Wenqing Xiao^1,#, Yuhang Liu^2,#, Yuxin He¹, Qiaoguang Li^1,*, Yongquan Li^3,*

Journal of Renewable Materials, Vol.12, No.3, pp. 615-628, 2024, DOI:10.32604/jrm.2023.046780

Abstract Plasticizers are essential additives in the processing of polyvinyl chloride (PVC), with phthalate plasticizers being widely used. However, these conventional plasticizers have been shown to be harmful to human health and environmentally unfriendly, necessitating the exploration of eco-friendly bio-based alternatives. In this study, Camellia oleifera seed oil, a specialty resource in China, was utilized as a raw material and reacted with 4,4′-Methylenebis(N,N-diglycidylaniline) (AG-80) to synthesize Phenyl Camellia seed Oil Ester (PCSOE). PCSOE was employed as a plasticizer to prepare modified PVC films with varying concentrations, with the conventional plasticizer dioctyl phthalate (DOP) serving as a control. Experimental results demonstrate that… More >

KAVITA^*, R.K. TIWARI

Journal of Polymer Materials, Vol.36, No.2, pp. 195-205, 2019, DOI:10.32381/JPM.2019.36.02.7

Abstract The effect of poly (vinyl butyral) and acid functionalized multiwalled carbon nanotubes (f-MWCNT) on the thermal and mechanical performance of Kevlar fiber reinforced novolac epoxy nanocomposites was investigated and presented in this paper. Nanocomposite containing 1.5 wt. % poly (vinyl butyral) and 0.5 wt. % f-MWCNT exhibited best thermal and mechanical properties (except flexural strength) among all the nanocomposites reported here. It showed ~5%, 27% and 126 % improvement in tensile strength, young’s modulus and impact strength respectively as compared to the neat novolac epoxy Kevlar composite.Nanocomposite containing 0.5 wt. % f- MWCNT and 2 wt. % poly (vinyl butyral)… More >

D. MURALI MANOHAR^1,*, B.C. CHAKRABORTY², S. SHAMSHATH BEGUM³

Journal of Polymer Materials, Vol.37, No.1-2, pp. 91-107, 2020, DOI:10.32381/JPM.2020.37.1-2.7

Abstract In search of improved materials for efficient shock and vibration mounts for machineries, graphite loaded NBR and NBR/PVC blend were made and investigated. The scorch time was seen to be reduced and vulcanization rate was enhanced due to graphite inclusion. Scanning electron microscopy images have shown homogenous dispersion of graphite powder. NBRgraphite showed a gradual increase in the hardness, tensile strength, Young’s modulus, and tear values with increasing graphite loading. In the case of NBR/PVC-graphite composition, a drop in the tensile strength and increase in the Young’ modulus and tear strength was observed. Various mathematical models were used to investigate… More >

RAJEEV KUMAR

Journal of Polymer Materials, Vol.37, No.3-4, pp. 131-142, 2020, DOI:10.32381/JPM.2020.37.3-4.2

Abstract The optical, electrical and acoustical properties of a polymer solution based on polyvinyl pyrrolidone (PVP) doped with different concentration of cupric sulphate (CuSO₄ ) were studied.UVVIS spectroscopy results reflected that absorption increases in asymmetric manner and the absorption peak showed red shift with increasing Cu ions concentration. The optical band gap (direct and indirect) was found to decrease with increase in Cu ions concentration in the polymer due to increase in the density of localized states in the band-gap.The value of Urbach energy is also evaluated from the transmission spectra and the activation energies are also evaluated from the conductivity… More >

DIPESHKUMAR D. KACHHADIYA, Z.V.P. MURTHY^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 49-61, 2021, DOI:10.32381/JPM.2021.38.1-2.5

Abstract The conventional process for methanol-water separation like distillation consumes about 60 % of total energy. As an alternative, researchers have developed a membrane-based separation process for alcohol-water mixtures separation. However, there is a big challenge for researches to separate alcohol-water aqueous mixtures using a polymeric membrane because of swelling. In the present work, the aim is to separate methanol from water by pervaporation using polymeric membranes made up of polyvinylidenefluroide (PVDF) and polyethylene glycol (PEG200) modified PVDF membranes. The membranes were characterized by thermogravimetry analysis (TGA), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FTIR). A study on… More >

ASIS K. MANDAL¹, DEBABRATA CHAKRABORTY², MAHUYA DAS³, SAMIR K SIDDHANTA^4,*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 21-34, 2021, DOI:10.32381/JPM.2021.38.1-2.3

Abstract Elastomeric chlorosulfonated polyethylene (Hypalon) and thermoplastic polypropylene (PP) based thermoplastic Vulcanizates (TPVs) were prepared in presence of different doses of partial methyl ester of styrene-maleic anhydride copolymer (PMES-MA) as compatibilizer employing dynamic vulcanization technique. The mechanical analysis of the prepared TPVs exhibited significant improvements in stress at 25% modulus, ultimate tensile strength (UTS), and hardness values. FTIR studies revealed that a chemical interaction had taken place between hypalon and compatibilizer during the process of dynamic vulcanization which led to an enhancement of interfacial adhesion between them. The two-phase morphologies were clearly observed by scanning electron microscopic studies. The Tg values… More >

NIKHIL R. MENE¹, SARITA KALLA^1,*, Z.V.P. MURTHY^1,*

Journal of Polymer Materials, Vol.39, No.3-4, pp. 307-323, 2022, DOI:10.32381/JPM.2022.39.3-4.9

Abstract Membrane distillation-crystallization (MDC) is presented as a novel technique in the treatment of waste concentrated water which produces valuable crystals along with pure water. In the present study, multi-walled carbon nanotubes (MWCNT)/polyvinylidene fluoride (PVDF) flat sheet membranes were prepared via the wet phase inversion method and applied in MDC for the treatment of pharmaceutical waste. The pure and modified membrane surface properties are characterized with the help of SEM, FTIR, and contact angle measurement. The present work reported the effect of MWCNT content and feed temperature on the MDCperformance and measured pure water flux and pharmaceutical compounds recovery. The observed… More >

SOBHA KOTA^*, RATNAKUMARI ANANTHA, VAYUNANDANA RAO GOVADA, PRADEEP DUMPALA

Journal of Polymer Materials, Vol.40, No.3-4, pp. 285-303, 2023, DOI:10.32381/JPM.2023.40.3-4.10

Abstract The exoskeleton of marine shrimp contains a natural, biocompatible polymer chitin, which is dumped as a waste. The study proposes the sustainable single-pot-extraction of chitosan from the waste and its use in the fabrication of wound-dressings, and thus leverage its piezoelectric, antioxidant, hypoglycaemic and medicinal properties in wound-healing. The Fourier transform infrared spectrum revealed that marine chitosan contains functional groups with N-O, O-H, and CO stretching. Scanning electron micrographs demonstrated the spherical and mesoporous structures of the extracted chitosan. X-ray diffraction analysis showed a semi-crystalline phase of chitosan particles with a mean size of 28.9 nm. The film prepared with… More >

RABIRANJAN MURMU^a,b, DEBASHIS ROY^a, HAREKRUSHNA SUTAR^b, PRAGYAN SENAPATI^c, SWETAK ABHISEK MOHAPATRA^b

Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

Zhongping Liu¹, Enhui Sun^2,*, Jiahao Shi², Lei Zhang², Qi Wang¹, Jiali Dong¹

Energy Engineering, Vol.121, No.4, pp. 913-932, 2024, DOI:10.32604/ee.2023.043973

Abstract There is a growing need to explore the potential of coal-fired power plants (CFPPs) to enhance the utilization rate of wind power (wind) and photovoltaic power (PV) in the green energy field. This study developed a load regulation model for a multi-power generation system comprising wind, PV, and coal energy storage using real-world data. The power supply process was divided into eight fundamental load regulation scenarios, elucidating the influence of each scenario on load regulation. Within the framework of the multi-power generation system with the wind (50 MW) and PV (50 MW) alongside a CFPP (330 MW), a lithium-iron phosphate… More > Graphic Abstract