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  • Open Access

    ARTICLE

    Matrix Assisted Laser Desorption Ionization Time of Flight (MALDI-TOF)-Mass Spectrometry and 13C-NMR-Identified New Compounds in Paraberlinia bifoliolata (Ekop-Beli) Bark Tannins

    Liliane Nga1, Benoit Ndiwe1,2, Achille Bernard Biwolé1, Antonio Pizzi3,*, Jean Jalin Eyinga Biwole1, Joseph Zobo Mfomo1

    Journal of Renewable Materials, Vol.12, No.3, pp. 553-568, 2024, DOI:10.32604/jrm.2023.046568

    Abstract Extracts of plant origin, particularly tannins, are attracting growing interest for the sustainable development of materials in the industrial sector. The discovery of new tannins is therefore necessary. The aim of this work was to contribute to the understanding of the properties of Paraberlinia bifoliolata tannin by Matrix Assisted Laser Desorption Ionization Time of Flight Mass Spectroscopy MALDI-TOF/MS and Carbon 13 Nuclear Magnetic Resonance (13C NMR). The chemical composition of tannin extracted from Paraberlinia bifoliolata bark was determined, as was the mechanical strength of the resin hardened with Acacia nilotica extracts. Yield by successive water extraction was 35%. MALDI-TOF/MS analysis… More >

  • Open Access

    ARTICLE

    Self-Cross-Linked Tannin-Aminated Tannin Surface Coatings for Particleboard

    Bengang Zhang1,*, Antonio Pizzi2,*, Mathieu Petrissans1, Anelie Petrissans1, Colin Baptiste1

    Journal of Renewable Materials, Vol.11, No.12, pp. 4097-4121, 2023, DOI:10.32604/jrm.2023.029761

    Abstract Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many, if not all of the tannin hydroxyl groups with –NH2 groups. A tannin-aminated tannin (ATT) particleboard coating was then prepared by reacting raw tannin extract with aminated tannin extract and thus cross-liking the two by substituting tannin’s hydroxyl groups with the –NH2 groups on the aminated tannin to form –NH-bridges between the two. The resulting particleboard coating gave encouraging results when pressed at 180°C for 3 min. Conversely, the system in which tannin was reacted/cross-liked with urea (ATU) by a similar amination reaction… More >

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