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    ARTICLE

    Chemical Modification of Cassava Starch by Transesterification Using Vegetable Oil/Aluminum Chloride

    A.G. Gouater Issola1, A. Ngueteu Kamlo2, A.M. Cheumani Yona1,*, M. Kor Ndikontar1

    Journal of Renewable Materials, Vol.6, No.6, pp. 642-650, 2018, DOI:10.7569/JRM.2018.634108

    Abstract Chemical modification of cassava starch by transesterification of a vegetable oil (palm kernel oil) using aluminum chloride as a Lewis acid catalyst was achieved under relatively mild conditions (temperature 60–110 °C; atmospheric pressure). The reaction was carried out without any additional solvent. The modified starch was characterized by degree of substitution (DS), FTIR, X-ray diffraction and thermal analysis. DS of 0.09 to 0.53 were obtained. The cassava starch presented an X-ray diffraction pattern of a type A starch. X-ray analyses showed that the reaction did not significantly affect the crystallinity of starch. The modified starch films (MStF) adsorbed less water… More >

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