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  • Open Access

    ARTICLE

    Chitosan/Nanocrystalline Cellulose Biocomposites Based on Date Palm (Phoenix Dactylifera L.) Sheath Fibers

    Abeer M. Adel1, Amira M. El-Shafei2, Atef A. Ibrahim1, Mona T. Al-Shemy1,*

    Journal of Renewable Materials, Vol.7, No.6, pp. 567-582, 2019, DOI:10.32604/jrm.2019.00034

    Abstract In this study, nanocrystalline celluloses were used to enhance physical, mechanical and water vapor barrier properties of chitosan films for potential food packaging applications. Two different mineral acids (sulfuric and phosphoric) were used to extract nanocrystalline cellulose from date palm sheath fibers. The influence of cellulose I and cellulose II on the properties of the isolated nanocrystalline celluloses (e.g., yield, energy and length of intra- and intermolecular hydrogen bonds, and degree of substitution) were studied too. The characteristics of chitosan biocomposite film with phosphorylated nanocrystalline cellulose were compared to those with sulfated nanocrystalline cellulose. Results More >

  • Open Access

    ARTICLE

    Poly (Butylene Adipate-Co-Terephthalate) and Poly (Ɛ-Caprolactone) and Their Bionanocomposites with Cellulose Nanocrystals: Thermo-Mechanical Properties and Cell Viability Study

    Marcia Cristina Branciforti1,*, Caroline Faria Bellani2, Carolina Lipparelli Morelli2, Alice Ferrand3, Nadia Benkirane-Jessel3, Rosario Elida Suman Bretas2

    Journal of Renewable Materials, Vol.7, No.3, pp. 269-277, 2019, DOI:10.32604/jrm.2019.01833

    Abstract Although nanocomposites have recently attracted special interest in the tissue engineering area, due to their potential to reinforce scaffolds for hard tissues applications, a number of variables must be set prior to any clinical application. This manuscript addresses the evaluation of thermo-mechanical properties and of cell proliferation of cellulose nanocrystals (CNC), poly(butylene adipate-co-terephthalate) (PBAT), poly(ε-caprolactone) (PCL) films and their bionanocomposites with 2 wt% of CNC obtained by casting technique. Cellulose nanocrystals extracted from Balsa wood by acid hydrolysis were used as a reinforcing phase in PBAT and PCL matrix films. The films and pure CNC… More >

  • Open Access

    ARTICLE

    Edible Coatings Based on Apple Pectin, Cellulose Nanocrystals, and Essential Oil of Lemongrass: Improving the Quality and Shelf Life of Strawberries (Fragaria Ananassa)

    Ingrid Souza Vieira da Silva1, Natália Soares Prado1, Patrícia Gontijo de Melo2, Danilo Campion Arantes3, Mara Zeni Andrade4, Harumi Otaguro1, Daniel Pasquini1,*

    Journal of Renewable Materials, Vol.7, No.1, pp. 73-87, 2019, DOI:10.32604/jrm.2019.00042

    Abstract In this work, nine different types of edible coating based on pectin, cellulose nanocrystals, glycerol, and essential oil of lemongrass were prepared and used to coat strawberries with a film formed directly on the surface of the coated fruit. The effects of the different edible coatings on refrigerated fruits in terms of weight loss, titratable acidity, total soluble solids, pH, and anthocyanin content was evaluated after 2 days, 4 days, 6 days, and 8 days of storage. Application of the edible coatings reduced the weight loss of the coated strawberries and the anthocyanin content. The More >

  • Open Access

    ARTICLE

    Biocomposite Films of Polylactic Acid Reinforced with Microcrystalline Cellulose from Pineapple Leaf Fibers

    Galia Moreno, Karla Ramirez, Marianelly Esquivel, Guillermo Jimenez*

    Journal of Renewable Materials, Vol.7, No.1, pp. 9-20, 2019, DOI:10.32604/jrm.2019.00017

    Abstract Poly(lactic acid) (PLA) composite films reinforced with microcrystalline cellulose (MCC) extracted from pineapple leaf fibers (PALF) were prepared by a solution casting procedure. In an attempt to improve the interaction between PLA and cellulose, two approaches were adopted; first, poly(ethylene glycol) (PEG) was used as a surfactant, and second, the cellulosic fibers were pre-treated using tert-butanol (TBA). Lignocellulosic and cellulosic substrates were characterized using Fourier transform infrared (FTIR), wide-angle X-ray scattering (WAXS), and thermogravimetrical analysis (TGA). MCC from PALF showed good thermal stability, left few residues after decomposing, and exhibited high crystallinity index. Mechanical, thermal More >

  • Open Access

    ARTICLE

    Thickness Effect of Nanocrystalline Layer on the Deformation Mechanism of Amorphous/Crystalline Multilayered Structure

    Wen-Jay Lee1,*, Yu-Chien Lo2, Anchen Yang3, Kuanpeng Chen3, Nan-Yow Chen3

    CMES-Computer Modeling in Engineering & Sciences, Vol.120, No.2, pp. 293-304, 2019, DOI:10.32604/cmes.2019.06620

    Abstract Different thickness of amorphous/nanocrystalline multi-layered structure can be used to modulate the strength and ductility of the composite materials. In this work, molecular dynamics simulations were conducted to study the thickness effect of nanocrystalline layer on mechanical properties and deformation behavior of the Cu64Zr36/Cu multi-layer structure. The stress-strain relationship, local stress, local strain, and deformation mechanism are investigated. The results reveal that the change of thickness of the crystalline layer significantly affects the mechanical properties and deformation behavior. As the strain at the elastic region, the amorphous Cu64Zr36 layer dominates the mechanical behavior, leading the fact More >

  • Open Access

    ARTICLE

    Surfactant-Assisted Poly(lactic acid)/Cellulose Nanocrystal Bionanocomposite for Potential Application in Paper Coating

    Ragab E. Abou-Zeid1*, Mohamed A. Diab1, Salah A. A. Mohamed2, Ahmed Salama1, Hind Abdullah Aljohani3, Kamel Rizq Shoueir4

    Journal of Renewable Materials, Vol.6, No.4, pp. 394-401, 2018, DOI:10.7569/JRM.2017.634156

    Abstract The current article addresses a new strategy for the preparation of polylactic acid/cellulose nanocrystal (PLA/CNCs) nanobiocomposite films with improved structural morphology, mechanical and barrier properties for food packaging applications. The addition of hexadecyltrimethylammonium bromide (CTAB) and sodium lauryl sulfate (SLS) as cationic and anionic surfactants respectively, was found to play a crucial role in preventing re-aggregation of the CNCs during drying and improving the dispersion of CNCs in the PLA. The coated paper was characterized using mechanical tests, water vapor permeability (WVP), X-ray diffraction (XRD), scanning electron microscopy (SEM) and air permeability. The results showed More >

  • Open Access

    ARTICLE

    Carbon Nanotube/Cellulose Nanocrystal Hybrid Conducting Thin Films

    Christophe Olivier1,2, Jean Bruno Mougel1,2, Patricia Bertoncini1, Celine Moreau2, Isabelle Capron2, Bernard Cathala2, Olivier Chauvet1*

    Journal of Renewable Materials, Vol.6, No.3, pp. 237-241, 2018, DOI:10.7569/JRM.2017.634168

    Abstract Cellulose nanocrystals (CNCs) have a high ability to disperse single-walled carbon nanotubes (SWNTs) in aqueous media and to form hybrids. These hybrids are used to grow layer-by-layer thin films of controlled thickness. Thanks to the presence of SWNTs, these films are conducting. In this article, we describe the process by which the CNC/SWNT hybrids are obtained and discuss the electrical properties of the hybrid-based layer-by-layer films. More >

  • Open Access

    ARTICLE

    Inhibitors of PI3K/ERK1/2/p38 MAPK Show Preferential Activity Against Endocrine-Resistant Breast Cancer Cells

    Maitham A. Khajah, Princy M. Mathew, Yunus A. Luqmani

    Oncology Research, Vol.25, No.8, pp. 1283-1295, 2017, DOI:10.3727/096504017X14883245308282

    Abstract Current mainstream pharmacological options for the treatment of endocrine-resistant breast cancer have limitations in terms of their side effect profile and lack of discrimination between normal and cancer cells. In the current study, we assessed the responses of normal breast epithelial cells MCF10A, estrogen receptorpositive (ER+ ) MCF-7, and ER-silenced pII breast cancer cells to inhibitors (either individually or in combination) of downstream signaling molecules. The expression/activity of ERK1/2, p38 MAPK, and Akt was determined by Western blotting. Cell proliferation, motility, and invasion were determined using MTT, wound healing, and Matrigel assays, respectively. Morphological changes… More >

  • Open Access

    ARTICLE

    CXCL5 Plays a Promoting Role in Osteosarcoma Cell Migration and Invasion in Autocrine- and Paracrine-Dependent Manners

    Hongsheng Dang, Wuzhou Wu, Bo Wang, Cao Cui, Juwei Niu, Jie Chen, Ziqiu Chen, Yi Liu

    Oncology Research, Vol.25, No.2, pp. 177-186, 2017, DOI:10.3727/096504016X14732772150343

    Abstract CXCL5, a CXC-type chemokine, is an important attractant for granulocytic immune cells by binding to its receptor CXCR2. Recently, CXCL5/CXCR2 has been found to play an oncogenic role in many human cancers. However, the exact role of CXCL5 in osteosarcoma cell migration and invasion has not been revealed. Here we found that the protein expression of CXCL5 was significantly increased in osteosarcoma tissues compared with that in matched adjacent nontumor tissues. Moreover, the expression of CXCL5 was significantly associated with advanced clinical stage and metastasis. Further investigation showed that the CXCL5 expression levels were also… More >

  • Open Access

    ARTICLE

    Effect of Cellulose Nanocrystals on Fire, Thermal and Mechanical Behavior of N,N’-Diallylphenylphosphoricdiamide Modified Poly(lactic acid)

    Weijun Yang1†, Xiaomin Zhao2†, Elena Fortunati1, Franco Dominici1, Jose M. Kenny1, Debora Puglia1*, De-Yi Wang2*

    Journal of Renewable Materials, Vol.5, No.5, pp. 423-434, 2017, DOI:10.7569/JRM.2017.634146

    Abstract Presented herein is a deep investigation of the fire, mechanical and thermal performances of poly(lactic acid) (PLA)-based nanocomposites, which were obtained by combining cellulose nanocrystals (CNC) with various contents of N,N’-diallyl-phenylphosphoricdiamide (P-AA) via a two-steps masterbatch melt extrusion process (glycidyl methacrylate grafting on PLA and CNC premixing with PLA). Results have shown that the value of the limiting oxygen index (LOI) increased to 28.8% and a V-0 rating in UL94 test was obtained when 2 wt% of P-AA was added in the presence of cellulose nanocrystals (3 wt%). The incorporation of CNC induced a decrease More >

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