Open Access

ARTICLE

Nitrogen-Doped Amorphous Carbon Homojunction from Palmyra Sugar as a Renewable Solar Cell

Budhi Priyanto^1,2,*, Imam Khambali^1,2, Irma Septi Ardiani², Khoirotun Nadhiyah², Anna Zakiyatul Laila², M. Chasrun Hasani¹, Bima Romadhon³, Retno Asih², Yoyok Cahyono², Triwikantoro², Darminto^2,*

1 Department of Electronic Engineering, Faculty of Engineering, Universitas Muhammadiyah Malang, Kota Malang, Indonesia
2 Advanced Materials Research Group, Department of Physics, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia
3 Department of Electronic Engineering, Faculty of Industrials Engineering, Institut Teknologi National Malang, Kota Malang, Indonesia

* Corresponding Authors: Budhi Priyanto. Email: ; Darminto. Email:

Journal of Renewable Materials 2024, 12(1), 57-69. https://doi.org/10.32604/jrm.2023.028619

Received 29 December 2022; Accepted 09 June 2023; Issue published 23 January 2024

Abstract

An a-C/a-C:N junction, which used palmyra sugar as the carbon source and ammonium hydroxide (NH₄OH) as the dopant source, was successfully deposited on the ITO glass substrate using the nano-spraying method. The current-voltage relationship of the junction was found to be a Schottky-like contact, and therefore the junction shows the characteristic rectifiers. This means the a-C and a-C:N are semiconductors with different types of conduction. Moreover, the samples showed an increase in current and voltage value when exposed to visible light (bright state) compared to the dark condition, thereby, indicating the creation of electron-hole pairs during the exposure. It was also discovered that the relationship between current and voltage for the a-C/a-C:N junction sample formed a curve that satisfies the rule of the photovoltaic effect when exposed to visible light from a light bulb. The exposure of this sample to direct sunlight at AM 1.5 conditions produced a curve that meets the rules for the emergence of the photovoltaic effect with higher characteristics for the current-voltage relationship. Thus, the a-C/a-C:N junction sample is a solar cell successfully fabricated using a sample method and has a maximum efficiency of 0.0013%.

---

Graphical Abstract

---

Keywords

---