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New Biobased Polyurethane Materials from Modified Vegetable Oil

Chakib Mokhtari1, Fouad Malek1, Sami Halila2, Mohamed Naceur Belgacem3,*, Ramzi Khiari3,4,5,*
1 Laboratoire de Chimie Appliquée et Environnement–ECOMP—Faculté des Sciences, Université Mohamed Premier, Oujda, 60 000, Maroc
2 University of Grenoble Alpes, CNRS, CERMAV, Grenoble, Cedex 9, France
3 University of Grenoble Alpes, CNRS, Grenoble INP, Grenoble, F-38000, France
4 University of Monastir, Faculty of Sciences of Monastir, Research Unit of Applied Chemistry and Environment, Monastir, 5019, Tunisia
5 Higher Institute of Technological Studies (ISET) of Ksar-Hellal, Ksar-Hellal, 5070, Tunisia
* Corresponding Authors: Mohamed Naceur Belgacem. Email: ; Ramzi Khiari. Email:

Journal of Renewable Materials 2021, 9(7), 1213-1223. https://doi.org/10.32604/jrm.2021.015475

Received 21 December 2020; Accepted 19 January 2021; Issue published 18 March 2021

Abstract

Bio-based polyurethanes (PUs) have been occurred a large attention nowadays. It was found to be an alternative to the petrochemical based materials to the fact of their weak environmental influence, availability, good price and biodegradability. In addition, the nature shows several bio-derived compounds as raw materials for the synthesis of polyols, including the vegetable oils, polyphenol, terpene, and other bio-renewable sources. With the aim to develop a new family of biobased polyurethanes (PUs) via vegetable oils, the elaboration of new Jojoba-based PUs was performed by catalyst-free polycondensation reaction of a synthesized Jojoba diol with various diisocyanates such us toluene diisocyanate (TDI) and isophorone diisocyanate (IPDI). All the compounds were characterized by FTIR and NMR spectroscopies, and their properties were determined by gel permeation chromatography, differential scanning calorimetry and thermogravimetric analysis. The obtained results show renewable vegetable oils-based PUs materials can be preparing using a new environmentally ways and giving various good properties performances.

Graphical Abstract

New Biobased Polyurethane Materials from Modified Vegetable Oil

Keywords

Biopolymers; Jojoba oil; polyurethane; polyol; thiol-ene

Cite This Article

Mokhtari, C., Malek, F., Halila, S., Belgacem, M. N., Khiari, R. (2021). New Biobased Polyurethane Materials from Modified Vegetable Oil. Journal of Renewable Materials, 9(7), 1213–1223.

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This work is licensed under a Creative Commons Attribution 4.0 International License , which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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