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  • Open Access

    ARTICLE

    Performance Evaluation of Hierarchically Structured Superhydrophobic PVDF Membranes for Heavy Metals Removal via Membrane Distillation

    Pooja Yadav1,*, Ramin Farnood2, Vivek Kumar1,*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1181-1197, 2025, DOI:10.32604/jpm.2025.072564 - 26 December 2025

    Abstract Heavy metal contamination in water sources is a widespread global concern, particularly in developing nations, with various treatment approaches under extensive scientific investigation. In the present study, we fabricated electrospun composite polyvinylidene fluoride (PVDF) nanofibrous membranes exhibiting hierarchical surface roughness and superhydrophobicity for the removal of heavy metal ions via vacuum membrane distillation (VMD) process. The membranes were prepared by incorporating optimized dosing of silica nanoparticles, followed by a two-step membrane modification approach. These membranes exhibited notable characteristics, including elevated water contact angle (152.8 ± 3.2°), increased liquid entry pressure (127 ± 6 kPa), and… More > Graphic Abstract

    Performance Evaluation of Hierarchically Structured Superhydrophobic PVDF Membranes for Heavy Metals Removal via Membrane Distillation

  • Open Access

    ARTICLE

    Synthesis of Hyperbranched Polyethyleneimine-Propylene Oxide-N-isopropylacrylamide (HPEI-co-PO-co-NIPAM) Terpolymer as a Shale Inhibitor

    Wenjun Hu, Liquan Zhang*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1159-1179, 2025, DOI:10.32604/jpm.2025.072450 - 26 December 2025

    Abstract Addressing the persistent challenge of shale hydration and swelling in water-based drilling fluids (WBDFs), this study developed a smart thermo-responsive shale inhibitor, Hyperbranched Polyethyleneimine-Propylene Oxide-N-isopropylacrylamide (HPN). It was synthesized by grafting hyperbranched polyethyleneimine (HPEI) with propylene oxide (PO) and N-isopropylacrylamide (NIPAM), creating a synergistic hydration barrier through hydrophobic association and temperature-triggered pore plugging. Structural characterization by Fourier-Transform Infrared (FTIR) spectroscopy and gel permeation chromatography (GPC) confirmed the successful formation of the HPN terpolymer, revealing a unique “cationic–nonionic” amphiphilic architecture with temperature-responsive properties. Performance evaluation demonstrated that HPN significantly outperforms conventional inhibitors, including potassium chloride (KCl),… More >

  • Open Access

    ARTICLE

    Highly Pure Water-Soluble Aspen Wood Hemicelluloses Derived by Catalytic Peracetic Treatment and Their Antioxidant and Flocculation Activity

    Valentina Sergeevna Borovkova1,2,*, Yuriy Nikolaevich Malyar1,2, Vladislav Alexandrovich Ionin1,2, Alexander Sergeevich Kazachenko1,2

    Journal of Renewable Materials, Vol.13, No.12, pp. 2281-2296, 2025, DOI:10.32604/jrm.2025.02025-0067 - 23 December 2025

    Abstract The valorization of plant biomass towards high-value chemicals is a global trend aimed at solving the problem of the huge accumulation of lignocellulosic waste. Plant polysaccharides are natural polymers that make up about 20% by weight of biomass, with a unique variety of structures and properties that depend on the type of raw materials and the method of their extraction. In this study, the effect of variability of the oxidative delignification process conditions in the «acetic acid-hydrogen peroxide-water-(NH4)6Mo7O24» on the extraction and properties of aspen (Populus tremula) wood hemicelluloses was investigated for the first time. The developed… More > Graphic Abstract

    Highly Pure Water-Soluble Aspen Wood Hemicelluloses Derived by Catalytic Peracetic Treatment and Their Antioxidant and Flocculation Activity

  • Open Access

    ARTICLE

    A Comprehensive Numerical and Data-Driven Investigations of Nanofluid Heat Transfer Enhancement Using the Finite Element Method and Artificial Neural Network

    Adnan Ashique1,#, Khalid Masood2, Usman Afzal1, Mati Ur Rahman2, Maddina Dinesh Kumar3, Sohaib Abdal3, Nehad Ali Shah1,#,*

    CMES-Computer Modeling in Engineering & Sciences, Vol.145, No.3, pp. 3627-3699, 2025, DOI:10.32604/cmes.2025.072523 - 23 December 2025

    Abstract This study outlines a quantitative and data-driven study of the mixed convection heat transfer processes that concern Cu-water nanofluids in a Γ-shaped enclosure with one to five rotating cylinders. The dimensionless equations of mass, momentum, and energy are solved using the finite element method as implemented in the COMSOL Multiphysics 6.3 software in different rotating Reynolds numbers and cylinder geometries. An artificial Neural Network that is trained using Bayesian Regularization on data produced by the COMSOL is utilized to estimate the average Nusselt numbers. The analysis is conducted for a wide range of rotational… More >

  • Open Access

    ARTICLE

    Development of a Multi-Resolution SPH-PD Model for Simulating Ice Sheet Fragmentation under Underwater Explosion Loads

    Guang-Qi Liang1, Peng-Nan Sun1,2,*, A-Man Zhang3

    CMES-Computer Modeling in Engineering & Sciences, Vol.145, No.3, pp. 3405-3431, 2025, DOI:10.32604/cmes.2025.072496 - 23 December 2025

    Abstract A multi-resolution smoothed particle hydrodynamics and peridynamics (SPH-PD) coupling model is proposed in this study for simulating the fracture characteristics of ice plates exposed to underwater blast loads. The SPH model employs a volume adaptive scheme (VAS) and a multi-resolution particle technique to accurately simulate explosive charge detonation and shock wave propagation. This approach addresses numerical challenges from charge expansion and significant size disparity between the charge and the fluid particles. The model captures the full underwater explosion process, covering both the shock wave phase and the bubble expansion stage, by applying appropriate equations of More >

  • Open Access

    ARTICLE

    Development of a CNT/Bi2S3/PVDF composite waterproof film-based strain sensor for motion monitoring

    A. X. Yanga, L. F. Huangb,*, Y. Y. Liuc

    Chalcogenide Letters, Vol.22, No.7, pp. 649-663, 2025, DOI:10.15251/CL.2025.227.649

    Abstract An innovative flexible electronic device was developed by integrating functionalized carbon nanotubes, bismuth sulfide nanostructures, and a polyvinylidene fluoride matrix to create a highly water‐resistant strain detection platform. The fabricated film exhibited a remarkable static water contact angle of 141°, with only a 3–4° reduction after 48 hours of immersion, confirming its excellent hydrophobic performance. Mechanical testing revealed a tensile strength of 43.2 MPa and maintained over 96% of its original strength following 1000 bending cycles, thereby demonstrating outstanding durability under repetitive deformation. Electrical characterization showed an initial conductivity of 12.3 S/m and a baseline resistance near… More >

  • Open Access

    ARTICLE

    Fe-doped SnO2-SnS2/polypyrrole: an efficient photocatalyst for the degradation of organic pollutant in wastewater

    F. Khana, S. Noreena, M. S. Youssefb, A. Jilanic, H. T. Alib, G. Mustafad, M. Zahida,*

    Chalcogenide Letters, Vol.22, No.9, pp. 807-820, 2025, DOI:10.15251/CL.2025.229.807

    Abstract In this study Fe doped SnO2-SnS2 (FS) and Fe doped SnO2-SnS2-polypyrrole (FS-PPY) were synthesized and studied for the methylene blue (MB) egrdation under UV light. The morphological and structural characterizations were carried out by FTIR, SEM-EDX, XRD and XPS. It has been found that FS-PPy degrade methylene blue upto 98 % under optimized conditions as pH =3, dye concentration = 10 ppm, oxidant dose = 2 mM. The Langmuir-Hinshelwood kinetics model fitted well. The optimization was studied using response surface methodology. Scavengers study was carried out to find the active species. Reusability of photocatalyst was evaluated More >

  • Open Access

    ARTICLE

    Chemically deposited cubic SnS photocathodes for photoelectrochemical water splitting

    U. Chalapathia, M. Vasudeva Reddyb,c, C. P. Reddyd, R. Dhanalakshmie, A. Divyaf, K. Mohanarangamg, S. H. Parka,*

    Chalcogenide Letters, Vol.22, No.9, pp. 787-796, 2025, DOI:10.15251/CL.2025.229.787

    Abstract Recently, cubic SnS shows promising potential for optoelectronic applications, including solar cells. Despite its advantages, the photoelectrochemical (PEC) properties of cubic SnS photoelectrodes remain underexplored. This study examines the PEC performance of cubic SnS photocathodes synthesized on FTO substrates via chemical bath deposition and annealed at 250o C for varying durations (10, 20, and 30 min). The as-deposited SnS films, characterized by a cubic crystal structure (lattice parameter: 1.162 nm, crystallite size: 17 nm), an energy gap of 1.75 eV, and an initial photocurrent of 0.8 mA/cm2 at -1 V vs. Hg/HgO, showed significant enhancement More >

  • Open Access

    ARTICLE

    Development of AgCuS nanostructures with optimized photocatalytic efficiency under solar irradiation

    S. Younus, N. Amin*, A. Ali, K. Mahmood

    Chalcogenide Letters, Vol.22, No.10, pp. 905-915, 2025, DOI:10.15251/CL.2025.2210.905

    Abstract Wastewater generated by the textile industry contains high levels of various pollutants. Advanced conventional methods, such as chemical and electrical treatments, are effective in addressing these contaminants. However, the significant operational and capital costs associated with these conventional systems limit their accessibility for industrial stakeholders. In contrast, more economically viable methods tend to be less efficient. This study aims to identify a suitable approach for integrating photocatalytic degradation (PCD) with a low-cost method to enhance the cost-effectiveness of wastewater treatment processes in the textile sector. The study utilized silver copper sulfide (AgCuS) nanocomposites as a… More >

  • Open Access

    ARTICLE

    Influence of Nozzle Geometry and Operating Parameters on High-Pressure Water Jets

    Yuxin Wang1, Youjiang Wang2, Jieping Wang2, Chao Zhang1,*, Fanguang Meng3, Linhua Zhang1, Yongxing Song1,*

    FDMP-Fluid Dynamics & Materials Processing, Vol.21, No.11, pp. 2761-2777, 2025, DOI:10.32604/fdmp.2025.072236 - 01 December 2025

    Abstract High-pressure water jet technology has emerged as a highly effective method for removing industrial-scale deposits from pipelines, offering a clean, efficient, and environmentally sustainable alternative to conventional mechanical or chemical cleaning techniques. Among the many parameters influencing its performance, the geometry of the nozzle plays a decisive role in governing jet coherence, impact pressure distribution, and overall cleaning efficiency. In this study, a comprehensive numerical and experimental investigation is conducted to elucidate the influence of nozzle geometry on the behavior of high-pressure water jets. Using Computational Fluid Dynamics (CFD) simulations based on the Volume of… More >

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