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  • Open Access

    ARTICLE

    Green Synthesis of Reduced Graphene Oxide Nanosheet by using L-ascorbic Acid and Study of its Cytotoxicity on Human Cervical Cancer Cell Line

    PRABHAT KUMAR, ANJANA SARKAR, PURNIMA JAIN*

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 121-135, 2022, DOI:10.32381/JPM.2022.39.1-2.8

    Abstract Biocompatible graphene derivative materials (GBMs) to harness the maximum potential of pristine graphene biologically, is the most important strategy for its advanced applications in pharmaceutical and other biomedical fields. Currently, scientists are trying to find this by using biopolymer nanocomposites or anchored materials. Nevertheless, tuning the bare GBMs towards biocompatibility is a beautiful approach to exploit the fundamental potential of pristine graphene vis-à-vis suppressing the effects of incorporated biopolymers or anchored materials. Herein, a large-scale, cost-effective, facile, and environment-friendly green synthetic strategy is used for the synthesis of reduced graphene oxide (rGO) nanosheet using L-ascorbic… More >

  • Open Access

    ARTICLE

    Silk Fibroin-Based Hydrogel for Multifunctional Wearable Sensors

    Yiming Zhao1,2, Hongsheng Zhao3, Zhili Wei4, Jie Yuan1, Jie Jian1, Fankai Kong1, Haojiang Xie1, Xingliang Xiong1,2,*

    Journal of Renewable Materials, Vol.10, No.11, pp. 2729-2746, 2022, DOI:10.32604/jrm.2022.019721 - 29 June 2022

    Abstract The flexible wearable sensors with excellent stretchability, high sensitivity and good biocompatibility are signifi- cantly required for continuously physical condition tracking in health management and rehabilitation monitoring. Herein, we present a high-performance wearable sensor. The sensor is prepared with nanocomposite hydrogel by using silk fibroin (SF), polyacrylamide (PAM), polydopamine (PDA) and graphene oxide (GO). It can be used to monitor body motions (including large-scale and small-scale motions) as well as human electrophysiological (ECG) signals with high sensitivity, wide sensing range, and fast response time. Therefore, the proposed sensor is promising in the fields of rehabilitation, More >

  • Open Access

    ARTICLE

    Development of Magnetite/Graphene Oxide Hydrogels from Agricultural Wastes for Water Treatment

    Hebat-Allah S. Tohamy, Mohamed El-Sakhawy, Samir Kamel*

    Journal of Renewable Materials, Vol.10, No.7, pp. 1889-1909, 2022, DOI:10.32604/jrm.2022.019211 - 08 March 2022

    Abstract A novel magnetic hydrogel loaded with graphene oxide (GO) was developed in this study. Firstly, GO was prepared from bagasse through a single step via oxidation in the presence of ferrocene under muffled atmospheric conditions, followed by the loading of different amounts of magnetite onto GO via co-precipitation reaction of iron onto GO sheets. Finally, the 2-acrylamido-2-methyl-1-propane sulfonic acid was grafted onto carboxymethyl cellulose in the presence of magnetite GO and N, N′-methylenebisacrylamide as crosslinker yielded hydrogel. The structure, morphological, and thermal behavior of the prepared hydrogels were investigated. In addition, the adsorption performance of More > Graphic Abstract

    Development of Magnetite/Graphene Oxide Hydrogels from Agricultural Wastes for Water Treatment

  • Open Access

    ARTICLE

    Strong and Tough PAm/SA Hydrogel with Highly Strain Sensitivity

    Lingqin Zhang, Qifeng Jiang, Yiming Zhao, Jie Yuan, Xiaoying Zha, Haojiang Xie, Fankai Kong, Xingliang Xiong*

    Journal of Renewable Materials, Vol.10, No.2, pp. 415-430, 2022, DOI:10.32604/jrm.2022.016650 - 30 August 2021

    Abstract The hydrogel is a preferred material for flexible wearable sensors. In practical application, it should have high-efficiency mechanical toughness and self-healing performance. Besides, hydrogel requires good affinity and adhesion because of its contact with the skin. In this experiment, we made an ultra-tough hydrogel with excellent cell affinity and adhesion. We used sodium alginate (SA) and polyacrylamide (PAm) mixture as a flexible base fluid. Polydopamine reduce graphene oxide (prGO) was used as conductive nanofiller, and then PAm-prGO-SA semi-interpenetrating network hydrogel was formed through Am radical polymerization. The presence of prGO endows the hydrogels with excellent More >

  • Open Access

    ARTICLE

    Growth of Non-enzymatic Cholesterol Biosensor using TiO2 Decorated Graphene Oxide with Bare GCE and PPy-GCE

    S. DEIVANAYAKI1,*, P. JAYAMURUGAN2, S. ASHOKAN3, V. GOPALA KRISHNAN4, B. YOGESWARI5

    Journal of Polymer Materials, Vol.38, No.3-4, pp. 295-307, 2021, DOI:10.32381/JPM.2021.38.3-4.10

    Abstract The cholesterol level determination is a significant clinical diagnostic solution for heart and, thrombosis problems. In this work, we examined a novel non-enzymatic cholesterol biosensor using cholesterol oxidase (ChOx) enzyme immobilized on TiO2 nanoparticles influenced by reduced graphene oxide (rGO) - polypyrrole (PPy) (rGO-TiO2 /PPy-GCE) nanocomposite was developed on a glassy carbon electrode (GCE) and the higher sensing response with lower detection limits were observed. The electrochemical properties of GCE modified PPy (PPy-GCE) were studied using CV (Cyclic Voltammetry) and DPV (Differential Pulse Voltammetry). The reported sensor exhibited piecewise linearity in the range of 0.1 µM More >

  • Open Access

    ARTICLE

    The Bacteria Absorption-based Yolk-Shell Ni3P-Carbon @ Reduced Graphene Oxides for Lithium-Ion Batteries

    Yuhua Yang1,2, Ke Xu1, Bo Zhao1, Nana Liu1, Jun Zhou3,4,*

    Journal of Renewable Materials, Vol.9, No.5, pp. 855-865, 2021, DOI:10.32604/jrm.2021.014525 - 20 February 2021

    Abstract Traditional carbon layer enwrapping active materials cannot easily realize perfect cladding. Therefore, it still cannot prevent the pulverization of active materials during the course of charging/discharging. In this paper, we utilize natural bacteria to absorb nickel acetate, the active materials Ni3P nanoparticles are well enwrapped, as a natural organisms surviving for billions of years, their cell walls have a perfect carbon structure, and the cell walls become carbon layer through high annealing temperature. Based on this, the yolk-shell Ni3P–carbon @ reduced graphene oxides paper is prepared, through a proper annealing temperature, the Ni3P particles disperse in the… More >

  • Open Access

    ARTICLE

    Performance Enhancement of Bio-fouling Resistant Cellulose triacetate-based Osmosis Membranes using Functionalized Multiwalled Carbon Nanotube & Graphene Oxide

    A.K. GHOSH1, RUTUJA S. BHOJE2, R.C. BINDAL1

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 109-120, 2020, DOI:10.32381/JPM.2020.37.1-2.8

    Abstract In this study, cellulose triacetate (CTA) based nanocomposite membranes were developed by incorporation of carboxylic acid functionalized multiwalled carbon-nanotube (cMWCNT) and graphene oxide (GO) which have enhancement of both flux and fouling resistance properties of the membranes. Membranes were casted at room temperature and annealed at 90o C hot water for 10 minutes. The incorporation level of both the nanomaterials is 1.5% of the CTA polymer weight in the nanocomposite membranes. Prepared membranes were characterized in terms of water contact angle, surface morphology and mechanical strength. The performance of the membranes was evaluated both in… More >

  • Open Access

    ARTICLE

    Influence of the Molecular Weight on PVA/GO Composite Membranes for Fuel Cell Applications

    C. González-Guisasola1, O. Gil-Castell1,2, R. Teruel-Juanes1, A. Ribes-Greus1,*

    Journal of Renewable Materials, Vol.8, No.9, pp. 1171-1180, 2020, DOI:10.32604/jrm.2020.04399 - 03 August 2020

    Abstract Composite polymer electrolyte membranes were prepared with poly (vinyl alcohol) (PVA). Two different molecular weight (Mw), 67·103 and 130·103 g·mol−1 were selected, cross-linked with sulfosuccinic acid (SSA) and doped graphene oxide (GO). The effects on the membranes obtained from these polymers were characterized in order to evaluate the fuel cell performance. Electron microscopy showed a proper nanoparticle distribution in the polymer matrix. The chemical structure was evaluated by Fourier transform infrared spectroscopy. The absence of a crystalline structure and the enhancement on the thermal stability with the addition of 1% of GO was demonstrated by thermal characterization. More >

  • Open Access

    ARTICLE

    Sunflower-Like SrCo2S4@f-MWCNTs Hybrid Wrapped by Engineering N-Reduced Graphene Oxide for High Performance Dye-Sensitized Solar Cells

    Weiming Zhang1, Muhammad Wasim Khan1, Xueqin Zuo1, Qun Yang1, Huaibao Tang1,2, Shaowei Jin1,2, Guang Li1,2,3,*

    Journal of Renewable Materials, Vol.8, No.4, pp. 431-446, 2020, DOI:10.32604/jrm.2020.09158 - 24 April 2020

    Abstract A novel sunflower-like nanocomposite of SrCo2S4 nanoflakes and functionalized multiwall carbon nanotubes (f-MWCNTs) entanglement enveloped in nitrogen-reduced graphene oxide (N-RGO) is prepared by a cheap process. The unique entanglement structure of the material exhibits higher specific surface area, better electrical conductivity and other properties. This helps to reduce the transfer resistance in the photoelectric process of the battery and improve the electrochemical activity, thus increasing the photoelectric conversion efficiency of the battery. The new ternary cobalt-based sulfide material can replace platinum as the counter electrode (CE) material loaded on dye-sensitized solar cells (DSSCs). DSSCs with SrCo2S4@f-MWCNTs@N-RGO More >

  • Open Access

    ARTICLE

    Functionalised Poly(Vinyl Alcohol)/Graphene Oxide as Polymer Composite Electrolyte Membranes

    O. Gil-Castell1,2, R. Cerveró1, R. Teruel-Juanes1, J. D. Badia1,2, A. Ribes-Greus1,*

    Journal of Renewable Materials, Vol.7, No.7, pp. 655-665, 2019, DOI:10.32604/jrm.2019.04401

    Abstract Crosslinked poly(vinyl alcohol) (PVA) based composite films were prepared as polyelectrolyte membranes for low temperature direct ethanol fuel cells (DEFC). The membranes were functionalised by means of the addition of graphene oxide (GO) and sulfonated graphene oxide (SGO) and crosslinked with sulfosuccinic acid (SSA). The chemical structure was corroborated and suitable thermal properties were found. Although the addition of GO and SGO slightly decreased the proton conductivity of the membranes, a significant reduction of the ethanol solution swelling and crossover was encountered, more relevant for those functionalised with SGO. In general, the composite membranes were More >

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