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  • Open Access

    ARTICLE

    Synthesis of Functional Photoactive Polysilane Copolymers with Disperse Yellow 7 Methacrylate and Study of their Optical, Photophysical and Thermal Properties

    KM. MEENU, DIBYENDU S. BAG*, REKHA LAGARKHAa

    Journal of Polymer Materials, Vol.36, No.3, pp. 275-292, 2019, DOI:10.32381/JPM.2019.36.03.7

    Abstract Functional photoactive polysilane copolymers of poly(methylphenylsilane) (PMPS) and disperse yellow 7 methacrylate (DY7MA) were synthesized using UV-technique. In the same manner functional polysilane copolymers of poly(methylphenylsilane-co-dimethylsilane) (CPS) and disperse yellow 7 methacrylate (DY7MA) were also synthesized. By the UV irradiation polysilanes (PMPS and CPS) give rise to silyl macroradicals which initiate the polymerization of photoactive monomer (DY7MA). The synthesized samples were characterized by FTIR, NMR, and UV-Vis spectroscopy. The molar mass of synthesized photoactive functional polysilane copolymers is of order of 103 gm/mol. They exhibited multimodal optical and photoluminescence functional properties. Optical absorbance was observed at 336 nm due to… More >

  • Open Access

    ARTICLE

    Efficient Authentication System Using Wavelet Embeddings of Otoacoustic Emission Signals

    V. Harshini1, T. Dhanwin1, A. Shahina1,*, N. Safiyyah2, A. Nayeemulla Khan2

    Computer Systems Science and Engineering, Vol.45, No.2, pp. 1851-1867, 2023, DOI:10.32604/csse.2023.028136

    Abstract Biometrics, which has become integrated with our daily lives, could fall prey to falsification attacks, leading to security concerns. In our paper, we use Transient Evoked Otoacoustic Emissions (TEOAE) that are generated by the human cochlea in response to an external sound stimulus, as a biometric modality. TEOAE are robust to falsification attacks, as the uniqueness of an individual’s inner ear cannot be impersonated. In this study, we use both the raw 1D TEOAE signals, as well as the 2D time-frequency representation of the signal using Continuous Wavelet Transform (CWT). We use 1D and 2D Convolutional Neural Networks (CNN) for… More >

  • Open Access

    ARTICLE

    Numerical Study of Temperature and Electric Field Effects on the Total Optical Absorption Coefficient in the Presence of Optical Inter-Conduction-Subband Transitions in InGaN/GaN Single Parabolic Quantum Wells

    Redouane En-nadir1,*, Haddou El-ghazi2, Anouar Jorio1, Izeddine Zorkani1, Hassan Abboudi1, Fath Allah Jabouti1

    FDMP-Fluid Dynamics & Materials Processing, Vol.18, No.5, pp. 1253-1261, 2022, DOI:10.32604/fdmp.2022.021759

    Abstract In this paper, we theoretically investigate the total optical coefficient (TOAC) considering 1S-2P and 2S-2P conduction subband transitions in a single parabolic quantum well (SPQW) with an on-center hydrogen-like impurity. Within the framework of the effective-mass approximation, the Schrödinger equation is solved numerically to obtain the eigenvalues and their corresponding eigenvectors using the finite difference method. The calculations are performed for finite confinement potential height, taking into account the dielectric and effective mass mismatches between GaN and InGaN materials under the considered electric field and temperature effects. The temperature dependence of the effective mass, dielectric constant and band gap energy… More > Graphic Abstract

    Numerical Study of Temperature and Electric Field Effects on the Total Optical Absorption Coefficient in the Presence of Optical Inter-Conduction-Subband Transitions in InGaN/GaN Single Parabolic Quantum Wells

  • Open Access

    ARTICLE

    Synthesis of Photoactive Compounds from Tall Oil Fatty Acids

    Beatrise Sture1,*, Mikelis Kirpluks1, Sergejs Gaidukovs2, Edgars Vanags1

    Journal of Renewable Materials, Vol.8, No.9, pp. 1077-1089, 2020, DOI:10.32604/jrm.2020.09294

    Abstract Photocurable systems are more effective, faster and require less energy than conventional thermal curing methods. To facilitate the ongoing transition toward a biobased economy, photoactive compounds were synthesized from tall oil fatty acids (TOFA) which is a by-product from wood pulping. In this study, photoactive monomers were synthesized by two different chemical pathways using oleic acid and TOFA as raw materials. Firstly, double bonds present in TOFA were epoxidized, followed by epoxy ring-opening with acrylic acid which introduced photoactive functional groups into the fatty acid backbone. Intermediates and final products were analysed using titration methods (acidic value, epoxy value, iodine… More >

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