Henghui Deng1,2, Jingyi Lu1,2, Dunsheng Liang1,2, Xiaomin Wang1,2, Tongyao Wang1,2, Weihao Zhang1,2, Jing Wang3,*, Chaoqun Zhang1,2,*
Journal of Renewable Materials, Vol.11, No.3, pp. 1209-1222, 2023, DOI:10.32604/jrm.2022.023371
Abstract In this study, acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization. The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly (acrylic acid) (WPU-PAA) dispersion and the films were systematically investigated. The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid, leading to enhancement of the… More >
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