H. R. Shakir^a, O. A. Chichan^b, M. S. Sada^c,*, S. A. Hussein^d, S. S. Chiad^e, N. F. Habubi^f, Y. H. Kadhim^g, M. Jadan^h,i

Chalcogenide Letters, Vol.22, No.1, pp. 77-89, 2025, DOI:10.15251/CL.2025.221.77

Abstract CdS, and CdS: Al were grown onto glass bases via Chemical spray pyrolysis (CSP). XRD analysis of CdS films indicates a polycrystalline hexagonal structure with a predominant orientation of the (101) plane. The strain decreased from 28.55 to 25.66, and the grain size of undoped CdS films was around (13.51–12.14) nm as Al content rose. According to the results of AFM, CdS, CdS:2% Al, and CdS:4% Al all exhibit smooth surfaces with decreasing particle size in the range of (78.46), (69.75), and (42.20) nm, respectively. The root-mean-square roughness values for CdS and CdS:4% Al were… More >

R. I. Jasim^a, E. H. Hadi^a, A. A. Mansour^b, S. A. Hussein^c, S. S. Chiad^a,*, N. F. Habubi^d, Y. H. Kadhim^e, M. Jadan^f,g

Chalcogenide Letters, Vol.22, No.1, pp. 43-55, 2025, DOI:10.15251/CL.2025.221.43

Abstract Using chemical bath deposition (CBD) methods and various molarities, nanostructured CdS thin films were developed. XRD assured that these films were cubic polycrystalline, containing larger grains as the solution's concentration of cadmium ions increased. Dislocation density values dropped from 79.32 to 62.90 as a result, nevertheless. Also, the strain is lowered from 30.88 to 27.50. AFM results demonstrate that these films suffer a decrease in the value of average particle size, root mean square, and roughness with the molarity concentration. SEM images show CdS thin films at various molarities (0.10, 0.15, 0.20) M, indicating reduced More >

J. Ahmad^a, Naeem-Ur-Rehman^a,*, M. Shakil^a, M. Saleem^a, K. Mahmood^b, A. Ali^b, M. Imran^c, S. Sharif^d, Hosam O. Elansary^e, S. Mumtaz^f, A. D. Khalid^g

Chalcogenide Letters, Vol.22, No.4, pp. 277-292, 2025, DOI:10.15251/CL.2025.224.277

Abstract This study highlights the superior electrochemical performance of Co₃O₄/Co₃S₄ composite nanoparticles for supercapacitors, compared to individual Co₃O₄ and Co₃S₄, synthesized using sol-gel, co-precipitation, and mechanical alloying methods. The composite combines pseudocapacitance and electric double-layer capacitance, as evidenced by cyclic voltammetry. It exhibits a specific capacitance of 722.9 F/g at 0.5 A/g and an energy density of 73.8 Wh/kg at 405 W/kg. Electrochemical impedance spectroscopy reveals low charge transfer resistance and excellent cycling stability is achieved, with 98.5% capacitance retention after 1500 cycles. These results confirm the composite's potential for high-performance energy storage applications. More >

K. Wang^a,b,*, G. L. Lian^c, Y. F. Qiao^d

Chalcogenide Letters, Vol.22, No.10, pp. 889-904, 2025, DOI:10.15251/CL.2025.2210.889

Abstract The remediation of acid mine drainage (AMD), characterized by its high concentrations of toxic metal ions and low pH, presents a significant environmental challenge. In this study, exfoliated two-dimensional MoS_₂ nanosheets were prepared using a liquid-phase ultrasonication method and evaluated for their efficiency in removing Cd^²⁺, Cu^²⁺, and Pb^²⁺ from aqueous solutions. Detailed structural and morphological analyses confirmed that the exfoliation process significantly enhanced surface area, pore volume, and exposure of reactive sulfur sites. Through isotherm and kinetic modeling analyses, the adsorption behavior was found to align with the Langmuir model and pseudo-second-order kinetic equation, which implies More >

R. Yoga Indra Eniya¹, K. Vijayakumar², B. Vigneashwari^3,*

Chalcogenide Letters, Vol.22, No.11, pp. 971-985, 2025, DOI:10.15251/CL.2025.2211.971

Abstract Nanocrystals (~16 nm) of semiconducting lead sulphide (PbS) were synthesized using the coprecipitation method, which was characterized for phase and compositional purity. These ultrafine particles of PbS exhibited quantum confinement characteristics, which were revealed by blue-shifting in optical absorption using UV-DRS analysis. These QDs of PbS were driven under the influence of the applied electric field using monodispersed colloidal suspension on the Indium-Tin-Oxide (ITO) substrate using the electrophoretic deposition technique (EPD). The formation of self-organized arrays of PbS quantum dots (QDs) and their stacked assemblies was achieved through EPD. Interestingly, neither complexing agents nor templates More >

Nanpu Cao¹, Huan Luo¹, Song Yue¹, Yong Chen¹, Mao Xu¹, Pu Cao¹, Tao Xin¹, Hongying Luo¹, Fa Zhang^2,*

Journal of Polymer Materials, Vol.42, No.3, pp. 661-675, 2025, DOI:10.32604/jpm.2025.067313 - 30 September 2025

Abstract This review systematically summarizes recent advancements in the design of antibacterial hydrogels and the surface-related factors influencing microbial adhesion to polymeric materials. Hydrogels, characterized by their three-dimensional porous architecture and ultra-high water content, serve as ideal platforms for incorporating antibacterial agents (e.g., metal ions, natural polymers) through physical/chemical interactions, enabling sustained release and enhanced antibacterial efficacy. For traditional polymers, surface properties (e.g., roughness, charge, superhydrophobicity, free energy, nanoforce gradients) play critical roles in microbial adhesion. Modifying the surface properties of polymers through surface treatment can regulate antibacterial performance. In particular, by referencing the micro/nanostructures found More >

A. A. Mansour^a, H. A. Salman^b, S. A. Abdul Wahab^c, N. F. Habubi^c, S. S. Chiad^d,*, Z. S. A. Mosa^c, Y. H. Kadhim^d

Chalcogenide Letters, Vol.21, No.3, pp. 275-284, 2024, DOI:10.15251/CL.2024.213.275

Abstract To grow SnS films, the spray pyrolysis deposition (SPD) process is applied. The films were deposited at various substrate temperatures (S_T) of 400, 450, and 500 degrees Celsius for two hours. Through XRD analysis, the impact of ST on the structure was investigated. Peak (113) crystallite sizes were 13.16, 21.48, and 38.87 nm, respectively, at base temperatures of (400, 450, and 500) ℃. The effect of ST on the structure was examined using XRD analysis. A predominat Peak at (113) plane. The crystallite sizes at base temperatures of (400, 450, and 500) ℃ were 13.16, 21.48, More >

A. Mustafa^*, S. Turki Al-Rashid

Chalcogenide Letters, Vol.21, No.5, pp. 407-411, 2024, DOI:10.15251/CL.2024.215.407

Abstract Applying the cohesive energy model, this research theoretically studies how the size of nanoparticles affects their optical characteristics. The findings demonstrate that optical characteristics are size-dependent for nanoparticles, with an exponentially growing energy gap for nanoparticles on a scale of less than 4 nm. As the size of nanoparticles is reduced, the absorption wavelength also decreases. Compounds undergo a transition to a higher energy spectral area (blue shift) when their wavelength decreases; this change can make these compounds effective in certain optical nanodevices. More >

Alan F.N. Boss¹, Manuella G.C. Munhoz¹, Gisele Amaral-Labat², Rodrigo G.A. Lima², Leonardo I. Medeiros^2,3, Nila C.F.L. Medeiros^2,3, Beatriz C.S. Fonseca², Flavia L. Braghiroli^4,*, Guilherme F.B. Lenz e Silva¹

Journal of Renewable Materials, Vol.12, No.10, pp. 1639-1659, 2024, DOI:10.32604/jrm.2024.056004 - 23 October 2024

Abstract Radar Absorbing Materials (RAM) are a class of composites that can attenuate incident electromagnetic waves to avoid radar detection. Most carbon allotropes that have the potential to be used as RAM are either carbon nanotubes (CNTs), graphene, carbon black (CB) and ultimately, sustainable porous carbon (SPC). Here, black wattle bark waste (following tannin extraction) was used as a sustainable source to produce SPC made from biomass waste. It was characterized and used as a filler for a silicone rubber matrix to produce a flexible RAM. The electromagnetic performance of this composite was compared with composites… More > Graphic Abstract

Qishan Huang¹, Haofei Zhou^2,*

The International Conference on Computational & Experimental Engineering and Sciences, Vol.25, No.3, pp. 1-1, 2023, DOI:10.32604/icces.2023.010014

Abstract Nanostructured metals contain vast amount of grain boundaries which are crucial to their mechanical behaviors. The plastic deformation mechanisms mediated by grain boundaries have been attracted increasing attentions in recent years. Our recent studies have been focused on using atomistic simulations to understand the grain boundary mediated plastic deformation mechanisms including deformation twinning initiated by dislocation nucleation from grain boundaries [1], cyclic plastic deformability governed by reversible slip of grain boundary dislocations [2], and extreme shear deformation of nanocrystals induced by twin boundary sliding [3]. We have also proposed a misorientation-dependent model to explain the More >