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  • Open Access

    ARTICLE

    Characterization and Selection of Microcrystalline Cellulose from Oil Palm Empty Fruit Bunches for Strengthening Hydrogel Films

    Susi Susi1,2,*, Makhmudun Ainuri3,*, Wagiman Wagiman3, Mohammad Affan Fajar Falah3

    Journal of Renewable Materials, Vol.12, No.3, pp. 513-537, 2024, DOI:10.32604/jrm.2024.045586

    Abstract Microcrystalline cellulose (MCC) is one of the cellulose derivatives produced as a result of the depolymerization of a part of cellulose to achieve high crystallinity. When implemented in other polymers, high crystallinity correlates with greater strength and stiffnes, but it can reduce the water-holding capacity. The acid concentration and hydrolysis time will affect the acquisition of crystallinity and water absorption capacity, both of which have significance as properties of hydrogel filler. The study aimed to evaluate the properties and select the MCC generated from varying the proportion of hydrochloric acid (HCl) and the appropriate hydrolysis time as a filler for… More > Graphic Abstract

    Characterization and Selection of Microcrystalline Cellulose from Oil Palm Empty Fruit Bunches for Strengthening Hydrogel Films

  • Open Access

    ARTICLE

    Sulfonated Poly (Ether Ether Ketone) and its Blended Nanocomposite for Proton Conducting Membranes

    ABDUL KALAM AZAD1, ARVIND GUPTA3, LAKSHMI UNNIKRISHNAN2,3,*, SMITA MOHANTY3, SANJAY KUMAR NAYAK2,3

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 121-136, 2021, DOI:10.32381/JPM.2021.38.1-2.10

    Abstract Proton conducting hydrophilic channels were created successfully in poly (ether ether ketone) (PEEK) by means of step by step modification followed by the optimization of sulfonation process (SPEEK70, DS=68.57%). Although highly sulfonated PEEK has excellent proton conductivity, it lacks in mechanical stability due to low swelling degree. Therefore, a potential method has been proposed in this work by integrating poly (sulfone) and nanosilica (SiO2 ) into SPEEK matrix. SPEEK 70 (S) was utilized to prepare blended nanocomposite membranes for further enhancement of hydrophilic channels. The blended nanocomposite membranes are, SPEEK/SiO2 as SNS, SPEEK blended with poly (sulfone) as SP, SPEEK… More >

  • Open Access

    ARTICLE

    Glass/Biofibers/Epoxy Methacrylate of Bisphenol-C Sandwich Composites: Comparative Mechanical and Electrical Properties and Chemical Resistance

    RITESH D. BHATT, JIGNESH P. PATEL, P. H. PARSANIA*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 71-87, 2021, DOI:10.32381/JPM.2021.38.1-2.7

    Abstract Glass/Biofibers/Epoxy methacrylate of bisphenol-C (G/BF/EBCMAS) sandwich composites was prepared by compression molding. G/BF/EBCMAS showed good mechanical and good to excellent electrical properties and excellent chemical resistance. Studied properties are compared with EBCMAS and G/EBCMAS. In comparison with G/EBCMAS, G/BF/EBCMAS showed considerable decline of tensile strength (18-63.4%), flexural strength (18.8-38.7%), flexural modulus (12.8-50.7%), Izod impact strength (17.4-43.5%), Barcol hardness (2.1-16.7%) and dielectric strength (23.8-76.8%) except flexural strength of G/BM/EBCMAS. G/WC/EBCMAS (96.7%), G/B/EBCMAS (79.2%), G/GN/EBCMAS (83.3%) and G/RH/EBCMAS (97.9%) showed decline of volume resistivity, whereas other sandwich composites showed 1150-58233% improvement. The decrease in mechanical properties and dielectric strength of G/BF/EBCMAS sandwich… More >

  • Open Access

    ARTICLE

    Effects of PEG200 on the Properties and Performance of PVDF Membranes in the Separation of MethanolWater Mixtures by Pervaporation

    DIPESHKUMAR D. KACHHADIYA, Z.V.P. MURTHY*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 49-61, 2021, DOI:10.32381/JPM.2021.38.1-2.5

    Abstract The conventional process for methanol-water separation like distillation consumes about 60 % of total energy. As an alternative, researchers have developed a membrane-based separation process for alcohol-water mixtures separation. However, there is a big challenge for researches to separate alcohol-water aqueous mixtures using a polymeric membrane because of swelling. In the present work, the aim is to separate methanol from water by pervaporation using polymeric membranes made up of polyvinylidenefluroide (PVDF) and polyethylene glycol (PEG200) modified PVDF membranes. The membranes were characterized by thermogravimetry analysis (TGA), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FTIR). A study on… More >

  • Open Access

    ARTICLE

    Recovery of Pure Water, Salicylic Acid Crystals, and Paracetamol using PVDF-MWCNT Membranes by Membrane Distillation-crystallization

    NIKHIL R. MENE1, SARITA KALLA1,*, Z.V.P. MURTHY1,*

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 307-323, 2022, DOI:10.32381/JPM.2022.39.3-4.9

    Abstract Membrane distillation-crystallization (MDC) is presented as a novel technique in the treatment of waste concentrated water which produces valuable crystals along with pure water. In the present study, multi-walled carbon nanotubes (MWCNT)/polyvinylidene fluoride (PVDF) flat sheet membranes were prepared via the wet phase inversion method and applied in MDC for the treatment of pharmaceutical waste. The pure and modified membrane surface properties are characterized with the help of SEM, FTIR, and contact angle measurement. The present work reported the effect of MWCNT content and feed temperature on the MDCperformance and measured pure water flux and pharmaceutical compounds recovery. The observed… More >

  • Open Access

    ARTICLE

    Fabrication and Comparative Properties of Sustainable Epoxy Methacrylate of Bisphenol-C-Jute/Treated JuteNatural Fibers Sandwich Composites: Part-2

    RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA*

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 223-239, 2022, DOI:10.32381/JPM.2022.39.3-4.4

    Abstract Compression-molded epoxy methacrylate of bisphenol-C-jute/treated jute-banana/groundnut/ cane sugar/pineapple leaf/rice husk/wheat husk sandwich composites were fabricated under 5 MPa pressure at room temperature for 3 h. Alkali treated jute-natural fiber sandwich composites displayed considerably improved mechanical properties over untreated jute-natural fiber sandwich composites due to surface modification of the jute fibers. Both types of sandwich composites showed high water uptake tendency, excellent hydrolytic stability against acids, alkali, and salt solutions, and also a longer equilibrium time at 30o C. Alkali treated sandwich composites revealed a considerably lower water uptake tendency than untreated sandwich composites. Observed water uptake trend is H2 SO4More >

  • Open Access

    ARTICLE

    Fabrication and Comparative Properties of Sustainable Epoxy Methacrylate of Bisphenol-C-Jute/Treated JuteNatural Fibers Sandwich Composites: Part-1

    RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA*

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 205-221, 2022, DOI:10.32381/JPM.2022.39.3-4.3

    Abstract Epoxy methacrylate of bisphenol-C-jute/treated jute and their sandwich composites of white coir, brown coir, wild almond, bamboo, betel nut, and palmyra were prepared by a compression molding technique under 5MPa pressure and at room temperature for three h. The neat sample showed almost double tensile strength than its jute composite, while it is comparable for treated jute. The composites revealed substantially improved flexural strength compared to neat. The neat, jute/treated jute and their sandwich composites indicated good impact strength, pretty good Barcol hardness, and fairly good electric strength. The neat sample showed excellent volume resistivity, while jute/treated jute and their… More >

  • Open Access

    ARTICLE

    Effect of Tetramethylurea (TMU) on Polysulfone Membrane Performance for Atrazine-containing Wastewater Treatment

    NIKITA GUPTA, SARITA KALLA, Z.V.P. MURTHY*

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 317-328, 2023, DOI:10.32381/JPM.2023.40.3-4.12

    Abstract Tetramethylurea (TMU) is a good solvent for organic substances and has received little attention as compared to other solvents. The TMU is a polar solution and is one of the molecules with an amphiphilic character. In the present work, an attempt has been made to use TMU as an additive in the preparation of nanofiltration membranes to improve the hydrophilicity of the membrane. The polysulfone membrane has been modified by incorporating different concentrations of TMU (0, 0.5, and 1 wt.%) in order to check the rejection of atrazine in water. This study aim is to optimize the conditions to enhance… More >

  • Open Access

    ARTICLE

    Synthesis and Characterization of Bisphenol-C Epoxy Crotonate and Its Fiber-Reinforced Composites

    PARSOTAM H. PARSANIA1,*, JIGNESH V. PATEL2, JIGNESH P. PATEL3

    Journal of Polymer Materials, Vol.40, No.3-4, pp. 271-284, 2023, DOI:10.32381/JPM.2023.40.3-4.9

    Abstract Bisphenol-C epoxy crotonate resin was synthesized by reacting 8.09g epoxy resin of bisphenolC, and 2.15g crotonic acid using 25 mL 1,4-dioxane as a solvent, and 1 mL triethylamine as a catalyst at reflux temperature for 1-6 h. Solid epoxy crotonate (ECCR) is highly soluble in common organic solvents. ECCR was characterized by its acid (24.5-1.5 mg KOH/g) and hydroxyl (504.5-678.4 mg KOH/g) values. The structure of ECCR is supported by FTIR and 1 HNMR spectroscopic methods. A DSC endothermic transition at 229o C indicated melting followed by thermal polymerization of ECCR. ECCR is thermally stable up to 320o C and… More >

  • Open Access

    ARTICLE

    SiRAP2-12, a Positive Regulatory Factor, Effectively Improves the Waterlogging Tolerance of Foxtail Millet (Setaria italica)

    Xueyan Xia1,#, Xiaohong Fu2,#, Yu Zhao1, Jihan Cui1, Nuoya Xiao1, Jingxin Wang1, Yiwei Lu1, Meihong Huang1, Cheng Chu1, Jia Zhang2, Mengxin Yang2, Shunguo Li1,*, Jianfeng Liu2,*

    Phyton-International Journal of Experimental Botany, Vol.93, No.3, pp. 445-465, 2024, DOI:10.32604/phyton.2024.048273

    Abstract Foxtail millet (Setaria italica) growth was inhibited because of waterlogging stress, which has caused yield reduction. ERF family plays an important role to plant adversity tolerance. In our study, we obtained 19,819 differential expressed genes (DEGs) between the two treatments based on the RNA-seq sequencing of foxtail millet of waterlogging stress. Furthermore, a total of 28 ERF family members were obtained, which have a complete open reading frame. We studied the evolution and function of SiERF family and how they affected the waterlogging tolerance. It was found that SiERF1A/B/C (GenBank ID: OR775217, OR775219, OR775218) and SiRAP2-12 (GenBank ID: OR775216) have… More >

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