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ARTICLE
Copolymerization of 5-[4-(methacryloylamino)phenyl]- l0,15, 20-triphenylporphyrin with Styrene: Investigation of Spectroscopic, Structural and Thermal Properties
FEHMI SALTAN1,2, AYLIN PALAMUTLU2, HAKAN AKAT2,*
1
ÇankIrI Karatekin University, Faculty of Science, Department of Chemistry,
18100, ÇankIrI , Turkey
2
Ege University, Faculty of Science, Department of Chemistry, 35100, Izmir, Turkey
* Corresponding Author: e-mail:
Journal of Polymer Materials 2019, 36(2), 133-147. https://doi.org/10.32381/JPM.2019.36.02.3
Abstract
In this work, tetraphenylporphyrin (TPP) compound was first synthesized by the condensation
reaction of pyrrole and benzaldehyde using Adler method. Then, the synthesized
tetraphenylporphyrin was nitrated with sodium nitrite. Nitro-functionalized porphyrin (TPP-NO
2
)
compound was reduced to amine-functional using ammonia and this amine- functionalized
porphyrin was reacted with methacryloyl chloride to obtain porphyrin-derived radical monomer
(TPP-MAO). Copolymer was synthesized with obtained porphyrin functional monomer and styrene
by free radical polymerization method. Structural characterization and spectroscopic studies of
the synthesized compounds were carried out by FTIR, H
1
-NMR, UV spectroscopy. The molecular
weight and thermal properties of the copolymer were determined using gel permeation
chromatography (GPC) and thermogravimetry (TG). Tetraphenyl porphyrin containing polymer
shows good photoluminescence property.
Keywords
Cite This Article
APA Style
SALTAN, F., PALAMUTLU, A., AKAT, H. (2019). Copolymerization of 5-[4-(methacryloylamino)phenyl]- l0,15, 20-triphenylporphyrin with styrene: investigation of spectroscopic, structural and thermal properties. Journal of Polymer Materials, 36(2), 133-147. https://doi.org/10.32381/JPM.2019.36.02.3
Vancouver Style
SALTAN F, PALAMUTLU A, AKAT H. Copolymerization of 5-[4-(methacryloylamino)phenyl]- l0,15, 20-triphenylporphyrin with styrene: investigation of spectroscopic, structural and thermal properties. J Polym Materials . 2019;36(2):133-147 https://doi.org/10.32381/JPM.2019.36.02.3
IEEE Style
F. SALTAN, A. PALAMUTLU, and H. AKAT "Copolymerization of 5-[4-(methacryloylamino)phenyl]- l0,15, 20-triphenylporphyrin with Styrene: Investigation of Spectroscopic, Structural and Thermal Properties," J. Polym. Materials , vol. 36, no. 2, pp. 133-147. 2019. https://doi.org/10.32381/JPM.2019.36.02.3