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  • Open Access

    ARTICLE

    Synthetic Process of Bio-Based Phenol Formaldehyde Adhesive Derived from Demethylated Wheat Straw Alkali Lignin and Its Curing Behavior

    Yan Song1,2, Zhixin Wang3, Xin Zhang4, Rong Zhang1, Jinchun Li1,2,*

    Journal of Renewable Materials, Vol.9, No.5, pp. 943-957, 2021, DOI:10.32604/jrm.2021.014131

    Abstract Lignin is a natural biopolymer with a complex three-dimensional network, commercially obtained from waste liquid of paper pulp and bioethanol production, and could be a candidate for preparation of environment-friendly bio-based polyphenol material. In the present work, the demethylated wheat straw alkali lignin (D-Lig), prepared by demethylation of wheat straw alkali lignin (Lig) using an in-situ generated Lewis acid, was used to synthesize bio-based phenol formaldehyde resin adhesive (D-LPF) applied in plywood. Effects of synthetic process’s factors, including lignin substitution for phenol, NaOH concentration and molar ratio of formaldehyde to phenol, on the bonding strength and free formaldehyde content of… More >

  • Open Access

    ARTICLE

    Securing Technique Using Pattern-Based LSB Audio Steganography and Intensity-Based Visual Cryptography

    Pranati Rakshit1, Sreeparna Ganguly1, Souvik Pal2, Ayman A. Aly3, Dac-Nhuong Le4,5,*

    CMC-Computers, Materials & Continua, Vol.67, No.1, pp. 1207-1224, 2021, DOI:10.32604/cmc.2021.014293

    Abstract With the increasing need of sensitive or secret data transmission through public network, security demands using cryptography and steganography are becoming a thirsty research area of last few years. These two techniques can be merged and provide better security which is nowadays extremely required. The proposed system provides a novel method of information security using the techniques of audio steganography combined with visual cryptography. In this system, we take a secret image and divide it into several subparts to make more than one incomprehensible sub-images using the method of visual cryptography. Each of the sub-images is then hidden within individual… More >

  • Open Access

    ARTICLE

    An Eco-Friendly Wood Adhesive from Alfalfa Leaf Protein

    Bengang Zhang1,2,#, Xuedong Xi3,#, Zhigang Wu1,*, Hong Lei2,*, Lifen Li1, Meifen Tian1

    Journal of Renewable Materials, Vol.8, No.11, pp. 1429-1441, 2020, DOI:10.32604/jrm.2020.011985

    Abstract According to the preparation method commonly used for soy proteinbased adhesives, alfalfa leaf protein was used as the raw material to prepare alfalfa leaf protein-based wood adhesive. Differential scanning calorimetry analyzer (DSC), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) were used to characterize properties of the alfalfa leaf protein-based adhesive in this paper. The results revealed the following: (1) Chemical compositions and chemical structures of the alfalfa leaf protein were basically identical with those of the soy protein, both belonging to spherical proteins with the basis and potential for protein adhesives preparation, and spatial cross-linked network structures would… More >

  • Open Access

    ARTICLE

    Investigate the Effect of the Magnetic Field on the Mechanical Properties of Silicone Rubber-Based Anisotropic Magnetorheological Elastomer during Curing Process

    Tao Li1,2, Ali Abd El-Aty1,2,4, Cheng Cheng1,2, Yizhou Shen1,2, Cong Wu1,2, Qiucheng Yang1,2, Shenghan Hu1,2, Yong Xu3, Jie Tao1,2,*, Xunzhong Guo1,2,*

    Journal of Renewable Materials, Vol.8, No.11, pp. 1411-1427, 2020, DOI:10.32604/jrm.2020.012939

    Abstract In this investigation, a new silicone rubber-based MRE material was prepared to be used as a forming medium in manufacturing thin-walled complex- shaped Ni-based tubes through the bulging process. Thus, it is significant to investigate the effect of magnetic field intensity, magnetic field loading time, and angle on the mechanical properties of the prepared MRE material during the curing process. The obtained results showed that increasing the magnetic field intensity during the curing process can improve the orientation of the chain structure in the elastomer matrix effectively. However, its mechanical properties are the best under the corresponding magnetic field intensity… More >

  • Open Access

    ARTICLE

    Effect of Phenolation, Lignin-Type and Degree of Substitution on the Properties of Lignin-Modified Phenol-Formaldehyde Impregnation Resins: Molecular Weight Distribution, Wetting Behavior, Rheological Properties and Thermal Curing Profiles

    Marion Thébault1, Larysa Kutuzova2, Sandra Jury1, Iris Eicher1, Edith-Martha Zikulnig-Rusch1, Andreas Kandelbauer2,*

    Journal of Renewable Materials, Vol.8, No.6, pp. 603-630, 2020, DOI:10.32604/jrm.2020.09616

    Abstract Here, the effects of substituting portions of fossil-based phenol in phenol formaldehyde resin by renewable lignin from two different sources are investigated using a factorial screening experimental design. Among the resins consumed by the wood-based industry, phenolics are one of the most important types used for impregnation, coating or gluing purposes. They are prepared by condensing phenol with formaldehyde (PF). One major use of PF is as matrix polymer for decorative laminates in exterior cladding and wet-room applications. Important requirements for such PFs are favorable flow properties (low viscosity), rapid curing behavior (high reactivity) and sufficient self-adhesion capacity (high residual… More >

  • Open Access

    ARTICLE

    Bio-Based Hyperbranched Toughener From Tannic Acid and Its Enhanced Solvent-Free Epoxy Resin with High Performance

    Jie Xu1,3, Jiayao Yang1, Peng Lin2, Xiaohuan Liu1,*, Jinjie Zhang1, Shenyuan Fu1,*, Yuxun Tang2,*

    Journal of Renewable Materials, Vol.7, No.12, pp. 1333-1346, 2019, DOI:10.32604/jrm.2019.07905

    Abstract It is essential to design economic and efficient tougheners to prepare high-performance epoxy resin; however, this has remained a huge challenge. Herein, an eco-friendly, low-cost, and facile-fabricated bio-based hyperbranched toughener, carboxylic acid-functionalized tannic acid (CATA), was successfully prepared and applicated to the preparation of solvent-free epoxy resins. The mechanical performance, morphology, structural characterization, and thermal characterization of toughened epoxy resin system were studied. The toughened epoxy resin system with only 1.0wt% CATA reached the highest impact strength, 111% higher than the neat epoxy resin system. Notably, the tensile strength and elongation at break of toughened epoxy resin systems increased moderately… More >

  • Open Access

    ARTICLE

    Effect of Epoxidized Jatropha Oil on the Cure, Thermal, Morphological and Viscoelastic Properties of Epoxy Resins

    A. Sammaiah1, K. V. Padmaja1, K. I. Suresh*,2, R. B. N. Prasad1

    Journal of Renewable Materials, Vol.4, No.2, pp. 113-122, 2016, DOI:10.7569/JRM.2015.634118

    Abstract This article reports the effect of epoxidized jatropha oil (EJO) on the thermal, cure and viscoelastic properties of epoxy resins. Epoxidized jatropha oil with an oxirane value of 5.0 was prepared and epoxy formulations containing different concentrations of EJO were evaluated for cure, morphology, thermal and viscoelastic properties. The curing temperature of the formulations increased with increasing EJO content. The glass transition temperature of the cured films decreased from 56 °C for unmodified epoxy resin to 23 °C for the sample with 60 wt% EJO reactive diluent, suggesting good plasticizing action. The thermal decomposition was only marginally affected. More >

  • Open Access

    ARTICLE

    Superhydrophobic and Oleophobic UV-Curable Surface Engineering of Cellulose-Based Substrates

    José M. R. C. A. Santos*, Ana R. Sampaio, Joana Branquinho

    Journal of Renewable Materials, Vol.4, No.1, pp. 31-40, 2016, DOI:10.7569/JRM.2015.634123

    Abstract Cellulose-based materials are one of the most widely used materials provided by nature to mankind. In particular, cotton fi bers have been used for millennia to produce clothing items. This wide usage stems from the inherent properties of cotton fabrics such as hydrophilicity and permeability to water vapor. However, increasingly sophisticated uses for cotton-based clothing (e.g., technical textiles) demand specifi c properties such as hydrophobicity and oleophobicity for repellent functions. The current surface treatments used to attain these functionalities are based on thermally initiated polymerization reactions, using water-based formulations. Thus, the current technologies are energy- and water-intensive. The advantages of… More >

  • Open Access

    ARTICLE

    Securing Display Path for Security-Sensitive Applications on Mobile Devices

    Jinhua Cui1,2, Yuanyuan Zhang3, Zhiping Cai1,*, Anfeng Liu4, Yangyang Li5

    CMC-Computers, Materials & Continua, Vol.55, No.1, pp. 17-35, 2018, DOI:10.3970/cmc.2018.055.017

    Abstract While smart devices based on ARM processor bring us a lot of convenience, they also become an attractive target of cyber-attacks. The threat is exaggerated as commodity OSes usually have a large code base and suffer from various software vulnerabilities. Nowadays, adversaries prefer to steal sensitive data by leaking the content of display output by a security-sensitive application. A promising solution is to exploit the hardware visualization extensions provided by modern ARM processors to construct a secure display path between the applications and the display device. In this work, we present a scheme named SecDisplay for trusted display service, it… More >

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