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  • Open Access

    ARTICLE

    Fabrication of UV–Curing Linalool–Polysiloxane Hybrid Films with High Refractive Index and Transparency

    Wenqing Xiao1,#, Lewen Tan1,2,#, Xunjun Chen1,*, Qiaoguang Li1,*, Yunqing Ruan1

    Journal of Renewable Materials, Vol.12, No.3, pp. 569-583, 2024, DOI:10.32604/jrm.2023.046662

    Abstract

    In this article, a series of high refractive indices (1.50–1.53) thiol phenyl polysiloxane (TPS) were synthesized via hydrolytic sol–gel reaction. The Fourier transform infrared spectra (FT–IR) and nuclear magnetic resonance spectra (NMR) results showed that TPS conformed to the predicted structures. Natural terpene linalool was exploited as photocrosslinker to fabricate UV–curing linalool–polysiloxane hybrid films (LPH) with TPS via photoinitiated thiol–ene reaction. LPH rapidly cured under UV irradiation at the intensity of 80 mW/cm2 in 30 s, exhibiting good UV–curing properties. The optical transmittance of LPH in the wavelength of 300–800 nm was over 90%, exhibiting good optical transparency. The water… More >

  • Open Access

    ARTICLE

    Fabrication of Microspherical Catalyst with Hierarchical Porous Structure from Functional Monomers via Low-Temperature Phase-Separation Photopolymerization

    KEMIN WANG, LIFEI HE

    Journal of Polymer Materials, Vol.36, No.3, pp. 253-260, 2019, DOI:10.32381/JPM.2019.36.03.5

    Abstract This study proposes a simple approach for the fabrication of microspherical catalysts with a hierarchical porous structure. The cross-linked porous microspheres with catalytic ability were prepared directly from small-molecular monomers via low-temperature phase-separation photopolymerization of water/oil suspension. The morphology, pore size, chemical structure, and thermal stability of the obtained porous microspheres were characterized by SEM, Mercury Intrusion Porosimetry, FTIR, and TGA. The porous microspheres directly served as an acid catalyst for the condensation reaction of benzaldehyde and ethylene glycol, which exhibited superior catalytic activity and recyclability. The results indicated that such porous microspheres have great potential in the application of… More >

  • Open Access

    ARTICLE

    Fabrication and Comparative Properties of Sustainable Epoxy Methacrylate of Bisphenol-C-Jute/Treated JuteNatural Fibers Sandwich Composites: Part-2

    RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA*

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 223-239, 2022, DOI:10.32381/JPM.2022.39.3-4.4

    Abstract Compression-molded epoxy methacrylate of bisphenol-C-jute/treated jute-banana/groundnut/ cane sugar/pineapple leaf/rice husk/wheat husk sandwich composites were fabricated under 5 MPa pressure at room temperature for 3 h. Alkali treated jute-natural fiber sandwich composites displayed considerably improved mechanical properties over untreated jute-natural fiber sandwich composites due to surface modification of the jute fibers. Both types of sandwich composites showed high water uptake tendency, excellent hydrolytic stability against acids, alkali, and salt solutions, and also a longer equilibrium time at 30o C. Alkali treated sandwich composites revealed a considerably lower water uptake tendency than untreated sandwich composites. Observed water uptake trend is H2 SO4More >

  • Open Access

    ARTICLE

    Fabrication and Comparative Properties of Sustainable Epoxy Methacrylate of Bisphenol-C-Jute/Treated JuteNatural Fibers Sandwich Composites: Part-1

    RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA*

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 205-221, 2022, DOI:10.32381/JPM.2022.39.3-4.3

    Abstract Epoxy methacrylate of bisphenol-C-jute/treated jute and their sandwich composites of white coir, brown coir, wild almond, bamboo, betel nut, and palmyra were prepared by a compression molding technique under 5MPa pressure and at room temperature for three h. The neat sample showed almost double tensile strength than its jute composite, while it is comparable for treated jute. The composites revealed substantially improved flexural strength compared to neat. The neat, jute/treated jute and their sandwich composites indicated good impact strength, pretty good Barcol hardness, and fairly good electric strength. The neat sample showed excellent volume resistivity, while jute/treated jute and their… More >

  • Open Access

    ARTICLE

    Fabrication and Comparative Properties of Sustainable Epoxy Methacrylate of Bisphenol-C-Jute/Treated JuteNatural Fibers Sandwich Composites: Part-II

    RITESH D. BHATT, JIGNESH P. PATEL, PARSOTAM H. PARSANIA*

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 37-53, 2022, DOI:10.32381/JPM.2022.39.1-2.3

    Abstract Compression-molded epoxy methacrylate of bisphenol-C-jute/treated jute-banana/groundnut/ cane sugar/pineapple leaf/rice husk/wheat husk sandwich composites were fabricated under 5 MPa pressure at room temperature for 3 h. Alkali treated jute-natural fiber sandwich composites displayed considerably improved mechanical properties over untreated jute-natural fiber sandwich composites due to surface modification of the jute fibers. Both types of sandwich composites showed high water uptake tendency, excellent hydrolytic stability against acids, alkali, and salt solutions, and also a longer equilibrium time at 30o C. Alkali treated sandwich composites revealed a considerably lower water uptake tendency than untreated sandwich composites. Observed water uptake trend is H2 SO4More >

  • Open Access

    ARTICLE

    Effect of Different Etching Time on Fabrication of an Optoelectronic Device Based on GaN/Psi

    Haneen D. Jabbar1,*, Makram A. Fakhri1,*, Mohammed Jalal Abdul Razzaq1, Omar S. Dahham2,3, Evan T. Salim4, Forat H. Alsultany5, U. Hashim6

    Journal of Renewable Materials, Vol.11, No.3, pp. 1101-1122, 2023, DOI:10.32604/jrm.2023.023698

    Abstract Gallium nitride (GaN)/porous silicon (PSi) film was prepared using a pulsed laser deposition method and 1064 nm Nd: YAG laser for optoelectronic applications and a series of Psi substrates were fabricated using a photoelectrochemical etching method assisted by laser at different etching times for 2.5–15 min at 2.5 min intervals. X-ray diffraction, room-temperature photoluminescence, atomic force microscopy and field emission scanning electron microscopy images, and electrical characteristics in the prepared GaN on the Psi film were investigated. The optimum Psi substrate was obtained under the following conditions: 10 min, 10 mA/cm2, and 24% hydrofluoric acid. The substrate exhibited two highly cubic crystalline structures at (200)… More >

  • Open Access

    REVIEW

    Recent Progress of Fabrication, Characterization, and Applications of Anodic Aluminum Oxide (AAO) Membrane: A Review

    Saher Manzoor1, Muhammad Waseem Ashraf1,*, Shahzadi Tayyaba2, Muhammad Imran Tariq3,*, M. Khalid Hossain4

    CMES-Computer Modeling in Engineering & Sciences, Vol.135, No.2, pp. 1007-1052, 2023, DOI:10.32604/cmes.2022.022093

    Abstract The progress of membrane technology with the development of membranes with controlled parameters led to porous membranes. These membranes can be formed using different methods and have numerous applications in science and technology. Anodization of aluminum in this aspect is an electro-synthetic process that changes the surface of the metal through oxidation to deliver an anodic oxide layer. This process results in a self-coordinated, exceptional cluster of round and hollow formed pores with controllable pore widths, periodicity, and thickness. Categorization in barrier type and porous type films, and different methods for the preparation of membranes, have been discussed. After the… More > Graphic Abstract

    Recent Progress of Fabrication, Characterization, and Applications of Anodic Aluminum Oxide (AAO) Membrane: A Review

  • Open Access

    REVIEW

    Fabrication and Modification Strategies of Metal Halide Perovskite Absorbers

    Xueyuan Wei, Yang Bai*, Qi Chen*

    Journal of Renewable Materials, Vol.11, No.1, pp. 61-77, 2023, DOI:10.32604/jrm.2023.022773

    Abstract Due to the long carrier lifetime, high carrier mobility, and high absorption coefficient of perovskite materials, the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has increased from 3.8% in 2009 to 25.7% in 2021, which have already surpassed the PCE of thin-film solar cells and closes to the efficiency of Si-based photovoltaics (26.7%). Therefore, PSCs have become a promising clean energy technology for commercialization. However, the low defect formation energy of perovskite leads to a higher defect density than other conventional photovoltaic materials. It results in severe non-radiative recombination, limiting its further development and the commercialization. In this… More > Graphic Abstract

    Fabrication and Modification Strategies of Metal Halide Perovskite Absorbers

  • Open Access

    ARTICLE

    Fabrication of High Toughness Silk Fibroin/Tungsten Disulfide Nanoparticles Hybrid Fiber and Self-Heating Textile by Wet Spinning

    Jianjun Guo1,2, Lingling Jia3, Sandra Senyo Fometu4, Qiang Ma5, Jinjin Wang1, Hang Li1, Lei Jiang5, Guohua Wu1,*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3373-3389, 2022, DOI:10.32604/jrm.2022.021087

    Abstract Traditionally, silkworm silk has been used to make high-quality textiles. Nevertheless, various wastes from silkworm silk textiles that are no longer used are increasing, which is also causing considerable waste and contamination. This issue is causing widespread concern in countries that use more silk. Regenerated silk fibroin (RSF) fibers have been shown to be fragile and tender, which prohibits RSF from being widely used as a structural component. Therefore, enriching the function of silk and enhancing the RSF mechanical properties are important directions to expand the comprehensive utilization of silk products. In the present research, wet spinning was used to… More >

  • Open Access

    ARTICLE

    Pulse Laser Deposition of HfO2 Nanoporous-Like Structure, Physical Properties for Device Fabrication

    Shams B. Ali1, Sarmad Fawzi Hamza Alhasan1, Evan T. Salim2,*, Forat H. Alsultany3, Omar S. Dahham4,5

    Journal of Renewable Materials, Vol.10, No.11, pp. 2819-2834, 2022, DOI:10.32604/jrm.2022.021609

    Abstract The pulsed laser deposition (PLD) technology was used to effectively create conductive nano and micro hafnium oxide with great purity and transparency for (HfO2) nanofilms. In many optoelectronics devices and their applications, the presence of a high dielectric substance like a nano HfO2, between the metal contacts and the substrates was critical. We used the Pulsed Laser Deposition method to fabricate an Al/HfO2/p-Si Schottky barrier diode where the nanostructured HfO2 films as an intermediate layer and varied substrate temperatures. The optical result reveals a high degree of transparency (93%). The optical bandgap of deposited HfO2 films was observed to vary… More >

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