Wenqing Xiao^1,#, Yuhang Liu^2,#, Yuxin He¹, Qiaoguang Li^1,*, Yongquan Li^3,*

Journal of Renewable Materials, Vol.12, No.3, pp. 615-628, 2024, DOI:10.32604/jrm.2023.046780

Abstract Plasticizers are essential additives in the processing of polyvinyl chloride (PVC), with phthalate plasticizers being widely used. However, these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly, necessitating the exploration of eco-friendly bio-based alternatives. In this study, Camellia oleifera seed oil, a specialty resource in China, was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline) (AG-80) to synthesize Phenyl Camellia seed Oil Ester (PCSOE). PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations, with the conventional plasticizer dioctyl phthalate (DOP) serving as a control. Experimental results demonstrate that… More >

Qinghua Lao^1,#, Hui Zhang^1,#, Zhihong Wang², Puyou Jia³, Yongquan Li^1,*, Qiaoguang Li^4,*

Journal of Renewable Materials, Vol.11, No.7, pp. 3025-3041, 2023, DOI:10.32604/jrm.2023.026646

Abstract In this study, as the plasticizer, Camellia oleifera seed-oil-based cyclohexyl ester (COSOCE) was prepared by the reaction of cyclohexene oxide and refined C. oleifera seed oil (RCOSO) obtained by acidification hydrolysis after saponification. In addition, the structure of the target product was confirmed by Fourier transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, and Raman spectroscopy. COSOCE was used as plasticizer-modified polyvinyl chloride (PVC) membranes. The structure of the COSOCE-modified PVC membranes were characterized by Raman spectroscopy and scanning electron microscopy (SEM). The properties of the COSOCE-modified PVC membrane were characterized by contact angle measurements, universal testing machine, thermogravimetric… More >

Mei Wang¹, Xinzhu Fan¹, Quan Bu¹, Puyou Jia^2,3,*, Shouqi Yuan⁴

Journal of Renewable Materials, Vol.11, No.4, pp. 2015-2031, 2023, DOI:10.32604/jrm.2023.026063

Abstract The additives present in polyvinyl chloride (PVC) materials are the major source of organic by-products during PVC degradation. The thermal stabilizer and plasticizer are the main additives that endow PVC with the required properties during its processing. However, these two additives easily migrate when samples are obtained by physical mixing of the additives with PVC. This causes the reduction of PVC sample efficacy and the increase in the formation of organic by-products in the radiolysis process. In this work, two kinds of grafted PVC samples (tung-oil derivative grafted PVC and Atz grafted PVC, abbreviated as P-GT₄ and P-AZ₃) were synthesized… More > Graphic Abstract

Zhijie Fan¹, Huaxin Liu¹, Genjin Liu^2,*, Xuezhi Wang¹, Wenqi Cui¹

Journal of Renewable Materials, Vol.11, No.4, pp. 1763-1791, 2023, DOI:10.32604/jrm.2023.024319

Abstract The development of recycled aggregate concrete (RAC) provides a new approach to limiting the waste of natural resources. In the present study, the mechanical properties and deformability of RACs were improved by adding basalt fibers (BFs) and using external restraints, such as a fiber-reinforced polymer (FRP) jacket or a PVC pipe. Samples were tested under axial compression. The results showed that RAC (50% replacement of aggregate) containing 0.2% BFs had the best mechanical properties. Using either BFs or PVC reinforcement had a slight effect on the loadbearing capacity and mode of failure. With different levels of BFs, the compressive strengths… More > Graphic Abstract

Hongying Chu^1,2,*, Huabei Li^1,2, Xiaoyan Sun¹, Yaowang Zhang^1,2

Journal of Renewable Materials, Vol.11, No.4, pp. 1731-1743, 2023, DOI:10.32604/jrm.2022.024160

Abstract The application of phthalate plasticizers has been restricted around the world due to their poor migration and potential harm to the human body. Hence, producing functional bio-based plasticizers via exploiting clean and reusable resources meets the satisfaction of current demands. In this study, flame-retardant rubber seed oil-based plasticize (FRP) was prepared via epoxidation reaction and ring opening addition reactions, which was used as a flame-resistant plasticizer for polyvinyl chloride to replace petroleum-based phthalate plasticizer. When DOP was replaced with FRP, the torque of PVC blends increased from 11.4 to 18.4 N⋅m, the LOI value increased from 24.3% for PVC-FRP-0% to 33.1%… More > Graphic Abstract

Amar Boukerrou^*, Dalila Hammiche, Djidjelli Hocine, Hassina Aouat

Journal of Renewable Materials, Vol.2, No.4, pp. 249-257, 2014, DOI:10.7569/JRM.2014.634119

Abstract The lack of compatibility between cellulose fi bers and some polymers, such as thermoplastics, is due on one hand to the hydrophilic nature of the vegetable fi bers and on the other hand to the hydrophobic character of the matrix. This incompatibility induces bad dispersion of the fi bers and the formation of a heterogeneous material with mechanical properties which are not very satisfactory. The scope of this article is to describe the possibility of using Olive Husk Flour (OHF) as reinforcement in the elaboration of a composite material based on polyvinyl chloride (PVC). In this context, we used the… More >

H. Khellafi¹, H.M. Meddah¹, B. Ould Chikh¹, B. Bouchouicha², M. Benguediab², M. Bendouba³

CMC-Computers, Materials & Continua, Vol.49-50, No.1, pp. 31-45, 2015, DOI:10.3970/cmc.2015.049.031

Abstract The polyvinyl chloride PVC is a polymer material widely used for a large variety of applications. The present work focuses on the identification of the physical processes responsible for the mechanical properties of the PVC containing different crystallinities rate applied in large deformation and different strain rates. In order to understand the behavior of the PVC, a thermodynamic modeling is needed. Therefore, the contribution of this approach was demonstrated by experiment and numerical modeling. This comparative study demonstrates that the proposed model provides better agreement with experimental evidence. More >