to earthen plasters in the same percentage to evaluate the influence on hygrothermal performance. The two types of earthen plasters were studied: one containing hemp fiber in the fine plaster (HFP) and the other containing cotton fiber in the fine plaster (CFP). Specific heat capacity, dry thermal conductivity, water vapor permeability,… More >

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