NORHABIBAH MOHAMAD^1,*, NOORDINI M. SALLEH^1,2, HABIBUN NABI MUHAMMAD EKRAMUL MAHMUD¹

Journal of Polymer Materials, Vol.40, No.3-4, pp. 165-189, 2023, DOI:10.32381/JPM.2023.40.3-4.4

Abstract The present study has explored the adsorption properties of polypyrrole-based adsorbents (polypyrrole and polypyrrole-polyethyleneimine composite) as novel conducting polymers in adsorbing methyl orange (MO) (an anionic dye) effectively from aqueous solution. The adsorption characteristics of the prepared polymer-based adsorbents were characterized by BET, FTIR, FESEM, and XRD methods. The effectiveness of PPy-based adsorbents for MO dye adsorption was examined using the batch adsorption method. Different parameters were changed during the adsorption process, including contact time, solution pH, and adsorbent dosage. The highest BET surface area of the PPy-PEI composite was found to be 11.85 m² /g,… More >

LIJUN CHEN^*, ZHEQING GONG, ZHENGRONG FU

Journal of Polymer Materials, Vol.40, No.3-4, pp. 157-164, 2023, DOI:10.32381/JPM.2023.40.3-4.3

Abstract The organic fluorine modified/containing cationic acrylic resin is prepared via solution polymerization technique using hexafluorobutyl methacrylate (HFMA) along with butyl acrylate (BA), methyl methacrylate (MMA), styrene (St), dimethylaminoethyl methacrylate (DMAEMA) and hydroxy propyl methacrylate (HPMA) as the comonomers, proprylene glycol monomethyl ether (PGME) as the solvent, and 2, 2-Azo-bis-iso-butyronitrile (AIBN) as the initiator. The synthesized resin in which fluorine atom is introduced into the polymer chains. The cathodic electrodeposition (CED) coatings were prepared by mixing the synthesized resin and blocked isocyanate. The influence of the amount of organic fluorine on the resin and the resultant More >

ARUN KUMAR M, JAYAKUMARI LS^*, RAMJI CHANDRAN

Journal of Polymer Materials, Vol.40, No.3-4, pp. 141-156, 2023, DOI:10.32381/JPM.2023.40.3-4.2

Abstract Nanocomposites are very important materials because it imparts superior properties than other composites with low level of filler loading. Styrene butadiene rubber (SBR) is a non-polar rubber which acts as an insulator and has low electrical conductivity. Graphene platelet nano-powder from 0.1 to 1.25 phr level is incorporated into SBR rubber in order to improve the electrical properties. Comparative studies on electrical and mechanical properties of styrene butadiene rubber with graphene platelet nano-powder (GPN) by varying the filler content are made. The incorporation of Graphene platelet nano-powder increases the electrical conductivity in styrene butadiene rubber. More >

RABIRANJAN MURMU^a,b, DEBASHIS ROY^a, HAREKRUSHNA SUTAR^b

Journal of Polymer Materials, Vol.40, No.3-4, pp. 125-139, 2023, DOI:10.32381/JPM.2023.40.3-4.1

Abstract A one dimensional isothermal model is proposed by modelling the kinetics of methanol transport at anode flow channel (AFC), membrane and cathode catalyst layer of direct methanol fuel cell (DMFC). Analytical model is proposed to predict methanol cross-over rate through the electrolyte membrane and cell performance. The model presented in this paper considered methanol diffusion and electrochemical oxidation at the anode and cathode channels. The analytical solution of the proposed model was simulated in a MATLAB environment to obtain the polarization curve and leakage current. The effect of methanol concentration on cell voltage and leakage More >

DIBYENDU S. BAG^*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (T_g ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The T_g increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically More >

HADIMANI SHIVAKUMAR¹, GURUMURTHY G. D.¹, BOMMEGOWDA K. B.², S. PARAMESHWARA³

Journal of Polymer Materials, Vol.40, No.1-2, pp. 93-103, 2023, DOI:10.32381/JPM.2023.40.1-2.8

Abstract Polymer composites are increasing in demand in energy storage applications including in the electronic as well as electrical industries due to the ease of processing of these materials with associated advantages like light weight, corrosion resistance, and high mechanical strength. In this investigation, efforts are made to enhance the charging and discharging properties of epoxy/carbon fabric composite by the addition of graphene nanoplatelets (GNPs) into the epoxy/ carbon matrix. The performance of the composites with graphene platelets of 0.5 to 5 wt. % in epoxy were characterized and 1wt.% percolation threshold was observed poor performance… More >

S. ARULMURUGAN^a,*, N. VENKATESHWARAN^a, S. KUMAR^a, P. CHANDRASEKAR^a

Journal of Polymer Materials, Vol.40, No.1-2, pp. 83-91, 2023, DOI:10.32381/JPM.2023.40.1-2.7

Abstract In this research, the effect of UV light on the mechanical properties of jute polymer nanocomposites was evaluated. Due to the fact that photodegradation is a surface process and is confined to the degradation of the mechanical characteristics of polyester resin, this study focuses on the resin quality. Therefore, test samples comprised of fibre-reinforced polyester nanoclay composites were fabricated different weight ratios of nanoclay. They were put through UV exposure in an Ultraviolet (UV) chamber. Tensile testing samples were made in accordance with ASTMD638 and had a minimum thickness of 3 mm. Additionally, specimens for… More >

B. BRAILSON MANSINGH¹, K. L. NARASIMHAMU², K. C. VARAPRASAD³, J. S. BINOJ^4,*, A. RADHAKRISHNAN⁵, ALAMRY ALI⁶

Journal of Polymer Materials, Vol.40, No.1-2, pp. 71-82, 2023, DOI:10.32381/JPM.2023.40.1-2.6

Abstract Several agro-wastes are rich in natural fibers and finds scope to be used as reinforcement in composite industry. These natural fibers have some advantages over man-made fibers, including low cost, light weight, renewable nature, high specific strength and modulus, and availability in various forms worldwide. In this paper, the effect of surface modification of leaf sheath coconut fiber (LSF) (an agro-waste) reinforced in phenol formaldehyde matrix composites with silicon carbide (SiC) nano particles as filler material were investigated for its mechanical characteristics. The investigation portrays that coconut LSF (CLSF) modified with potassium permanganate reinforced polymer More >

FOUED KHOFFI^1,*, OMAR HARZALLAH², JEAN YVES DREAN²

Journal of Polymer Materials, Vol.40, No.1-2, pp. 59-69, 2023, DOI:10.32381/JPM.2023.40.1-2.5

Abstract The aim of this study is to analyze the interfacial and the frictional properties of copper (Cu) reinforced polyethylene terephthalate (PET) filament. This Cu-Embedded PET filament will be used as an information transmitter. This filament was prepared by a co-extrusion process. Mechanical properties of these filaments have been quantified by tensile and pull-out analyses. It is shown that the mechanical properties of composite filament were improved by adding the copper filament (from 0.82 to 1.2 GPa). The results of the pull-out test revealed some adhesion between the copper and the PET despite the existence of More >

CONGHUI XU, ZHEQING GONG, XIAOLONG CHEN, LIJUN CHEN^*

Journal of Polymer Materials, Vol.40, No.1-2, pp. 47-58, 2023, DOI:10.32381/JPM.2023.40.1-2.4

Abstract The self-crosslinking polyacrylate latex was prepared via the semi-continuous seed emulsion polymerization technology that methyl methacrylate(MMA) and butyl acrylate (BA)were used as the main monomers and hexafluorobutyl methacrylate (HFMA) and monobutylitaconate (MBI) were used as the modified monomers and glycidyl methacrylate (GMA) was used as the crosslinked monomer which were emulsified with the environmentally friendly mixed surfactant of the isomeric triethylene (9) ether (E-1309) and the lauryl polyoxyethylene ether sulfosuccinate disodium salt (MES-30). The resultant latex and its film is characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), laser particle sizer, contact More >