ARCHANA KUMARI, KHEYANATH MITRA, SAMBHAV VISHWAKARMA, SOUROV MONDAL, SHIKHA SINGH, RAJSHREE SINGH, JAYDEEP SINGH, BISWAJIT MAITI, SUSANTA KUMAR SEN GUPTA, BISWAJIT RAY*
Journal of Polymer Materials, Vol.37, No.3-4, pp. 143-164, 2020, DOI:10.32381/JPM.2020.37.3-4.3
Abstract A new acrylamide monomer N-(3-(hexylamino)-N-(3-(isopropylamino)-3-oxopropyl) acrylamide
(HA-NIPAM-AM) and a new RAFT agent O-propionyl-2-(N,N-diphenylcarbamothioylthio) propanoate
have successfully been synthesized and used for the synthesis of poly(HA-NIPAM-AM)
homopolymers via RAFT polymerization. The formed homopolymers have been characterized
by GPC, 1
H NMR, FTIR, contact angle measurement, TG-DTA, DSC, and PXRD. Numberaveragemolar masses of the prepared polymers are in the range of 2,500 – 11,500 g/mol. Selfassembly of homopolymer has been studied viacmc determination in water using pyrene as
fluorescence probe, HRTEM and DLS. Polymeris thermally stable up to 300 °C and has a glass
transition temperature at 85.3 °C. XRD study reveals… More >
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