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  • Open Access

    ARTICLE

    Fe-doped SnO2-SnS2/polypyrrole: an efficient photocatalyst for the degradation of organic pollutant in wastewater

    F. Khana, S. Noreena, M. S. Youssefb, A. Jilanic, H. T. Alib, G. Mustafad, M. Zahida,*

    Chalcogenide Letters, Vol.22, No.9, pp. 807-820, 2025, DOI:10.15251/CL.2025.229.807

    Abstract In this study Fe doped SnO2-SnS2 (FS) and Fe doped SnO2-SnS2-polypyrrole (FS-PPY) were synthesized and studied for the methylene blue (MB) egrdation under UV light. The morphological and structural characterizations were carried out by FTIR, SEM-EDX, XRD and XPS. It has been found that FS-PPy degrade methylene blue upto 98 % under optimized conditions as pH =3, dye concentration = 10 ppm, oxidant dose = 2 mM. The Langmuir-Hinshelwood kinetics model fitted well. The optimization was studied using response surface methodology. Scavengers study was carried out to find the active species. Reusability of photocatalyst was evaluated More >

  • Open Access

    ARTICLE

    CdS nanoparticles-Loaded 1D attapulgite Composites for Boosting Photocatalytic Activity

    Xiaowang Lu1,*, Cheng Luo1, Xinyu Zhu1, Ziwen Gu1, Chen Da1, Junyan Zhou1, Junchao Qian2

    Chalcogenide Letters, Vol.22, No.11, pp. 987-995, 2025, DOI:10.15251/CL.2025.2211.987

    Abstract Attapulgite clay-supported CdS composites were synthesized via hydrothermal approach and applied to remove Rhodamine B (RhB). The structural, morphological, and physicochemical properties of the materials were systematically characterized by XRD, TEM, XPS, BET and UV-Vis DRS. The combination of CdS and attapulgite could enhance active site availability and surface area, thereby boosting photocatalytic activity.The optimized CdS/attapulgite composite demonstrated remarkable photocatalytic efficiency under visible-light illumination. In addition, a potential photocatalytic degradation mechanism by the composites was proposed. More >

  • Open Access

    ARTICLE

    An Sn-Lignosulfonate Catalyst for the Dehydration of Xylose into Furfural in a Biphasic System

    Xueqin Liu1, Qingchong Xu1, Yao Liu1, Junli Ren1,*, Lihong Zhao1, Ruonan Zhu1, Xingjie Wang1, Wei Qi2

    Journal of Renewable Materials, Vol.13, No.11, pp. 2091-2107, 2025, DOI:10.32604/jrm.2025.02025-0060 - 24 November 2025

    Abstract It is highly attractive for the catalysts prepared from renewable materials and/or industrial by-products. Herein, lignosulfonate (LS) as the by-product in the papermaking industry was utilized to fabricate Sn-containing organic-inorganic complexing catalysts (Sn(x)@LS) by a simple hydrothermal self-assembly process. The fabricated Sn(x)@LS played an excellent performance in the dehydration of xylose into furfural in the carbon tetrachloride (CTC)-water biphasic system, yielding 78.5% furfural at 180°C for 60 min. It was revealed that strong coordination between Sn4+ and the phenolic hydroxyl groups of LS created a robust organic-inorganic skeleton (-Ar-O-Sn-O-Ar-), simultaneously generating potent Lewis acidic sites, and More > Graphic Abstract

    An Sn-Lignosulfonate Catalyst for the Dehydration of Xylose into Furfural in a Biphasic System

  • Open Access

    ARTICLE

    Digital Distraction or Creative Catalyst? Parental Smartphone Use and Adolescent Creativity among Chinese Vocational Students

    Min Qu1,2,#, Xiumei Chen1,3,#, Yue Zhou4, Xuelian Wang5,6,*, I-Hua Chen7,8,*

    International Journal of Mental Health Promotion, Vol.27, No.7, pp. 1029-1044, 2025, DOI:10.32604/ijmhp.2025.065876 - 31 July 2025

    Abstract Background: Despite growing research on parental technology use and its impacts on adolescent development, the influence of parental smartphone behavior on creativity remains understudied. This study addresses this gap by examining how parental phubbing affects adolescent creativity, exploring both direct and indirect pathways through creative self-efficacy as a mediator and problematic smartphone use (PSU) as a moderator. Methods: A total of 9111 Chinese vocational school adolescents (60.3% male; mean age = 16.88 years) were recruited via convenience sampling. Participants completed validated self-report questionnaires assessing creativity, parental phubbing, creative self-efficacy, and PSU. A moderated mediation model… More >

  • Open Access

    REVIEW

    Large Language Model-Driven Knowledge Discovery for Designing Advanced Micro/Nano Electrocatalyst Materials

    Ying Shen1, Shichao Zhao1, Yanfei Lv1, Fei Chen1, Li Fu1,*, Hassan Karimi-Maleh2,*

    CMC-Computers, Materials & Continua, Vol.84, No.2, pp. 1921-1950, 2025, DOI:10.32604/cmc.2025.067427 - 03 July 2025

    Abstract This review presents a comprehensive and forward-looking analysis of how Large Language Models (LLMs) are transforming knowledge discovery in the rational design of advanced micro/nano electrocatalyst materials. Electrocatalysis is central to sustainable energy and environmental technologies, but traditional catalyst discovery is often hindered by high complexity, fragmented knowledge, and inefficiencies. LLMs, particularly those based on Transformer architectures, offer unprecedented capabilities in extracting, synthesizing, and generating scientific knowledge from vast unstructured textual corpora. This work provides the first structured synthesis of how LLMs have been leveraged across various electrocatalysis tasks, including automated information extraction from literature,… More >

  • Open Access

    ARTICLE

    Preliminary Study: Furfural Production from Oat Husks via Phosphorus-Containing Catalysts Catalyzed Hydrothermal Pretreatment in the Context of Biorefinery

    Prans Brazdausks*, Maris Puke, Guntis Sosins

    Journal of Renewable Materials, Vol.13, No.4, pp. 719-730, 2025, DOI:10.32604/jrm.2025.057944 - 21 April 2025

    Abstract Oat husks, a byproduct of oat milling operations with limited economic value, present a promising feedstock for biorefinery processes due to their chemical composition. This study investigates the conversion of C5 carbohydrates in oat husks into furfural through hydrothermal pretreatment using various phosphate-based catalysts, including H3PO4, NH4H2PO4, NaH2PO4, KH2PO4, K2HPO4 and K3PO4 as catalyst. The catalysts’ effectiveness in promoting furfural production was evaluated under identical hydrothermal conditions (treatment time for 60 min at a constant temperature of 170°C and a catalyst amount). Continuous water steam was used to strip furfural from the reaction zone and minimize its degradation.… More > Graphic Abstract

    Preliminary Study: Furfural Production from Oat Husks via Phosphorus-Containing Catalysts Catalyzed Hydrothermal Pretreatment in the Context of Biorefinery

  • Open Access

    REVIEW

    Recent Advances in Polymer-Based Photocatalysts for Environmental Remediation and Energy Conversion: A Review

    Surajudeen Sikiru1,*, Yusuf Olanrewaju Busari2,3, John Oluwadamilola Olutoki4, Mohd Muzamir Mahat1, Sanusi Yekinni Kolawole5

    Journal of Polymer Materials, Vol.42, No.1, pp. 1-31, 2025, DOI:10.32604/jpm.2025.058936 - 27 March 2025

    Abstract Photocatalysis is a crucial technique for environmental cleanup and renewable energy generation. Polymer-based photocatalysts have attracted interest due to their adaptability, adjustable chemical characteristics, and enhanced light absorption efficiency. Unlike traditional inorganic photocatalysts, we can optimize polymeric systems to enhance photocatalytic efficiency and yield significant advantages in environmental remediation and energy conversion applications. This study talks about the latest developments in polymer-based photocatalysts and how important they are for cleaning water, breaking down pollutants, and making renewable energy through processes like hydrogen production and CO2 reduction. These materials are proficient in degrading harmful pollutants such as… More >

  • Open Access

    REVIEW

    Key Steps and Catalyst Performance for Conversion of Cellulose to Isosorbide: A Review

    Dan Wang, Jihuan Song, Qiyuan Wang, Chenmeng Cui, Ying Yang*

    Journal of Renewable Materials, Vol.13, No.1, pp. 49-78, 2025, DOI:10.32604/jrm.2024.056644 - 20 January 2025

    Abstract Upgrading of abundant cellulosic biomass to isosorbide can reduce the dependence on limited fossil resources and provide a sustainable way to produce isosorbide, utilized for polymers, medicine and health care product synthesis. This review comprehensively examines the key steps and catalytic systems involved in the conversion of cellulose to isosorbide. Initially, the reaction pathway from cellulose to isosorbide is elucidated, emphasizing three critical steps: cellulose hydrolysis, glucose hydrogenation, and the two-step dehydration of sorbitol to produce isosorbide. Additionally, the activation energy and acidic sites during cellulose hydrolysis, the impact of metal particle size and catalyst More > Graphic Abstract

    Key Steps and Catalyst Performance for Conversion of Cellulose to Isosorbide: A Review

  • Open Access

    ARTICLE

    Vacancy-defect promoting blue LED-driven H2O2 synthesis on Zn0.4Cd0.6S without additional cocatalysts

    W. W. Lu, J. N. Ding, Z. Y. Wang, Y. C. Wei, Y. P. Chen, J. Xu*

    Chalcogenide Letters, Vol.21, No.8, pp. 631-640, 2024, DOI:10.15251/CL.2024.218.631

    Abstract Photocatalytic synthesis of hydrogen peroxide offers an effective solution to the energy crisis. The design and development of high-activity and low-cost photocatalysts are crucial for H2O2 production. In this work, Zn0.4Cd0.6S with abundant S vacancies (SV-ZCS) is developed for H2O2 photosynthesis under 405 nm LED illumination without additional cocatalysts. The S vacancies serve as photo-generated electron trap centers, effectively extending the lifetimes of photogenerated carriers and promoting the separation of photoelectric carriers. Additionally, SV-ZCS is endowed with enhanced light capture capability, enhancing the overall photocatalytic activity for H2O2 production. The results were in line with expectations, the SV-ZCS samples More >

  • Open Access

    ARTICLE

    Influence of chromium concentration on the structural, optical, magnetical, and thermal properties of ZnS nanocrystals

    R. Selvaa, I. Devadossb,*, A. Krishnamoorthyb, S. P. Sheebab

    Chalcogenide Letters, Vol.21, No.9, pp. 747-755, 2024, DOI:10.15251/CL.2024.219.747

    Abstract Pure ZnS and Zn1-xCrxS nanoparticles were successfully prepared using the coprecipitation method, where x represents the concentration (x = 0.00, 0.10, and 0.05). There are many analytical methods used, such as X-ray diffraction (XRD), scanning electron microscopy (SEM), and Spectroscopy of energy dispersive (EDS). The magnetism structure of the catalysts was investigated using spectrophotometry (VSM), thermogravimetric analysis (TGA), and differential thermal analysis (DTA). X-ray diffraction studies determine the nanocrystal arrangement and size of microcrystals. As seen in SEM analysis, the particles are agglomerated. The coordination of sulfur ions around zinc ions was examined using FTIR analysis.… More >

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