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  • Open Access

    ARTICLE

    Synthesis of Carbon dots from Biomass Chenpi for the Detection of Hg2+

    Jun Xiang1,2,*, Xiaoqing Chen1, Qi Liu1, Huihua Jing2, Tongqiang Chen2, Wanli Tang2, Wenyang Xu2

    Journal of Renewable Materials, Vol.11, No.10, pp. 3739-3750, 2023, DOI:10.32604/jrm.2023.028090

    Abstract Biomass-derived carbon dots (C-dots) are considered a very important carbon material in metal ion detection of their small environmental impact, simple preparation process, and relatively low cost. A green approach for synthesizing biomass-derived C-dots from Chenpi using a hydrothermal method without further processing is proposed in the present study. The as-synthesized C-dots show excellent fluorescence properties, superior resistance to UV irradiation photobleaching, and high photostability in salt-containing solutions. The C-dots were used in the form of label-free fluorescent probes for sensitively detecting Hg2+ selectively. The outcome relationship behaved linearly and was established based on a given range between 10–300 nM… More > Graphic Abstract

    Synthesis of Carbon dots from Biomass Chenpi for the Detection of Hg<sup>2+</sup>

  • Open Access

    ARTICLE

    HCl-Induced Hg0 Transformation over CuMn2O4 Sorbent

    Aijia Zhang, Yingju Yang, Jing Liu*, Junyan Ding

    Energy Engineering, Vol.119, No.2, pp. 499-510, 2022, DOI:10.32604/ee.2022.015504

    Abstract CuMn2O4 spinel has been regarded as a highly efficient sorbent for Hg0 capture from flue gas. The regenerability and recyclability of CuMn2O4 sorbent are mainly associated with the mercury speciation adsorbed on its surface. However, the effect mechanism of HCl on Hg0 transformation over CuMn2O4 sorbent is still elusive. Experiments were conducted to understand the effect of HCl on Hg0 transformation over CuMn2O4 sorbent. The results indicate that CuMn2O4 sorbent is a mesoporous material and possesses a good thermal stability. CuMn2O4 shows >95% Hg0 removal efficiency in a wide temperature window of 50–350°C. The favorable electron-transfer environment caused by the… More >

  • Open Access

    ARTICLE

    Experimental Research on Mercury Catalytic Oxidation over Ce Modified SCR Catalyst

    Yadi Qin, Qiyu Weng, Yuqun Zhuo*

    Energy Engineering, Vol.119, No.1, pp. 35-47, 2022, DOI:10.32604/EE.2022.015477

    Abstract In order to improve the ability of SCR catalyst to catalyze the oxidation of gaseous elemental mercury, a series of novel Ce modified SCR (Selection Catalytic Reduction, V2O5–WO3/TiO2) catalysts were prepared via two-step ultrasonic impregnation method. The performance of Ce/SCR catalysts on Hg0 oxidation and NO reduction as well as the catalytic mechanism on Hg0 oxidation was also studied. The XRD, BET measurements and XPS were used to characterize the catalysts. The results showed that the pore volume and pore size of catalyst was reduced by Ce doping, and the specific surface area decreased with the increase of Ce content… More >

  • Open Access

    ARTICLE

    An Experimental Study on Oxidized Mercury Adsorption by Bromide Blended Coal Combustion Fly Ash

    Mingyu Yu1, Mengyuan Liu1, Guangqian Luo1,2,*, Ruize Sun1, Jingyuan Hu1, Hailu Zhu1, Li Zhong3, Lipeng Han3, Xian Li1, Hong Yao1

    Energy Engineering, Vol.118, No.5, pp. 1277-1286, 2021, DOI:10.32604/EE.2021.014810

    Abstract The application of forced mercury oxidation technology would lead to an increase of Hg2+ concentration in the flue gas. Although Hg2+ can be easily removed in the WFGD, the mercury re-emission in the WFGD can decrease the total removal of mercury from coal-fired power plants. Hence, it is necessary to control Hg2+ concentration in the devices before the WFGD. Fly ash adsorbent is considered as a potential alternative for commercial activated carbon adsorbent. However, the adsorption efficiency of the original fly ash is low. Modification procedure is needed to enhance the adsorption performance. In this study, the adsorption of Hg2+More >

  • Open Access

    ARTICLE

    Uncertainties in the Mercury Mass Balance in a Coal-Based IGCC Power Plant (Puertollano, Spain)

    José María Esbrí*, Alba Martinez-Coronado, Sofía Rivera Jurado, Eva García-Noguero, Pablo Higueras

    Energy Engineering, Vol.118, No.4, pp. 1223-1235, 2021, DOI:10.32604/EE.2021.015781

    Abstract Mercury (Hg) is a global pollutant that is subject to strict regulations to reduce anthropogenic emissions. The production of energy represents an important activity that leads to Hg emissions into the atmosphere. Of all the systems used, IGCC plants are the most promising for reducing Hg emissions, since it is possible to remove Hg from syngas prior to combustion. The aim of the present work was to evaluate the presence of Hg in the main streams of an experimental IGCC plant (ELCOGAS, Puertollano) in order to quantify Hg emissions and investigate the possibility of reducing them. The main streams of… More >

  • Open Access

    ARTICLE

    Ameliorative Role of Pre-Sowing Proline Treatment in Coriandrum sativum L. Seedlings under Mercury Toxicity

    Dhriti Kapoor1, Kapani Kavani1, Amandeep Rattan2, Marco Landi3,*, Anket Sharma4,*

    Phyton-International Journal of Experimental Botany, Vol.90, No.2, pp. 489-501, 2021, DOI:10.32604/phyton.2021.012359

    Abstract Heavy metal toxicity is one of the major ecosystem concerns globally in present time and is also responsible for significant threat to agronomic crops. The current work was conducted to investigate the possible ameliorative role of proline in Coriandrum sativum L. seedlings treated with mercury (Hg). The seedlings were exposed to different concentrations of Hg (0, 0.1, 0.3 and 0.5 mM) for 20 days. The effects of pre-sowing treatment with proline were studied on C. sativum seedlings in terms of pigment (chlorophylls, carotenoids and anthocyanins), malondialdehyde (MDA), antioxidant compound (glutathione, total phenolic compounds, ascorbic acid) and osmolytes (proline, glycine betaine).… More >

  • Open Access

    ARTICLE

    Analysis on Pore Structure of Non-Dispersible Underwater Concrete in Saline Soil Area

    Fang Liu1, Baomin Wang2,*, Mengsai Wang2, Xiaosa Yuan1

    Journal of Renewable Materials, Vol.9, No.4, pp. 723-742, 2021, DOI:10.32604/jrm.2021.013664

    Abstract

    In this paper, mercury intrusion porosimetry (MIP) is used to test the pore structure of non-dispersible underwater concrete so as to study the influence of pouring and curing environment, age and slag powder on the pore characteristics of concrete, analyze the pore characteristics, porosity and pore distribution of concrete in different hydration stages, and reveal the relationship between pore structure and permeability of concrete. The results show that the pore-size distribution of concrete in fresh water condition is better than that in sulfate environment and mixed salt environment, and therefore, sulfate as well as mixed salt are not conducive to… More >

  • Open Access

    ARTICLE

    Three-dimensional Simulations of Water-Mercury Anticonvection

    Thomas Boeck1, Alexander Nepomnyashchy2,3, Ilya Simanovskii2

    FDMP-Fluid Dynamics & Materials Processing, Vol.4, No.1, pp. 11-20, 2008, DOI:10.3970/fdmp.2008.004.011

    Abstract Anticonvection in a two-layer system of mercury and water is studied using three-dimensional direct numerical simulations with a Fourier-Chebyshev spectral method. The two fluid layers have equal thicknesses and are uniformly heated from above. Interface deformations and surface tension gradients are neglected. The quiescent state is replaced by steady hexagons upon increasing the heating from above. We investigate the destabilization of this primary convective pattern in a small and in a large computational domain upon increasing the temperature difference across the two fluid layers. For the large domain the convection cells become disordered at about twice the critical temperature difference… More >

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