Richard C. Ferguson, Sharathkumar K. Mendon, James W. Rawlins^*, Shelby F. Thames

Journal of Renewable Materials, Vol.2, No.3, pp. 166-172, 2014, DOI:10.7569/JRM.2013.634133

Abstract Commercial particleboards are currently synthesized by blending wood furnish with formaldehyde-based resins and curing them under a combination of heat and pressure. Particleboards manufactured with urea-formaldehyde resin are known to liberate formaldehyde during their service lives. Formaldehyde’s carcinogenicity has prompted the search for environmentally-friendly resins for wood composite manufacture. Soybean protein-based adhesives have been developed as a renewable and formaldehyde-free replacement for urea-formaldehyde resins. Particleboards processed using the soybean protein adhesive matched or exceeded performance criteria of M-2-grade commercial particleboards when evaluated as per American National Standards Institute (ANSI) specifi cations. More >

Houda Saad^1,2,*, Antonio Pizzi^3,4, Bertrand Charrier², Naceur Ayed¹, Karsten Rode⁵, Fatima Charrier - El Bouhtoury²

Journal of Renewable Materials, Vol.3, No.1, pp. 34-43, 2015, DOI:10.7569/JRM.2014.634130

Abstract The possible use of Tunisian pomegranate tannins in wood adhesive formulation was studied for the fi rst time. Colorimetric tests, Fourier transformed infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR) and matrix-assisted laser desorption/ionization time-of-fl ight (MALDI-TOF) mass spectrometry were used to examine pomegranate tannins. Analysis showed that pomegranate peels are rich in hydrolyzable tannins. The Stiasny number tests showed the low reactivity of pomegranate tannin extract to formaldehyde and thus the diffi culty of using it in wood adhesive formulation. Thermomechanical analysis (TMA) and strength analysis of pomegranate tannin/hexamine-based resin showed weak bonding properties. More >

D.N. Dorr, S.D. Frazier, K.M. Hess, L.S. Traeger, W.V. Srubar III^*

Journal of Renewable Materials, Vol.3, No.3, pp. 195-204, 2015, DOI:10.7569/JRM.2015.634108

Abstract A study of the potential for gelatin-based derivatives to serve as biorenewable, biodegradable adhesives for wood and engineered wood products is presented in this article. The effect of gelatin-to-water weight percent on the mechanical, specifically ultimate breaking (bond) strength, and thermal properties was investigated using tensile testing and differential scanning calorimetry, respectively. The breaking strengths of the gelatin-based adhesives were characterized and compared to four commercially available wood adhesives. The effect of 1–5% tannin addition on the mechanical, thermal, and moisture absorption behavior of the gelatin-based adhesives was also investigated. Results show that the gelatin-based materials demonstrate 1) appropriate thermal… More >

Weixing Zhang, Chunxia He^*

Journal of Renewable Materials, Vol.10, No.12, pp. 3263-3283, 2022, DOI:10.32604/jrm.2022.020516

Abstract With the exponential growth of the computing power, machine learning techniques have been successfully used in various applications. This paper intended to predict and optimize the shear strength of single lap cassava starchbased adhesive joints for comparison with the application of artificial intelligence (AI) methods. The shear strength was firstly determined by the experiment with three independent experimental variables (starch content, NaOH concentration and reaction temperature). The analysis of range (ANORA) and analysis of variance (ANOVA) were applied to investigate the optimal combination and the significance of each factor for the shear strength based on the orthogonal experiment. The performance… More >

Xuechuan Wang^1,2, Wenying Zhao^1,2, Xugang Dang^1,2,*, Yiqing Wang^1,2, Huijie Zhang^1,2,*

Journal of Renewable Materials, Vol.10, No.11, pp. 2747-2763, 2022, DOI:10.32604/jrm.2022.021555

Abstract As a non-toxic, highly reactive biomass material, gelatin is wildly used as the component of biomass-based adhesive. However, like most aqueous adhesives, gelatin-based adhesives suffer from long solidifying time or high solidifying temperature due to the low volatility of water, which highly limits the application potential of gelatinbased adhesives. Inspired by the fast adhesion of marine organisms through the formation of chemical crosslinks, herein, a kind of low temperature curable eco-friendly gelatin-based adhesive with good adhesive properties and fast curing at low temperature is developed by introducing clicking chemical Diels-Alder (DA) reaction between blocked waterborne polyurethane (MWPU) and gelatin. The… More > Graphic Abstract

Yantao Xu¹, Yufei Han¹, Jianzhang Li¹, Jing Luo², Sheldon Q. Shi³, Jingchao Li¹, Qiang Gao^1,*, An Mao^4,*

Journal of Renewable Materials, Vol.10, No.10, pp. 2519-2541, 2022, DOI:10.32604/jrm.2022.020750

Abstract Traditional formaldehyde-based adhesives rely excessively on petrochemical resources, release toxic gases, and pollute the environment. Plant-derived soybean protein adhesives are eco-friendly materials that have the potential to replace the formaldehyde-based adhesives used to fabricate wood-based panels. However, the poor water resistance, high brittleness, and poor mildew resistance of soybean protein adhesives limit their industrial applications. This article reviews recent research progress in the modification of soybean protein adhesives for improving the bonding performance of adhesives used for wood-based panel fabrication. Modification methods were summarized in terms of water resistance, solid content, and mildew resistance. The modification mechanisms and remaining problems… More >

Jaša Saražin¹, Ida Poljanšek¹, Antonio Pizzi², Milan Šernek^1,*

Journal of Renewable Materials, Vol.10, No.8, pp. 2117-2131, 2022, DOI:10.32604/jrm.2022.019602

Abstract The curing process of two biobased adhesives: pine tanninhexamine (TH) and organosolv lignin non-isocyanate polyurethane (NIPU), suitable for interior nonstructural use, were compared with commercial urea-formaldehyde (UF) adhesive. Changes in chemical structure before and after the curing process were observed with Fouriertransform infrared spectroscopy (FTIR). The process of adhesive curing was monitored with differential scanning calorimetry (DSC) and the automated bonding evaluation system (ABES). Both DSC and ABES measurements confirmed UF as the fastest and NIPU as the slowest curing adhesive observed. Taking into account the ABES results, the optimal pressing parameters for the TH adhesive would be 4 min… More >

Yinhuan Yang^1,*, Manfeng Gong¹, Xiaoqun Xia¹, Linzhi Wu^2,3

CMES-Computer Modeling in Engineering & Sciences, Vol.131, No.1, pp. 365-378, 2022, DOI:10.32604/cmes.2022.018535

Abstract The mechanical properties of Z-pins reinforced composites adhesively bonded single-lap joints (SLJs) under un-directional tension loading are investigated by experimental and numerical methods. Three kinds of joint configurations, including SLJs with three/two rows of Z-pins and “I” array of Z-pins, are investigated by tension test. The failure modes and mechanism of reinforced joints with different Z-pins numbers and alignment are analyzed, and the comparison is performed for the failure strengths of no Z-pins and Z-pins reinforced joints. According to experimental results, failure modes of three kinds of joints are all mixed failure. It turns out that the Z-pins are pulled… More >

Ke Shi^1,2, Luyang Wang^1,2, Ruige Qi^1,2, Chunxia He^1,2,*

Journal of Renewable Materials, Vol.10, No.5, pp. 1257-1268, 2022, DOI:10.32604/jrm.2022.017891

Abstract This work was aim to prepare a packing material from natural resources to reduce the environment pollution caused by plastics. Four bio-adhesives (guar gum, sodium alginate, agar and chitosan) were combined with lotus leaf fibers to prepare degradable composites, respectively. The mechanical properties, moisture absorption profiles and the thermal conductivity of the composites were studied and the cross section morphology and the thermal properties of the composites were analyzed. The Fourier-transform infrared spectroscopy (FTIR) results showed that the polar groups such as –OH and –COO^– in bio-adhesives can form hydrogen bond with –OH in lotus leaf fibers to connect the… More >

Saad Nader^1,2, Felipe Guzman³, Raphael Becar¹, César Segovia⁴, Cecilia Fuentealba³, Miguel Peirera³, Evelyne Mauret², Nicolas Brosse^1,*

Journal of Renewable Materials, Vol.10, No.2, pp. 263-271, 2022, DOI:10.32604/jrm.2022.017923

Abstract The reinforcing impact of Lignocellulosic micro and nanofibrillated cellulose (L-MNFCs) obtained from Eucalyptus Globulus bark in Urea-Formaldehyde UF adhesive was tested. L-MNFCs were prepared by an environmentally friendly, low-cost process using a combination process involving steam explosion followed by refining and ultra-fine grinding. Obtained L-MNFCs showed a web-like morphology with some aggregates and lignin nanodroplets. They present a mixture of residual fibers and fine elements with a width varying between 5 nm to 20 μm, respectively. The effects of the addition of low amounts of L-MNFCs (1% wt.) on the properties of three different adhesives (Urea-Formaldehyde UF, Phenol-Formaldehyde PF, and Tannin-Hexamine TH)… More > Graphic Abstract