Jaša Saražin¹, Antonio Pizzi², Siham Amirou², Detlef Schmiedl³, Milan Šernek^1,*

Journal of Renewable Materials, Vol.9, No.5, pp. 881-907, 2021, DOI:10.32604/jrm.2021.015047

Abstract A non-isocyanate-based polyurethane (NIPU) wood adhesive was produced from organosolv lignin, which is a bio-sourced raw material, available in large quantities and produced as a by-product of the paper industry. The formulation of this new lignin-based NIPU adhesive, which is presented, was chemically characterised by Matrix-Assisted Laser Desorption Ionization Time of Flight (MALDI ToF) mass spectrometry and by Fourier Transform Infra-Red (FTIR) spectrometry analyses. The oligomers formed were determined and showed that the three species involved in the NIPU adhesive preparation were formed by the co-reaction of the three reagents used: lignin, dimethyl carbonate, and hexamethylene diamine. Linear and branched… More >

Qian Wang^1,#,*, Zhaozhao Liu^1,2,#,*, Xiumei Zhong¹, Zhongnan Gao¹, Fuqiang Liu²

Journal of Renewable Materials, Vol.9, No.3, pp. 523-540, 2021, DOI:10.32604/jrm.2021.014114

Abstract To effectively improve the poor engineering properties of loess and enhance its seismic performance, the industrial by-product lignin is used as a modified material. Based on lots of dynamic triaxial tests, the dynamic elastic modulus and damping ratio of lignin-modified loess were tested. The effects of lignin content on the dynamic elastic modulus and damping ratio of lignin-modified loess were analyzed. Combined with scanning electron microscopy (SEM) and X-ray diffraction (XRD), the microscopic mechanism of lignin to improve the dynamic properties of loess was studied. The results show that lignin can effectively modify the dynamic deformation of loess under dynamic… More >

Raniyah Wazirali^*

Computer Systems Science and Engineering, Vol.36, No.2, pp. 339-351, 2021, DOI:10.32604/csse.2021.014301

Abstract Vision 2030 requires a new generation of people with a wide variety of abilities, talents, and skills. The adoption of augmented reality (AR) and virtual reality is one possible way to align education with Vision 2030. Immersive technologies like AR are rapidly becoming powerful and versatile enough to be adopted in education to achieve this goal. Technologies such as AR could be beneficial tools to enhance maintainable growth in education. We reviewed the most recent studies in augmented reality to check its appropriateness in aligning with the educational goals of Vision 2030. First, the various definitions, terminologies, and technologies of… More >

Lifen Li¹, Zhigang Wu¹, Xuedong Xi², Baoyu Liu³, Yan Cao³, Hailong Xu³, Yingcheng Hu^4,*

Journal of Renewable Materials, Vol.9, No.2, pp. 219-235, 2021, DOI:10.32604/jrm.2021.012099

Abstract Lignin is an abundant renewable macromolecular material in nature, and degradation of lignin to improve its hydroxyl content is the key to its efficient use. Alkali lignin (AL) was treated with Brønsted acidic deep eutectic solvent (DES) based on choline chloride and p-toluenesulfonic acid at mild reaction temperature, the structure of the lignin before and after degradation, as well as the composition of small molecules of lignin were analyzed in order to investigate the chemical structure changes of lignin with DES treatment, and the degradation mechanism of lignin in this acidic DES was elucidated in this work. FTIR and NMR… More >

Cheng Cheng^1,2,*, Weiwei Sun², Bo Hu³, Guixiang Tao², Chao Peng², Yanjuan Tian⁴, Shujuan Wu^4,5

Journal of Renewable Materials, Vol.8, No.10, pp. 1243-1255, 2020, DOI:10.32604/jrm.2020.012054

Abstract The use of lignin, which is a by-product of the pulp and paper industry, in the development of asphalt binders would contribute to waste reduction, providing environmental, economic, and social benefits. In this study, samples of lignin-modified asphalt binder samples with different content of lignin (3%, 6%, 9%, 12%, and 15%) and unmodified asphalt (control) were tested using Fourier transform infrared spectroscopy (FTIR), dynamic shear rheometer (DSR), and thermogravimetry. The mechanism and effectiveness of lignin in improving the thermal stability of asphalt at high temperatures were analyzed. The FTIR analysis shows that no new characteristic absorption peak is seen in… More >

Marion Thébault¹, Ya Li¹, Christopher Beuc¹, Stephan Frömel-Frybort^1,2, Edith-Martha Zikulnig-Rusch¹, Larysa Kutuzova³, Andreas Kandelbauer^3,*

Journal of Renewable Materials, Vol.8, No.10, pp. 1181-1198, 2020, DOI:10.32604/jrm.2020.09755

Abstract High Pressure Laminates (HPL) panels consist of stacks of self-gluing paper sheets soaked with phenol-formaldehyde (PF) resins. An important requirement for such PFs is that they must rapidly penetrate and saturate the paper pores. Partially substituting phenol with bio-based phenolic chemicals like lignin changes the physico-chemical properties of the resin and affects its ability to penetrate the paper. In this study, PF formulations containing different proportions of lignosulfonate and kraft lignin were used to prepare paper-based laminates. The penetration of a Kraft paper sheet was characterized by a recently introduced, new device measuring the conductivity between both sides of the… More >

Ningning Wang¹, Caili Zhang^1,2,*, Wenqin Zhu³, Yunxuan Weng^1,2,*

Journal of Renewable Materials, Vol.8, No.9, pp. 1139-1149, 2020, DOI:10.32604/jrm.2020.09961

Abstract To clarify the effects of lignin as a biodegradable filler added into the PLA matrix, PLA/lignin composites with or without silane coupling agent of γ- (2,3-epoxypropoxy)propy trimethoxysilane (KH560) were prepared by a one-step solvent-free modification method. The effects of KH560 as a compatibilizer on the morphology, chemical structure, crystallization behavior, thermal degradative behavior as well as mechanical strength of the PLA/lignin composites were analyzed in detail. It was found that, after modification by KH560, the fractured surfaces of composites became smooth, suggested sufficient bonding between the lignin and PLA in the composites with KH560 coupling agent molecules. This result further… More >

Plínio B. Mundim¹, Rondinele A. R. Ferreira¹, Leila A. C. Motta¹, Mariana A. Henrique², Daniel Pasquini^2,*

Journal of Renewable Materials, Vol.8, No.8, pp. 891-903, 2020, DOI:10.32604/jrm.2020.010655

Abstract The objective of this work was to evaluate different superficial treatments of sisal fibres employing lignin, and their use as a reinforcement agent in cementitious composites. The treatments consisted of superficially impregnating sisal fibres (S) with organosolv lignin (LO), organosolv lignin and glutaraldehyde (LOG), Kraft lignin (LK) and Kraft lignin and glutaraldehyde (LKG). The fibre modifications were verified by FTIR-ATR and SEM analyzes, and the presence of lignin on the surface of the fibres was evidenced, confirming the effectiveness of the treatments. The mechanical, thermal (by TGA) and water absorption properties of the fibres before and after the modifications were… More >

Marion Thébault¹, Larysa Kutuzova², Sandra Jury¹, Iris Eicher¹, Edith-Martha Zikulnig-Rusch¹, Andreas Kandelbauer^2,*

Journal of Renewable Materials, Vol.8, No.6, pp. 603-630, 2020, DOI:10.32604/jrm.2020.09616

Abstract Here, the effects of substituting portions of fossil-based phenol in phenol formaldehyde resin by renewable lignin from two different sources are investigated using a factorial screening experimental design. Among the resins consumed by the wood-based industry, phenolics are one of the most important types used for impregnation, coating or gluing purposes. They are prepared by condensing phenol with formaldehyde (PF). One major use of PF is as matrix polymer for decorative laminates in exterior cladding and wet-room applications. Important requirements for such PFs are favorable flow properties (low viscosity), rapid curing behavior (high reactivity) and sufficient self-adhesion capacity (high residual… More >

Galussi AA¹, JA Argüello², MM Cerana², M Maximino³, ME Moya¹

Phyton-International Journal of Experimental Botany, Vol.84, No.1, pp. 163-175, 2015, DOI:10.32604/phyton.2015.84.163

Abstract Seeds of alfalfa (Medicago sativa L.) can exhibit seedcoat imposed dormancy, which produces hard seeds within a seed lot. These seeds do not germinate because they do not imbibe water due to a barrier to water entry in the seed coat. The aim of this work was to analyze the anatomical and chemical characteristics of the testa of alfalfa seeds with respect to water permeability levels. The anatomy of seeds of the cv. Baralfa 85 was studied and structural substances, polyphenols, tannins and cutin present in the testa of seeds of different water permeability levels were determined. The anatomical characteristics… More >