Aman Santoso^*, Sumari Sumari, Muhammad Roy Asrori

Energy Engineering, Vol.119, No.6, pp. 2255-2276, 2022, DOI:10.32604/ee.2022.021596

Abstract Biodiesel research has been carried out via transesterification. However, biodiesel products (methyl esters) have not encountered new insights, because feedstocks have been explored and studied. Various optimum conditions on transesterification reaction could produce different methyl ester type with different compound. So, this review describes various oil feedstock that were to find new insights about methyl ester type. The review took the results of study that has been published with experience for 10 years. The results of the study reviewed on the transesterification method, characterization of methyl esters, and its components. The component reviewed and correlated to the literature, structure, and… More > Graphic Abstract

M. Kirpluks^1*, D. Kalnbunde¹, Z. Walterova², U. Cabulis¹

Journal of Renewable Materials, Vol.5, No.3-4, pp. 258-270, 2017, DOI:10.7569/JRM.2017.634116

Abstract In this study, polyols with high average functionality were synthesized from a renewable resource, rapeseed oil, as raw material for rigid PU foam production. A well-known method of rapeseed oil fatty acid double bond epoxidation was used to introduce oxirane rings into rapeseed oil structure. The temperature influence on epoxidation reaction conversion rate was studied by volumetric and FTIR spectra analysis. After epoxidation of rapeseed oil, an oxirane ring-opening reaction was carried out to obtain high functionality polyols. Diethylene glycol, a conventional oxirane ring-opening reagent, was compared to amine-based polyfunctional alcohols, diethanolamine and triethanolamine. The introduction of tertiary amine groups… More >