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  • Open Access

    ARTICLE

    Synthesis and characterizations of Cu2MgSnS4 nanoparticles by solvothermal method

    H. Guan*, J. X. Xu, Z. Y. Yang, X. Y. Qian, M. Q. Zhao

    Chalcogenide Letters, Vol.21, No.2, pp. 169-173, 2024, DOI:10.15251/CL.2024.212.169

    Abstract Cu2MgSnS4 (CMTS) nanoparticles are successfully prepared via a solvothermal approach. X-ray diffraction (XRD) and Raman reveal that pure zinc-blende CMTS phase is obtained. Scanning electron microscopy (SEM) shows that CMTS nanoparticles exhibit microsphere structure. The band gap of as-obtained CMTS nanoparticles is calculated to be 1.68eV, indicating a potential candidate for tandem solar cells. The degradation rate of methylene blue (MB) with under visible-light irradiation is about 87%, indicating that CMTS can be useful for effective visible-light photocatalyst. More >

  • Open Access

    ARTICLE

    Comparison of CdS nano films deposited by thermal evaporation and spray pyrolysis techniques

    A. N. Abouelkhira,*, E. R. Shaabanb,c, M. Tag El-Dinea, K. I. Hussaind, I. S. Yahiae

    Chalcogenide Letters, Vol.21, No.2, pp. 161-168, 2024, DOI:10.15251/CL.2024.212.161

    Abstract Cadmium sulfide was prepared by first turning it into a powder, which was then used to evaporate heat to create thin films. Additionally, the spray pyrolysis method was used to produce films of cadmium sulfide. A structural comparison using the crystallize size and lattice parameters. Furthermore for the prepared samples, an analysis of their optical characteristics was conducted through measurements of absorbance, transmission, and reflection, resulting in the determination of the energy gap. More >

  • Open Access

    ARTICLE

    Facile hydrothermal synthesis of a multifunctional copper zinc tin sulfide (CZTS) nanoparticle-coated sepiolite fiber composite: structural characterization and photocatalytic properties

    M. Boonkam, P. Tamdee, P. Tongying*

    Chalcogenide Letters, Vol.21, No.4, pp. 335-342, 2024, DOI:10.15251/CL.2024.214.335

    Abstract This work presents a facile hydrothermal synthesis method for fabricating a multifunctional composite of copper zinc tin sulfide (CZTS) nanoparticles coated onto sepiolite fibers. Morphological analysis confirms the firm attachment of approximately 10 nm CZTS nanoparticles onto the sepiolite surface. Elemental analysis verifies the presence of constituent elements from both CZTS and sepiolite, with a slight deficiency in Cu and an abundance of Zn observed. The compositional formula of CZTS in the composite is estimated as Cu1.93Zn1.05Sn0.98S4.04. Notably, the material exhibits a narrow band gap of 1.5 eV, enabling effective utilization of the entire visible light More >

  • Open Access

    ARTICLE

    Photocatalytic and thermoelectric properties of Cu2SrSnS4 nanoparticles by solvothermal method

    G. Hao*, J. Y. Shen, Y. L. Sun, K. Xu, Y. F. Wang

    Chalcogenide Letters, Vol.21, No.10, pp. 765-770, 2024, DOI:10.15251/CL.2024.2110.765

    Abstract In the present work, flower-like Cu2SrSnS4 (CSTS) sample is successfully prepared by solvothermal method. The XRD and Raman analysis confirm that pure CSTS phase with trigonal structure is obtained. The band gap of as-obtained CSTS naocrystals is estimated to be 1.49eV. The removal of methylene blue (MB) within 100min under simulated solar light irradiation is around 90%, depicting that CSTS is a potential material for effective solar light photocatalytic application. Meanwhile, The Seebeck coefficient and electrical conductivity of CSTS material can reach to 128.57μV•K-1 and 20.35S·m-1 at 675K, respectively, indicating its potential for thermoelectric application. More >

  • Open Access

    ARTICLE

    Structural and impedance analysis of tin-sulphide (SnS) nanoparticles produced with the help of hydrothermal process

    Z. Khana, A. D. Khalidb,*, M. I. Khanc, B. Parveena, Ihab M. Moussad, M. S. Hassane, N.-ur-Rehmanf, A. K. Khanf, S. Mumtazg

    Chalcogenide Letters, Vol.21, No.11, pp. 933-943, 2024, DOI:10.15251/CL.2024.2111.933

    Abstract The three samples of SnS with different molarity 1ml, 0.5ml and 0.25ml were prepared by hydrothermal method. The prepared samples were characterized by XRD, SEM and impedance spectroscopies. XRD confirmed the cubic and orthorhombic structure of SnS. The average size of nanoparticles was noted to be about 12.77 nm, 16.43 nm and 16.44 nm at 140 °C. These nanoparticles were of cubic and orthorhombic forms. Average strain came out to be 0.215, 0.142 and 0.140. This result shows that by changing molarity, crystal structure of SnS can be changed. Crystallite size is increasing with decreasing… More >

  • Open Access

    ARTICLE

    Selenium nanoparticles: effect of autoclave treatment on size, shape, phase and antimicrobial properties

    T. Hesabizadeha, R. Subedia, T. J. Websterb,c,d, G. Guisbiersa,*

    Chalcogenide Letters, Vol.21, No.11, pp. 847-854, 2024, DOI:10.15251/CL.2024.2111.847

    Abstract Amorphous selenium nanoparticles have been synthesized by pulsed laser ablation in liquids. After undergoing a thermal treatment at 121°C for 60 minutes, the amorphous nanoparticles crystallized into trigonal ones. The antimicrobial properties of both amorphous and trigonal nanoparticles have been compared; and the amorphous ones displayed better antibacterial and antifungal properties compared to the trigonal ones. Specifically, Methicillin-resistant Staphylococcus aureus (MRSA), Ampicillin-resistant Escherichia coli, Pseudomonas aeruginosa, Staphylococcus epidermidis, and Candida albicans were almost completely inhibited in the presence of amorphous selenium nanoparticles at 0.025 microgram/ml concentrations after 24 hours of in vitro culture, compared to controls (no nanoparticles). In summary, More >

  • Open Access

    ARTICLE

    Preparation and characterization of the nanoparticles of pure zinc sulfide (ZnS NPs) and doped with silver (ZnS:Ag NPs) by green method using ascorbic acid

    R. A. Ulwali*, N. K. Abbas

    Chalcogenide Letters, Vol.21, No.12, pp. 1011-1020, 2024, DOI:10.15251/CL.2024.2112.1011

    Abstract Pure zinc sulfide nanoparticles and doped with silver (0.5,1,1.5,2.5, and 3.5) % wt. were prepared by green method. The structural properties were studied using X-ray diffraction technology(XRD). The diffraction patterns showed the particles were crystalline and had a zinc-blend structure with different average grain size. The surface topography was investigated by Scanning Electron Microscope (FE-SEM), it was found the shape is spherical and had different nanosized. Chemical purity was studied using Energy Dispersive X-ray Spectroscopy(EDX), the results showed the appearance of basic elements (Zn, S) and silver. The results of Fourier Transform Infrared Spectroscopy(FTIR) showed More >

  • Open Access

    ARTICLE

    Phase transformation and size control of CdS and Fe/CdS nanoparticles prepared by pulsed laser ablation

    A. S. Ahmed*, A. B. Sharba, Q. M. Salman

    Chalcogenide Letters, Vol.21, No.12, pp. 989-999, 2024, DOI:10.15251/CL.2024.2112.989

    Abstract This work presents the synthesis and characterization of Homophase CdS and Heterophase Fe/CdS nanoparticles prepared by pulsed laser ablation (PLA) in water and methanol using nanosecond duration Nd:YAG laser. The morphology, the crystalline state, and the structure of the products were examined by performing SEM, XRD, and FTIR measurements, respectively. The results showed the transformation of the crystalline phase and changing the clustering size of CdS nanoparticles when performing PLA in methanol and water. Fe/CdS Heterojunctions were obtained in both liquids. The presence of Fe nanoparticle imposed another phase transformation and significantly improved the aggregation More >

  • Open Access

    CORRECTION

    CORRECTION: Ameliorative effects of melatonin and zinc oxide nanoparticles treatment against adverse effects of busulfan induced infertility in male albino mice

    AMOURA M. ABOU-EL-NAGA1, SHAKER A. MOUSA2, FAYEZ ALTHOBAITI3, EMAN FAYAD3,*, ENGY S. FAHIM1

    BIOCELL, Vol.48, No.12, pp. 1835-1837, 2024, DOI:10.32604/biocell.2024.054569 - 30 December 2024

    Abstract This article has no abstract. More >

  • Open Access

    REVIEW

    Exploring Metal Based Nanoparticles for Boosting Plant Tolerance to Heavy Metals and Trace Element Contamination

    Abdul Ghafoor1, Maria Latif2, Shafaqat Ali2,3,*, Muhammad Munir4,*, Muhammad Naeem Sattar5, Mohammed Ali Alshehri6

    Phyton-International Journal of Experimental Botany, Vol.93, No.11, pp. 2683-2705, 2024, DOI:10.32604/phyton.2024.055898 - 30 November 2024

    Abstract Heavy metal pollution in agricultural soils is a significant challenge for global food production and human health with the increasing industrialization and urbanization. There is a concern about introducing innovative techniques that are eco-friendly, cost-effective, and have the potential to alleviate metals, enhance crop growth, and protect plants against various environmental threats. For this, nanotechnology is one of the promising solutions having various applications in almost every field of life. This review explores various nano-based strategies that use nanoparticles (NPs) to lessen the harmful effects that heavy metals have on plants. Incorporated literature including published… More >

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