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  • Open Access

    ARTICLE

    Effect of Drying Methods on the Morphology and Electrochemical Properties of Cellulose Gel Polymer Electrolytes for Lithium-Ion Batteries

    Jiling Song1, Hua Wang2,*, Jianbing Guo1, Minghua Lin2, Bin Zheng2,*, Jiqiang Wu3,*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1143-1157, 2025, DOI:10.32604/jpm.2025.073414 - 26 December 2025

    Abstract The pursuit of safer energy storage systems is driving the development of advanced electrolytes for lithium-ion batteries. Traditional liquid electrolytes pose flammability risks, while solid-state alternatives often suffer from low ionic conductivity. Gel polymer electrolytes (GPEs) emerge as a promising compromise, combining the safety of solids with the ionic conductivity of liquids. Cellulose, an abundant and eco-friendly polymer, presents an ideal base material for sustainable GPEs due to its biocompatibility and mechanical strength. This study systematically investigates how drying methods affect cellulose-based GPEs. Cellulose hydrogels were synthesized through dissolution-crosslinking and processed using vacuum drying (VD),… More >

  • Open Access

    ARTICLE

    Unveiling Ionic Conductivity and Ion Transport Properties in Polyvinyl Alcohol-Based Gel Polymer Electrolytes with Quaternary Ammonium Iodide

    M. F. Aziz1,2,*, A. A. Rahim1, A. R. M. Rais1,2,*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1097-1109, 2025, DOI:10.32604/jpm.2025.071129 - 26 December 2025

    Abstract To study the behavior of structural dynamics, ionic conductivity and ion transport properties, the gel polymer electrolytes (GPEs) was developed using polyvinyl alcohol in combination with potassium iodide, dimethyl sulfoxide, ethylene carbonate, propylene carbonate and tetra-N-propylammonium iodide (C12H28IN), The GPEs were synthesized via a solution mixing technique, systematically varying the tetra-N-propylammonium iodide concentration to optimize ionic transport properties. The gel polymer electrolytes (GPEs) preparation was initially dissolving the potassium iodide and tetra-N-propylammonium iodide in a measured combination of ethylene carbonate, propylene carbonate, and dimethyl sulfoxide within a glass container. Subsequently, polyvinyl alcohol (PVA) was introduced into… More >

  • Open Access

    ARTICLE

    Improved electrochemical performance of nanostructured CO3O4/CO3S4 composite for supercapacitor applications

    J. Ahmada, Naeem-Ur-Rehmana,*, M. Shakila, M. Saleema, K. Mahmoodb, A. Alib, M. Imranc, S. Sharifd, Hosam O. Elansarye, S. Mumtazf, A. D. Khalidg

    Chalcogenide Letters, Vol.22, No.4, pp. 277-292, 2025, DOI:10.15251/CL.2025.224.277

    Abstract This study highlights the superior electrochemical performance of Co3O4/Co3S4 composite nanoparticles for supercapacitors, compared to individual Co3O4 and Co3S4, synthesized using sol-gel, co-precipitation, and mechanical alloying methods. The composite combines pseudocapacitance and electric double-layer capacitance, as evidenced by cyclic voltammetry. It exhibits a specific capacitance of 722.9 F/g at 0.5 A/g and an energy density of 73.8 Wh/kg at 405 W/kg. Electrochemical impedance spectroscopy reveals low charge transfer resistance and excellent cycling stability is achieved, with 98.5% capacitance retention after 1500 cycles. These results confirm the composite's potential for high-performance energy storage applications. More >

  • Open Access

    ARTICLE

    Synthesis of MoS2/Fe3O4 composites for the detection of liver cancer biomarker alpha-fetoprotein

    C. B. Cuia,b, G. C. Yangb, Z. Zhanga,, X. J. Wangc,

    Chalcogenide Letters, Vol.22, No.6, pp. 507-520, 2025, DOI:10.15251/CL.2025.226.507

    Abstract This research introduces an innovative aptasensor for detecting alpha-fetoprotein with exceptional sensitivity and specificity, employing a novel MoS2/Fe3O4 composite fabricated through an advanced in-situ growth methodology. The composite exhibited a hierarchical flower-like structure with uniformly distributed Fe3O4 nanoparticles, confirmed by SEM, XRD, and Raman spectroscopy. The MoS2/Fe3O4 composite demonstrated a 66% increase in surface area (7.16 m²/g) compared to pristine MoS2, enhancing aptamer immobilization and electron transfer efficiency. Electrochemical characterization revealed a significant increase in interfacial resistance upon AFP binding, with a detection limit of 0.3 pg/mL and a dual linear range of 0.001–0.1 ng/mL and 0.1–100 More >

  • Open Access

    ARTICLE

    Preparation of ZnS-Carbon nanotube nanocomposites via solvothermal method and their application in electrochemical detection of escherichia coli O157:H7

    F. F. Tonga,*, J. L. Hanb

    Chalcogenide Letters, Vol.22, No.8, pp. 719-733, 2025, DOI:10.15251/CL.2025.228.719

    Abstract In this study, hierarchical ZnS–CNT hybrids were synthesized via a solvothermal reaction at 180 °C for 48 h, producing ∼200 nm ZnS spheres uniformly anchored onto oxidized multiwalled carbon nanotubes. Structural analyses by XRD confirmed the cubic sphalerite phase, while SEM and TEM revealed a “pearl-necklace” morphology and effective nanoparticle dispersion. XPS spectra verified Zn2+ and oxygen-containing surface groups on the composite. Nitrogen adsorption–desorption measurements showed that incorporating CNTs transformed the material’s isotherm from type III to type IV, increasing the BET surface area from 68 to 155 m2 /g and introducing mesoporosity. When drop-cast onto More >

  • Open Access

    ARTICLE

    Chemically deposited cubic SnS photocathodes for photoelectrochemical water splitting

    U. Chalapathia, M. Vasudeva Reddyb,c, C. P. Reddyd, R. Dhanalakshmie, A. Divyaf, K. Mohanarangamg, S. H. Parka,*

    Chalcogenide Letters, Vol.22, No.9, pp. 787-796, 2025, DOI:10.15251/CL.2025.229.787

    Abstract Recently, cubic SnS shows promising potential for optoelectronic applications, including solar cells. Despite its advantages, the photoelectrochemical (PEC) properties of cubic SnS photoelectrodes remain underexplored. This study examines the PEC performance of cubic SnS photocathodes synthesized on FTO substrates via chemical bath deposition and annealed at 250o C for varying durations (10, 20, and 30 min). The as-deposited SnS films, characterized by a cubic crystal structure (lattice parameter: 1.162 nm, crystallite size: 17 nm), an energy gap of 1.75 eV, and an initial photocurrent of 0.8 mA/cm2 at -1 V vs. Hg/HgO, showed significant enhancement More >

  • Open Access

    PROCEEDINGS

    Electrochemical Pneumatic Battery for Compact, Efficient, and Silent Robotic Actuation

    Junyu Ge1, Yifan Wang1, Hong Li1,2,*

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.33, No.4, pp. 1-3, 2025, DOI:10.32604/icces.2025.011446

    Abstract The advancement of untethered and adaptive robotic systems necessitates the development of compact, efficient, and silent pneumatic power sources [1,2]. Traditional pneumatic actuation relies on bulky compressors or external gas reservoirs, limiting their practical applications in mobile and autonomous systems [3,4]. This work presents a novel electrochemical pneumatic battery (EPB) that exploits electrochemical driven gas generation to achieve controlled and energy-efficient pneumatic actuation, offering a viable alternative to conventional air supply methods. The EPB operates through an electrochemical redox mechanism based on a zinc-oxygen battery [5–7], enabling reversible gas storage and controlled pressure modulation. This… More >

  • Open Access

    ARTICLE

    Cotton Residue Biomass-Based Electrochemical Sensors: The Relation of Composition and Performance

    Anna Elisa Silva, Eduardo Thiago Formigari, João Pedro Mayer Camacho Araújo, Dagoberto de Oliveira Silva, Jürgen Andreaus, Eduardo Guilherme Cividini Neiva*

    Journal of Renewable Materials, Vol.13, No.10, pp. 1899-1912, 2025, DOI:10.32604/jrm.2025.02025-0130 - 22 October 2025

    Abstract Here, we report a comprehensive study on the characterization of cotton biomass residue, its conversion into carbon-based materials via pyrolysis, and its application as an electrochemical sensor for ascorbic acid (AA). The compositions, morphologies, and structures of the resulting materials were investigated using XRD, FTIR, TGA, SEM, and EDS. Pyrolysis was carried out in an air atmosphere at different temperatures (300°C and 400°C) and durations (1, 60, and 240 min), leading to the transformation of lignocellulosic cotton residue into carbon-based materials embedded with inorganic nanoparticles, including carbonates, sulfates, chlorates, and phosphates of potassium, calcium, and… More > Graphic Abstract

    Cotton Residue Biomass-Based Electrochemical Sensors: The Relation of Composition and Performance

  • Open Access

    ARTICLE

    Biomimetic Flow Field Inspired by Sunflower Phyllotaxis: Design and Performance Optimization for Solid Oxide Fuel Cells

    Liangxiu Zhang1, Qinghai Zhao2,3,*, Feiteng Cheng1

    FDMP-Fluid Dynamics & Materials Processing, Vol.21, No.9, pp. 2177-2199, 2025, DOI:10.32604/fdmp.2025.068499 - 30 September 2025

    Abstract To advance the performance of solid oxide fuel cells (SOFCs), this work proposes a novel biomimetic flow field architecture inspired by the geometric arrangement of sunflower florets. Drawing on natural principles of optimal spatial distribution, a multi-physics simulation model of the resulting Sunflower Bionic Flow Field (SBFF) was developed. Building upon this foundation, an enhanced configuration was introduced by integrating an annular channel, yielding a modified variant referred to as Modified Sunflower Bionic Flow Field (MSBFF). For comparative purposes, a conventional Traditional Parallel Flow Field (TPFF) was also analyzed under identical conditions. Simulation results underscore… More >

  • Open Access

    ARTICLE

    Techno-Economic Comparison of Electrochemical Batteries and Supercapacitors for Solar Energy Storage in a Brazil Island Application: Off-Grid and On-Grid Configurations

    Alex Ximenes Naves1, Gladys Maquera2, Assed Haddad1, Dieter Boer3,*

    Energy Engineering, Vol.122, No.7, pp. 2611-2636, 2025, DOI:10.32604/ee.2025.061971 - 27 June 2025

    Abstract The growing concern for energy efficiency and the increasing deployment of intermittent renewable energies has led to the development of technologies for capturing, storing, and discharging energy. Supercapacitors can be considered where batteries do not meet the requirements. However, supercapacitors in systems with a slower charge/discharge cycle, such as photovoltaic systems (PVS), present other obstacles that make replacing batteries more challenging. An extensive literature review unveils a knowledge gap regarding a methodological comparison of batteries and supercapacitors. In this study, we address the technological feasibility of intermittent renewable energy generation systems, focusing on storage solutions… More > Graphic Abstract

    Techno-Economic Comparison of Electrochemical Batteries and Supercapacitors for Solar Energy Storage in a Brazil Island Application: Off-Grid and On-Grid Configurations

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