FEHMI SALTAN1,2, AYLIN PALAMUTLU2, HAKAN AKAT2,*
Journal of Polymer Materials, Vol.36, No.2, pp. 133-147, 2019, DOI:10.32381/JPM.2019.36.02.3
Abstract In this work, tetraphenylporphyrin (TPP) compound was first synthesized by the condensation
reaction of pyrrole and benzaldehyde using Adler method. Then, the synthesized
tetraphenylporphyrin was nitrated with sodium nitrite. Nitro-functionalized porphyrin (TPP-NO2
)
compound was reduced to amine-functional using ammonia and this amine- functionalized
porphyrin was reacted with methacryloyl chloride to obtain porphyrin-derived radical monomer
(TPP-MAO). Copolymer was synthesized with obtained porphyrin functional monomer and styrene
by free radical polymerization method. Structural characterization and spectroscopic studies of
the synthesized compounds were carried out by FTIR, H1
-NMR, UV spectroscopy. The molecular
weight and thermal properties of the copolymer were determined… More >
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