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  • Open Access

    ARTICLE

    Numerical Analysis of the Influence of Liquid Cooling Flow Space on the Assessment of Thermal Management of PEMFC

    Abubakar Unguwanrimi Yakubu1,2,4, Jiahao Zhao1, Qi Jiang1, Xuanhong Ye1, Junyi Liu1, Qinglong Yu1, Shusheng Xiong1,3,4,*

    Energy Engineering, Vol.122, No.3, pp. 1025-1051, 2025, DOI:10.32604/ee.2025.057680 - 07 March 2025

    Abstract This study uses numerical simulations of liquid cooling flow fields to investigate polymer exchange membrane fuel cell (PEMFC) thermal control. The research shows that the optimum cooling channel design significantly reduces the fuel cell’s temperature differential, improving overall efficiency. Specifically, the simulations show a reduction in the maximum temperature by up to 15% compared to traditional designs. Additionally, according to analysis, the Nusselt number rises by 20% with the implementation of serpentine flow patterns, leading to enhanced heat transfer rates. The findings demonstrate that effective cooling strategies can lead to a 10% increase in fuel More >

  • Open Access

    ARTICLE

    Preparation and characterization of ZnO@MoS2 nanocomposites: investigating photoelectrical, electrocatalytic, and electrochemical behaviors

    J. M. Shi*, H. F. Zhang, H. C. Wang

    Chalcogenide Letters, Vol.21, No.3, pp. 263-274, 2024, DOI:10.15251/CL.2024.213.263

    Abstract This study presents the synthesis and characterization of 3D ZnO@MoS2 nanocomposites, demonstrating their superior performance in photoelectrochemical applications. Employing a combination of hydrothermal and solvothermal methods, the research focuses on creating heterostructures with optimized interfacial characteristics. The ZnO@MoS2 composites show a substantial increase in photocurrent density (1.02 mA/cm²), compared to ZnO nanorods (0.32 mA/cm²), underlining enhanced charge separation efficiency. In electrocatalytic hydrogen evolution, the heterostructures exhibit a lower onset potential (-175 mV vs RHE) and reduced Tafel slope (51 mV/dec), indicating improved catalytic activity over MoS2 nanosheets. Additionally, the composites demonstrate a significant increase in electrochemical capacitance (398 More >

  • Open Access

    ARTICLE

    Characterization and application of electrochemical deposition Cdse thin films

    D. N. Alhilfia,*, A. S. Al-Kabbibb

    Chalcogenide Letters, Vol.21, No.8, pp. 641-649, 2024, DOI:10.15251/CL.2024.218.641

    Abstract The electrochemical deposition method created a CdSe thin film on FTO glass substrates. The film was examined using field scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction, Raman spectroscopy, and optical and electrochemical measurements. The results show that the CdSe nanoparticles were evenly distributed on the substrate, with a Cd/Se ratio of 63.30% Se and 36.70% Cd. The XRD revealed a polycrystalline, hexagonal structure. The film is n-type semiconductor concentration with a carrier concentration of 1.194×1020 cm-3 . The CdSe showed 552.5 mF/cm2 of specific capacity with energy and a power density of 2.5 mW/cm2 and 9000 mW/cm2 More >

  • Open Access

    ARTICLE

    Electrochemical analysis on SnSeO3/ZnSeO3 nanocomposite

    N. G. Basil Ralpha, S. Shanmugha Soundareb, D. Yamunaa, S. Ariponnammala,*

    Chalcogenide Letters, Vol.21, No.9, pp. 729-746, 2024, DOI:10.15251/CL.2024.219.729

    Abstract Nanocomposite SnSeO3/ZnSeO3 has been synthesized by hydrothermal method. X-ray powder diffraction confirms formation of SnSeO3/ZnSeO3 nanocomposite. It exhibits an interesting morphology of needle like nanorod structure. Thermal analysis reveals the thermal stability, decomposition behavior and critical temperatures where significant weight loss occurs. X-ray photoemission explains the role of the chemical state Sn, Zn, Se and O in SnSeO3/ZnSeO3. Electrochemical study has been made in both three electrode and two electrode system. In three electrode system, cyclic voltammetry exhibits a bell-shaped curve and the operational potential window is 0.8 V. The specific capacitance is 78.65 F/g for 5… More >

  • Open Access

    PROCEEDINGS

    Green Ammonia-Mediated CO2 Capture and Conversion to Valuable Chemicals

    Wenzhen Li1,*, Hengzhou Liu1, Yifu Chen1, Shuang Gu2

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.31, No.1, pp. 1-1, 2024, DOI:10.32604/icces.2024.012577

    Abstract Direct electrochemical conversion of CO2 capture solutions (instead of gaseous CO2) into valuable chemicals can circumvent the energy-intensive CO2 regeneration and pressurization steps. While commonly used CO2 capture agents include alkali and amine solutions, ammonia has been rarely investigated. In another aspect, mismanagement of reactive nitrogen (Nr) in waste has emerged as a major problem in water pollution to our ecosystems, causing severe eutrophication and health concerns. Sustainably recovering Nr [such as nitrate (NO3)-N] and converting it into green ammonia (NH3) could mitigate the environmental impacts of Nr and reduce the NH3 demand from the carbon-intensive Haber-Bosch process, as… More >

  • Open Access

    ARTICLE

    Determining the majority charge carrier, optical and structural properties of electrochemically deposited lead tin sulfide (PbSnS) thin films

    I. Nkrumah*, F. K. Ampong, A. Britwum, M. Paal, B. Kwakye-Awuah, R. K. Nkum, F. Boakye

    Chalcogenide Letters, Vol.20, No.3, pp. 205-213, 2023, DOI:10.15251/CL.2023.203.205

    Abstract Single phase lead tin sulfide (PbSnS) thin films have been successfully deposited on ITO coated glass substrates using a 3-electrode electrochemical cell having graphite as the counter electrode and Ag/AgCl as the reference electrode. In this single-step electrodeposition, the PbSnS precursor thin film was directly electrodeposited on the conductive substrate from the electrolytic bath solution which contained Pb(NO3)2, SnCl2.2H2O and Na2S2O3. This was followed by annealing in air at 250 °C for an hour to improve the crystallinity. The annealed films were characterized by a variety of techniques. Powder X-ray diffraction revealed peaks which were indexed to More >

  • Open Access

    ARTICLE

    The effect of the concentration of tin (Sn) in the metallic precursor, on the structure, morphology, optical and electrical properties of electrochemically deposited lead-tinsulphide (PbSnS) thin films

    I. Nkrumah*, F. K. Ampong, A. Britwum, M. Paal, B. Kwakye-Awuah, R. K. Nkum, F. Boakye

    Chalcogenide Letters, Vol.20, No.6, pp. 399-407, 2023, DOI:10.15251/CL.2023.206.399

    Abstract A study has been carried out to investigate the effect of the concentration of Sn in the metallic precursor on the structure, morphology, optical and electrical properties of PbSnS thin films. The films were directly electrodeposited on ITO-coated glass substrates using a 3-electrode electrochemical cell having graphite as the counter electrode and Ag/AgCl as the reference electrode. Several depositions were carried out, with each deposited film having a different concentration of Sn in the metallic precursor whilst all other parameters were kept constant for all the films. Post deposition annealing was carried out in air… More >

  • Open Access

    ARTICLE

    Analysis of Capacity Decay, Impedance, and Heat Generation of Lithium-ion Batteries Experiencing Multiple Simultaneous Abuse Conditions

    Casey Jones, Meghana Sudarshan, Vikas Tomar*

    Energy Engineering, Vol.120, No.12, pp. 2721-2740, 2023, DOI:10.32604/ee.2023.043219 - 29 November 2023

    Abstract Abuse of Lithium-ion batteries, both physical and electrochemical, can lead to significantly reduced operational capabilities. In some instances, abuse can cause catastrophic failure, including thermal runaway, combustion, and explosion. Many different test standards that include abuse conditions have been developed, but these generally consider only one condition at a time and only provide go/no-go criteria. In this work, different types of cell abuse are implemented concurrently to determine the extent to which simultaneous abuse conditions aggravate cell degradation and failure. Vibrational loading is chosen to be the consistent type of physical abuse, and the first… More >

  • Open Access

    ARTICLE

    Numerical Simulation of Fretting Fatigue Damage Evolution of Cable Wires Considering Corrosion and Wear Effects

    Ying Wang*, Zheng Yan, Yangyang Wu

    CMES-Computer Modeling in Engineering & Sciences, Vol.136, No.2, pp. 1339-1370, 2023, DOI:10.32604/cmes.2023.025830 - 06 February 2023

    Abstract In this paper, a numerical model of fretting fatigue analysis of cable wire and the fretting fatigue damage constitutive model considering the multi-axis effect were established, and the user material subroutine UMAT was written. Then, the constitutive model of wear morphology evolution of cable wire and the constitutive model of pitting evolution considering the mechanical-electrochemical effect were established, respectively. The corresponding subroutines UMESHMOTION_Wear and UMESHMOTION_Wear_Corrosion were written, and the fretting fatigue life was further predicted. The results show that the numerical simulation life obtained by the program in this paper has the same trend as… More > Graphic Abstract

    Numerical Simulation of Fretting Fatigue Damage Evolution of Cable Wires Considering Corrosion and Wear Effects

  • Open Access

    ARTICLE

    Effect of Different Etching Time on Fabrication of an Optoelectronic Device Based on GaN/Psi

    Haneen D. Jabbar1,*, Makram A. Fakhri1,*, Mohammed Jalal Abdul Razzaq1, Omar S. Dahham2,3, Evan T. Salim4, Forat H. Alsultany5, U. Hashim6

    Journal of Renewable Materials, Vol.11, No.3, pp. 1101-1122, 2023, DOI:10.32604/jrm.2023.023698 - 31 October 2022

    Abstract Gallium nitride (GaN)/porous silicon (PSi) film was prepared using a pulsed laser deposition method and 1064 nm Nd: YAG laser for optoelectronic applications and a series of Psi substrates were fabricated using a photoelectrochemical etching method assisted by laser at different etching times for 2.5–15 min at 2.5 min intervals. X-ray diffraction, room-temperature photoluminescence, atomic force microscopy and field emission scanning electron microscopy images, and electrical characteristics in the prepared GaN on the Psi film were investigated. The optimum Psi substrate was obtained under the following conditions: 10 min, 10 mA/cm2, and 24% hydrofluoric acid. The substrate exhibited two highly cubic… More >

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