DIBYENDU S. BAG^*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (T_g ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The T_g increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >

Xiao Luo^1,*, Hongying Chu², Mengqi Liu¹

Journal of Renewable Materials, Vol.8, No.10, pp. 1295-1304, 2020, DOI:10.32604/jrm.2020.011026

Abstract Herein, epoxidized soybean oil methyl ester (ESOM) plasticizer was synthesized for the preparation of plasticized poly(vinyl chloride) (PVC) films by the alcoholysis and epoxidation. The chemical structure of ESOM was investigated by infrared spectrum and ¹H nuclear magnetic resonance. The effect of content of ESOM and petroleum based plasticizer di-2-ethylhexyl phthalate (DEHP) on the performance of plasticized PVC films was studied. The result showed that substituting DEHP with ESOM can improve the thermal stability of plasticized PVC films. When the weight ratio of ESOM and PVC is fixed at 1:2, plasticized PVC film presents higher elongation at break (350.8% vs.… More >

Qiuren Ou^1,2,*, Peijun Ji², Jun Xiao¹, Ling Wu²

FDMP-Fluid Dynamics & Materials Processing, Vol.15, No.1, pp. 27-37, 2019, DOI:10.32604/fdmp.2019.04787

Abstract The properties of resin transfer molding (RTM) cyanate ester and its T800 grade carbon fiber composites were studied with the rheometer, differential scanning calorimetry (DSC), FT-IR, dynamic mechanical analyzer (DMA), thermal gravimetric analysis (TGA), mechanical property testing, and scanning electron microscopy (SEM). The results showed that the temperature of cyanate ester suitable for RTM process was 70℃. Curing process of the resin was 130℃/2 h+160℃/2 h+200℃/2 h+220℃/4 h. Glass transition temperature and heat decomposition temperature of the cured resin are 289℃ and 415℃, respectively. Mechanical properties of T800/RTM cyanate composites are 13.5% higher than that of T700/RTM cyanate composites and… More >