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  • Open Access

    ARTICLE

    Study of the Effect of Graphite Filler on the Vulcanizing Behavior and Properties of Nitrile Rubber and NBRPVC Blends

    D. MURALI MANOHAR1,*, B.C. CHAKRABORTY2, S. SHAMSHATH BEGUM3

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 91-107, 2020, DOI:10.32381/JPM.2020.37.1-2.7

    Abstract In search of improved materials for efficient shock and vibration mounts for machineries, graphite loaded NBR and NBR/PVC blend were made and investigated. The scorch time was seen to be reduced and vulcanization rate was enhanced due to graphite inclusion. Scanning electron microscopy images have shown homogenous dispersion of graphite powder. NBRgraphite showed a gradual increase in the hardness, tensile strength, Young’s modulus, and tear values with increasing graphite loading. In the case of NBR/PVC-graphite composition, a drop in the tensile strength and increase in the Young’ modulus and tear strength was observed. Various mathematical models were used to investigate… More >

  • Open Access

    ARTICLE

    Plasticized Polyethylene/Chitosan Blend Films and Study of the Effect of Plasticizers on their various Properties and Biodegradabilty

    HULYA SEMA KOKER1, HÜLYA YAVUZ ERSAN1, AYSE AYTAC2,3,*

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 165-177, 2020, DOI:10.32381/JPM.2020.37.3-4.4

    Abstract Chitosan (CH) and low-density polyethylene (PE) blend films were produced by a twin-screw extruder and heat press with different plasticizers glycerol (GLY), sorbitol (SOR) and polyethylene glycol (PEG). The tensile strength decreased and elongation at break increased with the incorporation of plasticizer for blends with 10 wt% of CH. The thermal stability of the films was slightly higher for films containing GLY and PEG as compared to SOR. Contact angles reduced from CH-PE film to the films containing PEG, SOR and GLY in decreasing order, respectively. Fourier transform infrared spectroscopy revealed no interactions between CH and PE in CH-PE film… More >

  • Open Access

    ARTICLE

    Sulfonated Poly (Ether Ether Ketone) and its Blended Nanocomposite for Proton Conducting Membranes

    ABDUL KALAM AZAD1, ARVIND GUPTA3, LAKSHMI UNNIKRISHNAN2,3,*, SMITA MOHANTY3, SANJAY KUMAR NAYAK2,3

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 121-136, 2021, DOI:10.32381/JPM.2021.38.1-2.10

    Abstract Proton conducting hydrophilic channels were created successfully in poly (ether ether ketone) (PEEK) by means of step by step modification followed by the optimization of sulfonation process (SPEEK70, DS=68.57%). Although highly sulfonated PEEK has excellent proton conductivity, it lacks in mechanical stability due to low swelling degree. Therefore, a potential method has been proposed in this work by integrating poly (sulfone) and nanosilica (SiO2 ) into SPEEK matrix. SPEEK 70 (S) was utilized to prepare blended nanocomposite membranes for further enhancement of hydrophilic channels. The blended nanocomposite membranes are, SPEEK/SiO2 as SNS, SPEEK blended with poly (sulfone) as SP, SPEEK… More >

  • Open Access

    ARTICLE

    Reinforcing Effect of Compatibilizers Containing Oxazoline Groups in Liquid Crystalline Polymer/ Polypropylene Blending Material

    SHOGO TAKASUKA1,*, TATSUHIRO TAKAHASHI1

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 1-10, 2021, DOI:10.32381/JPM.2021.38.1-2.1

    Abstract The effects of compounds containing oxazoline groups and the presence of maleic anhydridegrafted polypropylene (PP-g-MAH) on the spectral, morphological, and tensile properties of polypropylene (PP)/liquid crystalline polymer (LCP) blends were investigated. A wholly aromatic LCP having a low melting point which was copolyester, namely AL-7000 have been used, because thermal decomposition of PP and compatibilizer must be prevented.Compression molding was selected as the molding method because it allows molding with a small amount of sample. The binary blends of PP and LCP showed a degradation of tensile properties compared to pure PP. However, the addition of 2,2'-bis(2-oxazoline) and PP-g-MAH as… More >

  • Open Access

    ARTICLE

    Rheological Study on Blend Solutions of Non-mulberry Silk Fibroin and Gelatin Biopolymers

    PRITI1,*, RADHA SACHAN2, ROLI PURWAR3

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 205-214, 2023, DOI:10.32381/JPM.2023.40.3-4.6

    Abstract In current research work, we have studied the blending effect of non-mulberry silk fibroin (10% weight/volume basis) and gelatin (20% weight/volume basis) in formic acid. Several blends as SF10G0, SF2G8, SF3G7, SF5G5 and SF0G10 have been made and their rheological behaviour was investigated. The blend solutions were subjected to a steady shear rheological study in the variety of range of shear rates, namely 0.01–500 sec-1 and the viscosities of blend solutions were noticed to decrease in comparison to pure silk solution. The frequency sweep was employed in dynamic rheological tests to determine complex viscosity of these solutions from range of… More >

  • Open Access

    ARTICLE

    Toughening of Unsaturated Polyester Resin by Blending with Polyether Telechelics. Dependency of Toughening Efficacy on End Groups

    JEEMOL. P. A1, SURESH MATHEW1, REGHUNADHAN NAIR C.P.2,*

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 111-120, 2022, DOI:10.32381/JPM.2022.39.1-2.7

    Abstract Polyether telechelics based on ethylene glycol,1,2-propylene glycol and 1,4- butylene glycol of with various molar masses and bearing at both terminals functional groups such as maleimide, itaconimide, nadimide and hydroxyl groups were individually examined as toughening agents for an unsaturated polyester resin (UPER). For a given telechelic, the toughening effect was evaluated at different mass ratios. The difference in toughening efficacy arose from the differential reactivity of the telechelics end groups combined with the unsaturation of the UPER with the reactive diluent, styrene. This causes a differential distribution of the polyether groups in the UPER matrices, resulting in a differential… More >

  • Open Access

    ARTICLE

    Effect of Sulfuric Acid on the Physiochemical Properties of Chitosan-PVA Blend for Direct Methanol Fuel Cell

    RABIRANJAN MURMUa,b, DEBASHIS ROYa, HAREKRUSHNA SUTARb, PRAGYAN SENAPATIc, SWETAK ABHISEK MOHAPATRAb

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

    Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

  • Open Access

    ARTICLE

    Effect of Adhesive Type on the Quality of Coconut Shell Charcoal Briquettes Prepared by the Screw Extruder Machine

    Samsudin Anis1,*, Deni Fajar Fitriyana1, Aldias Bahatmaka1, Muhammad Choirul Anwar1, Arsyad Zanadin Ramadhan1, Fajar Chairul Anam1, Raffanel Adi Permana1, Ahmad Jazilussurur Hakim2, Natalino Fonseca Da Silva Guterres3, Mateus De Sousa Da Silva3

    Journal of Renewable Materials, Vol.12, No.2, pp. 381-396, 2024, DOI:10.32604/jrm.2023.047128

    Abstract Indonesia is one of the largest coconut-producing countries in the world. The utilization of coconut shell waste into briquettes will increase the selling value and become a great export opportunity. However, the effect of adhesives on the quality of coconut shell charcoal briquettes made using screw extruder machine has not been widely studied. This study aims to determine the effect of adhesive type on the quality of coconut shell charcoal briquettes. The process of fabricating briquettes in this study included crushing, mixing, blending, pressing, and drying. In the mixing process, 3 types of adhesives were used, namely tapioca flour (Briquette_1),… More > Graphic Abstract

    Effect of Adhesive Type on the Quality of Coconut Shell Charcoal Briquettes Prepared by the Screw Extruder Machine

  • Open Access

    ARTICLE

    STUDY OF INTERNAL FLOW CHARACTERISTICS OF INJECTOR FUELLED WITH VARIOUS BLENDS OF DIETHYL ETHER AND DIESEL USING CFD

    Vijayakumar Thulasi*, Thundil Karuppa Raj Rajagopal

    Frontiers in Heat and Mass Transfer, Vol.4, No.2, pp. 1-5, 2013, DOI:10.5098/hmt.v4.2.3007

    Abstract Researchers across the world are exploring the potential of using diethyl ether as an alternate fuel to meet the stringent emission norms due to the high oxygen content in the fuel. The spray characteristics of any injected fuel are highly influenced by its physical properties. Due to high injection pressure in CI engines the fuel tends to cavitate inside the nozzle greatly. The change in fuel properties will affect the cavitating behavior of the fuel. In this paper computational technique is used to study and compare the internal flow characteristics of a fuel injector for different blends of diethyl ether… More >

  • Open Access

    ARTICLE

    OPTIMIZATION OF COMPRESSION RATIO OF JATROPHA OIL BLEND WITH DIESEL FUELLED ON VARIABLE COMPRESSION RATIO ENGINE

    Biswajit De*, Rajsekhar Panua

    Frontiers in Heat and Mass Transfer, Vol.5, pp. 1-4, 2014, DOI:10.5098/hmt.5.10

    Abstract As the world is facing crisis due to the dwindling resources of fossil fuels, rapid depletion of conventional energy is a matter of serious concern for the mankind. So there is a necessity to find alternate fuels. Vegetable oils, because of their agricultural origin, due to less carbon content compared to mineral diesel are producing less CO2 emissions to the atmosphere is used as an alternate fuel in substitute to diesel fuel. In the present study optimum compression ratio for VCR diesel engine fuelled with Jatropha oil blends with diesel (30%) has been determined at 203 bars injector opening pressure,… More >

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