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  • Open Access

    ARTICLE

    Characterization and Selection of Microcrystalline Cellulose from Oil Palm Empty Fruit Bunches for Strengthening Hydrogel Films

    Susi Susi1,2,*, Makhmudun Ainuri3,*, Wagiman Wagiman3, Mohammad Affan Fajar Falah3

    Journal of Renewable Materials, Vol.12, No.3, pp. 513-537, 2024, DOI:10.32604/jrm.2024.045586

    Abstract Microcrystalline cellulose (MCC) is one of the cellulose derivatives produced as a result of the depolymerization of a part of cellulose to achieve high crystallinity. When implemented in other polymers, high crystallinity correlates with greater strength and stiffnes, but it can reduce the water-holding capacity. The acid concentration and hydrolysis time will affect the acquisition of crystallinity and water absorption capacity, both of which have significance as properties of hydrogel filler. The study aimed to evaluate the properties and select the MCC generated from varying the proportion of hydrochloric acid (HCl) and the appropriate hydrolysis time as a filler for… More > Graphic Abstract

    Characterization and Selection of Microcrystalline Cellulose from Oil Palm Empty Fruit Bunches for Strengthening Hydrogel Films

  • Open Access

    ARTICLE

    Structural, Thermal, Optical, Mechanical and Morphological Properties of ABS/RGO with DBDPE Nanocomposites

    İBRAHIM KARTERIa,b,*, MUSTAFA ÖZYEŞILDAĞb

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 167-177, 2021, DOI:10.32381/JPM.2021.38.1-2.13

    Abstract This study aims to provide a comprehensive account of chemically reduced graphene oxide (RGO) and decabromodiphenyl ethane (DBDPE) filled acrylonitrile-butadiene-styrene (ABS) multifunctional filaments for fused deposition modeling (FDM) applications. ABS/RGO with DBDPE nanocomposites (ABS-GDM) were fabricated by single-screw extrusion at a diameter of 1.75 mm. The proportion of RGO and DBDPE for the ABS-GDM filaments was set to 0.75 wt%. The properties of the ABS-GDM were determined using optical, mechanical, thermal, and morphological characteristics (using scanning electron microscopy). A three-dimensional (3D) model was successfully printed using the developed ABS-GDM filaments for FDM 3D printing. These ABS-GDM have the potential to… More >

  • Open Access

    ARTICLE

    Glass/Biofibers/Epoxy Methacrylate of Bisphenol-C Sandwich Composites: Comparative Mechanical and Electrical Properties and Chemical Resistance

    RITESH D. BHATT, JIGNESH P. PATEL, P. H. PARSANIA*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 71-87, 2021, DOI:10.32381/JPM.2021.38.1-2.7

    Abstract Glass/Biofibers/Epoxy methacrylate of bisphenol-C (G/BF/EBCMAS) sandwich composites was prepared by compression molding. G/BF/EBCMAS showed good mechanical and good to excellent electrical properties and excellent chemical resistance. Studied properties are compared with EBCMAS and G/EBCMAS. In comparison with G/EBCMAS, G/BF/EBCMAS showed considerable decline of tensile strength (18-63.4%), flexural strength (18.8-38.7%), flexural modulus (12.8-50.7%), Izod impact strength (17.4-43.5%), Barcol hardness (2.1-16.7%) and dielectric strength (23.8-76.8%) except flexural strength of G/BM/EBCMAS. G/WC/EBCMAS (96.7%), G/B/EBCMAS (79.2%), G/GN/EBCMAS (83.3%) and G/RH/EBCMAS (97.9%) showed decline of volume resistivity, whereas other sandwich composites showed 1150-58233% improvement. The decrease in mechanical properties and dielectric strength of G/BF/EBCMAS sandwich… More >

  • Open Access

    ARTICLE

    Studies on Compressive Loading-characteristics of PU Foam Materials Used in Footwear for Obese

    S. MATHIVANAN*, R. MOHAN, RAMES C PANDA, P. BALACHANDER1

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 195-204, 2022, DOI:10.32381/JPM.2022.39.3-4.2

    Abstract Optimum-designed footwear with polyurethane (PU) material for comfort is an important requirement for obese. Investigations on compressive behavior of varied designed footwear using 120 D PU material have been carried out. The energy absorption primarily depends on heel height, slope angle and load applied or body mass index of obese. Statistical analysis has been used to formulate the prediction of absorbed energy wherein a heel height of 30 mm with 20-degree angle provides optimum value with the incorporation of 120 D PU material. A coefficientof-determination (R2 ) value of 0.9406 confirms the suitability of the statistical regression model. Hence, the… More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Bisphenol-C Epoxy Crotonate and Its Fiber-Reinforced Composites

    PARSOTAM H. PARSANIA1,*, JIGNESH V. PATEL2, JIGNESH P. PATEL3

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 271-284, 2023, DOI:10.32381/JPM.2023.40.3-4.9

    Abstract Bisphenol-C epoxy crotonate resin was synthesized by reacting 8.09g epoxy resin of bisphenolC, and 2.15g crotonic acid using 25 mL 1,4-dioxane as a solvent, and 1 mL triethylamine as a catalyst at reflux temperature for 1-6 h. Solid epoxy crotonate (ECCR) is highly soluble in common organic solvents. ECCR was characterized by its acid (24.5-1.5 mg KOH/g) and hydroxyl (504.5-678.4 mg KOH/g) values. The structure of ECCR is supported by FTIR and 1 HNMR spectroscopic methods. A DSC endothermic transition at 229o C indicated melting followed by thermal polymerization of ECCR. ECCR is thermally stable up to 320o C and… More >

  • Open Access

    ARTICLE

    Gamma Radiation Induced Mutual Grafting of Quaternary Ammonium-Based Monomer on to Rayon Fibers to Improve its Water Absorbency and Antibacterial Efficacy

    SUBRATA PAL1,2, BHUVNESHWAR RAI1, AJAY KUMAR TYAGI1, SUNITA RATTAN2, VIRENDRA KUMAR3

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 55-70, 2022, DOI:10.32381/JPM.2022.39.1-2.4

    Abstract The present work is focused on the study of antimicrobial and water absorption properties of the surface of grafted rayon fiber with quaternary ammonium-based salts containing 3- Acrylamidopropyl trimethyl ammonium chloride (APTAC) monomer induced by gamma radiation. Grafting was qualitatively confirmed by FTIR-ATR,TGA, SEM and by calculating grafting yield and grafting efficiency. The performance was examined for water absorbency and antibacterial efficacy (R) against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Study showed that water absorption, grafting yield and grafting efficiency increased steadily with the increase in monomer concentration and absorbed gamma irradiation dose up to a certain… More >

  • Open Access

    ARTICLE

    Improve Chinese Aspect Sentiment Quadruplet Prediction via Instruction Learning Based on Large Generate Models

    Zhaoliang Wu1, Yuewei Wu1,2, Xiaoli Feng1, Jiajun Zou3, Fulian Yin1,2,*

    CMC-Computers, Materials & Continua, Vol.78, No.3, pp. 3391-3412, 2024, DOI:10.32604/cmc.2024.047076

    Abstract Aspect-Based Sentiment Analysis (ABSA) is a fundamental area of research in Natural Language Processing (NLP). Within ABSA, Aspect Sentiment Quad Prediction (ASQP) aims to accurately identify sentiment quadruplets in target sentences, including aspect terms, aspect categories, corresponding opinion terms, and sentiment polarity. However, most existing research has focused on English datasets. Consequently, while ASQP has seen significant progress in English, the Chinese ASQP task has remained relatively stagnant. Drawing inspiration from methods applied to English ASQP, we propose Chinese generation templates and employ prompt-based instruction learning to enhance the model’s understanding of the task, ultimately improving ASQP performance in the… More >

  • Open Access

    ARTICLE

    NUMERICAL SOLUTIONS FOR A NANOFLUID PAST OVER A STRETCHING CIRCULAR CYLINDER WITH NON-UNIFORM HEAT SOURCE

    A. Rasekha,*, D.D. Ganjib, S. Tavakolib

    Frontiers in Heat and Mass Transfer, Vol.3, No.4, pp. 1-6, 2012, DOI:10.5098/hmt.v3.4.3003

    Abstract The present paper deals with the analysis of boundary layer flow and heat transfer of a nanofluid over a stretching circular cylinder in the presence of non-uniform heat source/sink. The governing system of partial differential equations is converted to ordinary differential equations by using similarity transformations, which are then solved numerically using the Runge–Kutta–Fehlberg method with shooting technique. The solutions for the temperature and nanoparticle concentration distributions depend on six parameters, Prandtl number Pr, Lewis number Le, the Brownian motion parameter Nb, the thermophoresis parameter Nt, and non-uniform heat generation/absorption parameters A*, B*. Numerical results are presented both in tabular… More >

  • Open Access

    ARTICLE

    Investigation of Projectile Impact Behaviors of Graphene Aerogel Using Molecular Dynamics Simulations

    Xinyu Zhang1, Wenjie Xia2, Yang Wang3,4, Liang Wang1,*, Xiaofeng Liu1

    CMES-Computer Modeling in Engineering & Sciences, Vol.139, No.3, pp. 3047-3061, 2024, DOI:10.32604/cmes.2023.046922

    Abstract Graphene aerogel (GA), as a novel solid material, has shown great potential in engineering applications due to its unique mechanical properties. In this study, the mechanical performance of GA under high-velocity projectile impacts is thoroughly investigated using full-atomic molecular dynamics (MD) simulations. The study results show that the porous structure and density are key factors determining the mechanical response of GA under impact loading. Specifically, the impact-induced penetration of the projectile leads to the collapse of the pore structure, causing stretching and subsequent rupture of covalent bonds in graphene sheets. Moreover, the effects of temperature on the mechanical performance of… More >

  • Open Access

    ARTICLE

    The Relationship between Father-Love Absence and Loneliness: Based on the Perspective of the Social Functionalist Theory and the Social Needs Theory

    Yaping Zhou1,2,5,#, He Zhong3,#, Xiaojun Li4,*, Yanhui Xiang1,2,5,*

    International Journal of Mental Health Promotion, Vol.26, No.2, pp. 139-148, 2024, DOI:10.32604/ijmhp.2023.046598

    Abstract Fathers play an important role in adolescents’ development, which is significant for their development and influences their mental health, including feeling of loneliness. However, the effects and mechanisms of father-love absence on individual loneliness are not clear. Based on the social functionalist theory and the social needs theory, this study examines the influence of individual father-love absence on loneliness and its underlying mechanisms. A questionnaire survey was administered to 319 junior high school students and 1,476 high school students. The results showed that adolescents with father-love absence had higher levels of loneliness, and that father-love absence affected loneliness levels through… More >

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