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  • Open Access

    ARTICLE

    Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate)/ Purifi ed Cellulose Fiber Composites by Melt Blending: Characterization and Degradation in Composting Conditions

    Estefanía Lidón Sánchez-Safont1, Jennifer González-Ausejo1, José Gámez-Pérez1, José María Lagarón2, Luis Cabedo1*

    Journal of Renewable Materials, Vol.4, No.2, pp. 123-132, 2016, DOI:10.7569/JRM.2015.634127

    Abstract Novel biodegradable composites based on poly(3-hydroxybutirate-co-3-hydroxyvalerate) (PHBV) and different contents of purifi ed alpha-cellulose fi bers (3, 10, 25 and 45%) were prepared by melt blending and characterized. The composites were characterized by scanning electron microscopy (SEM), wide-angle X-ray scattering (WAXS) experiments, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanic analysis (DMA) and Shore D hardness measurements. Disintegrability under composting conditions was studied according to the ISO 20200 standard. Morphological results showed that high dispersion of the fi bers was achieved during mixing. Good adhesion on the fi ber-matrix interface was also detected by SEM. The addition of low… More >

  • Open Access

    ARTICLE

    Biodegradation Pretreatment of Wood of E. grandis, E. dunnii, and E. benthamii to Work in Biorefi nery Processes

    Mary Isabel Lopretti1,2*, Natalia Irene Baldyga3, Maria Gonzalez1, Laura Beatriz Olazabal3, Marina Graciela Torres3, Fernando Resquin4, Leonidas Carrasco4

    Journal of Renewable Materials, Vol.4, No.1, pp. 66-71, 2016, DOI:10.7569/JRM.2015.634133

    Abstract Nowadays, there is a great interest in using lignocellulosic materials as substrate for the production of biorefi nery products. Eucalypti are good options to use as crops to obtain different kinds of biofuels and derivatives, since their plantations show high adaptation potential to soil and weather conditions in Uruguay. The basic process steps involved in the obtainment of biorefi nery materials are: pretreatment, hydrolysis, fermentation and products separation. As delignifi cation is an important process to obtain biorefi nery products, in this context the evaluation of the biological (BT) and hydrothermal (TT) pretreatment of different species of Eucaliptus was studied.… More >

  • Open Access

    ARTICLE

    Biobased Additives as Biodegradability Enhancers with Application in TPU-Based Footwear Components

    Isabel Patrícia Fernandes1, Mariana Barbosa1, Joana Soares Amaral2, Vera Pinto3, José Luís Rodrigues3, Maria José Ferreira3, Maria Filomena Barreiro1*

    Journal of Renewable Materials, Vol.4, No.1, pp. 47-56, 2016, DOI:10.7569/JRM.2015.634126

    Abstract Among the wide variety of materials employed in the manufacture of shoes, thermoplastic polyurethanes (TPUs) are one of the most widely used. Given its widespread use, and associated waste management problems, the development of more biodegradable and evironmentally compatible solutions is needed. In this work, a polyester-based TPU used in the footwear industry for outsoles production was modifi ed by compounding with lignin, starch and cellulose at content of 4% (w/w). The biodegradability was evaluated by using agar plate tests with the fungi Aspergillus niger ATCC16404, the Gram-negative bacteria Pseudomonas aeruginosa ATCC9027 and an association of both (consortium), and soil… More >

  • Open Access

    ARTICLE

    Functional Electrospun Poly (Lactic Acid) Scaffolds for Biomedical Applications: Experimental Conditions, Degradation and Biocompatibility Study

    Idalba A. Hidalgo A., Felipe Sojo, Francisco Arvelo, Marcos A. Sabino∗,‡

    Molecular & Cellular Biomechanics, Vol.10, No.2, pp. 85-105, 2013, DOI:10.3970/mcb.2013.010.085

    Abstract The electrospinning technique is a method used to produce nano and microfibers using the influence of electrostatic forces. Porous three dimensional networks of continuous and interconnected fibers as scaffolds were obtained from a poly (lactic acid) solution. The concentration of the polymeric solution, 12.5% m/w, as well as the conditions of voltage (V=11kV) and tip-metallic collector distance (H=13cm) were established to develop these scaffolds through the electrospinning process. The characteristics of the scaffolds, such as fiber diameter, sintering and the biomimetics of the characteristics of a native extra cellular matrix were verified by Scanning Electron Microscopy (SEM). The orientation induced… More >

  • Open Access

    ARTICLE

    A Fully Coupled Poroelastic Reactive-Transport Model of Cartilage

    Lihai Zhang*, Bruce S. Gardiner*, David W. Smith*, Peter Pivonka*, Alan Grodzinsky

    Molecular & Cellular Biomechanics, Vol.5, No.2, pp. 133-154, 2008, DOI:10.3970/mcb.2008.005.133

    Abstract Cartilage maintains its integrity in a hostile mechanical environment. This task is made more difficult because cartilage has no blood supply, and so nutrients and growth factors need to be transported greater distances than normal to reach cells several millimetres from the cartilage surface. The chondrocytes embedded within the extracellular matrix (ECM) are essential for maintaining the mechanical integrity of the ECM, through a balance of degradation and synthesis of collagen and proteoglycans. A chondrocyte senses various chemical and mechanical signals in its local microenvironment, responding by appropriate adaption of the local ECM. Clearly a 'systems understanding' of cartilage behaviour… More >

  • Open Access

    ARTICLE

    Experimental Study on Mechanical Properties Degradation of TP110TS Tube Steel in High H2S Corrosive Environment

    Deli Gao1, Zengxin Zhao2

    CMC-Computers, Materials & Continua, Vol.26, No.2, pp. 157-166, 2011, DOI:10.3970/cmc.2011.026.157

    Abstract The research on casing corrosion in sour environment by a synergism of sweet corrosion and H2S corrosion has become the basis of casing selection and casing string safety evaluation with more and more sour reservoirs containing high H2S concentration being developed. It is essential to scientifically utilize casing service ability and reasonably control production rate of gas well to achieve the effective and safe developing of gas resources during the safety period of casing service with a precise casing life prediction. Scanning electron microscopy and tensile testing were applied to investigate the corrosion of TP110TS tube steel in stimulant solution… More >

  • Open Access

    ARTICLE

    Modeling of Degraded Composite Beam Due to Moisture Absorption For Wave Based Detection.

    Shamsh Tabrez, Mira Mitra, S. Gopalakrishnan1

    CMES-Computer Modeling in Engineering & Sciences, Vol.22, No.1, pp. 77-90, 2007, DOI:10.3970/cmes.2007.022.077

    Abstract In this paper, wave propagation is studied in degraded composite beam due to moisture absorption. The obtained wave responses are then used for diagnosis of the degraded zone. Moisture absorption causes an irreversible hygrothermal deterioration of the material. The change in temperature and moisture absorption changes the mechanical properties. Thus this affects the structure in dimensional stability as well as material degradation due to reduction in mechanical properties. Here, the composite beam is modeled as Timoshenko beam using wavelet based spectral finite element (WSFE) method. The WSFE technique is especially tailored for simulation of wave propagation. It involves Daubechies scaling… More >

  • Open Access

    ARTICLE

    Thermal Cycling Degradation of T650 Carbon Fiber/PT-30 Cyanate Ester Composite

    Huanchun Chen1, Kunigal Shivakumar1

    CMC-Computers, Materials & Continua, Vol.8, No.1, pp. 33-42, 2008, DOI:10.3970/cmc.2008.008.033

    Abstract Thermal cycling degradation effect on tensile and flexural properties of Cytec T650 carbon/Lonza Primaset PT-30 cyanate ester composite rods used for gas turbine engine brush seals was evaluated. The composite rods were thermal cycled in air from room temperature to 315°C for 100, 200, 400, 600 and 800 cycles. Each thermal cycle is a one hour period with 28 minutes hold at peak temperature and a high heating/cooling rate of 73°C/min. The composite withstood the first 100 thermal cycles with less than 10% property change. After that, tensile strength and fracture strain as well as flexural modulus were gradually reduced.… More >

  • Open Access

    ARTICLE

    Neural Network Mapping of Corrosion Induced Chemical Elements Degradation in Aircraft Aluminum

    Ramana M. Pidaparti1,2, Evan J. Neblett2

    CMC-Computers, Materials & Continua, Vol.5, No.1, pp. 1-10, 2007, DOI:10.3970/cmc.2007.005.001

    Abstract A neural network (NN) model is developed for the analysis and prediction of the mapping between degradation of chemical elements and electrochemical parameters during the corrosion process. The input parameters to the neural network model are alloy composition, electrochemical parameters, and corrosion time. The output parameters are the degradation of chemical elements in AA 2024-T3 material. The NN is trained with the data obtained from Energy Dispersive X-ray Spectrometry (EDS) on corroded specimens. A very good performance of the neural network is achieved after training and validation with the experimental data. After validating the NN model, simulations were carried out… More >

  • Open Access

    ARTICLE

    A Correlation Coefficient Approach for Evaluation of Stiffness Degradation of Beams Under Moving Load

    Thanh Q. Nguyen1,2, Thao T. D. Nguyen3, H. Nguyen-Xuan4,5,*, Nhi K. Ngo1,2

    CMC-Computers, Materials & Continua, Vol.61, No.1, pp. 27-53, 2019, DOI:10.32604/cmc.2019.07756

    Abstract This paper presents a new approach using correlation and cross-correlation coefficients to evaluate the stiffness degradation of beams under moving load. The theoretical study of identifying defects by vibration methods showed that the traditional methods derived from the vibration measurement data have not met the needs of the actual issues. We show that the correlation coefficients allow us to evaluate the degree and the effectiveness of the defects on beams. At the same time, the cross-correlation model is the basis for determining the relative position of defects. The results of this study are experimentally conducted to confirm the relationship between… More >

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