JITENDRA. S. TATE^1,2,*, HARISH KALLAGUNTA^1,2, ANDREW ALVAREZ¹

Journal of Polymer Materials, Vol.38, No.1-2, pp. 101-120, 2021, DOI:10.32381/JPM.2021.38.1-2.9

Abstract The exponential growth in composites and their increased use in military, aerospace, energy, and automotive industry is driven by their high performance and light weight. High performance thermosetting polymers such as cyanate ester have received considerable attention due to its ability of volatile-free curing. It also offers advantages such as excellent radiation shielding, high thermal stability, and hydrophobicity with lots of potential for enhanced mechanical strength. This research article discusses the results of effects of multiwalled carbon nanotubes (MWCNT) at predetermined loading levels of 0.5wt%, 1wt% and 1.5wt% on mechanical, thermal and flammability properties of cyanate ester modified carbon fiber… More >

ANU SINGH AND P.K. DUTTA^*

Journal of Polymer Materials, Vol.38, No.1-2, pp. 63-69, 2021, DOI:10.32381/JPM.2021.38.1-2.6

Abstract The experiment was designed to examine the microsphere of the chitin-glucan complex. We formed a chitin-glucan microsphere (ChGMS) from the spray dryer technique. SEM images observed that shape of ChGMS was spherical. From particle size analyzer and SEM analysis both showed that the size of particles was in the range of 1.5 to 3.5 µm. It showed amorphous nature after the formation of microsphere particles of chitin-glucan. The effect of chitin-glucan complex and ciprofloxacin loaded chitin-glucan microsphere on Bacillus subtilis and Escherichia coli were also tested. Antibacterial analysis was indicating that the ciprofloxacin loaded chitinglucan microsphere strongly inhibited the growth… More >

ELIF ANT BURSALI^1,*, DILER ABACI¹, MURAT KIZIL², MURUVVET YURDAKOC¹

Journal of Polymer Materials, Vol.38, No.3-4, pp. 231-245, 2021, DOI:10.32381/JPM.2021.38.3-4.5

Abstract Genipin cross-linked/boron doped starch/polyvinily alcohol (PVA) based hydrogel (SH-GNP-B) was synthesized as a new material having antimicrobial and antioxidant activity. The prepared hydrogel was characterized by X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Thermal Gravimetric Analysis (TGA) and Scanning Electron Microscope (SEM) methods and evaluated for in vitro antimicrobial activities against selected organisms by disc diffusion tests. The antioxidant activity of the prepared hydrogels was evaluated using 2,2-diphenyl-1- picrylhydrazyl radical scavenging assays. Swelling behavior of the hydrogel was also investigated. The synthesized hydrogel was thermally stable and showed pH independent swelling tendency. SH-GNP-B hydrogel was found to have antimicrobial… More >

A. MADHAN KUMAR¹, K. JAYAKUMAR^2,*, M. SHALINI³

Journal of Polymer Materials, Vol.39, No.3-4, pp. 269-281, 2022, DOI:10.32381/JPM.2022.39.3-4.7

Abstract Polylactic acid (PLA) is the most popular thermoplastic biopolymer providing a stiffness and strength alternative to fossil-based plastics. It is also the most promising biodegradable polymer on the market right now, thus gaining a substitute for conservative artificial polymers. Therefore, the current research focuses on synthesizing and mechanical characterization of particlereinforced PLA composites. The hot compression molding technique was used to fabricate PLA-based composites with 0, 2.5, 5, and 7.5 weight % of sawdust, rice husk, and bagasse particle reinforcements to enhance the performance of the PLA. The pellets of PLA matrix were taken with an average size of 3… More >

RABIRANJAN MURMU^a,b, DEBASHIS ROY^a, HAREKRUSHNA SUTAR^b

Journal of Polymer Materials, Vol.40, No.3-4, pp. 125-139, 2023, DOI:10.32381/JPM.2023.40.3-4.1

Abstract A one dimensional isothermal model is proposed by modelling the kinetics of methanol transport at anode flow channel (AFC), membrane and cathode catalyst layer of direct methanol fuel cell (DMFC). Analytical model is proposed to predict methanol cross-over rate through the electrolyte membrane and cell performance. The model presented in this paper considered methanol diffusion and electrochemical oxidation at the anode and cathode channels. The analytical solution of the proposed model was simulated in a MATLAB environment to obtain the polarization curve and leakage current. The effect of methanol concentration on cell voltage and leakage current is studied. The methanol… More >

RABIRANJAN MURMU^a,b, DEBASHIS ROY^a, HAREKRUSHNA SUTAR^b, PRAGYAN SENAPATI^c, SWETAK ABHISEK MOHAPATRA^b

Journal of Polymer Materials, Vol.39, No.1-2, pp. 89-109, 2022, DOI:10.32381/JPM.2022.39.1-2.6

Abstract In this work, we have successfully cross-linked the different weight ratio of Chitosan-PVA blend with sulfuric acid. The effect of cross-linker on the properties of blends are studied by using different experimental technique. The cross-linked membrane provides higher ion exchange capacity due to the procurement of extra ionic hooping sites in the membrane. The compatibility of the blends are confirmed from the FTIR and DSC analysis. The crosslinking reaction fastening the phase transition behavior of the blends which reduces the glass transition temperature. The highly compatiblized cross-linked blend provides higher tensile strength and lower modulus at moderate temperature. The significant… More >

DIBYENDU S. BAG^*, SHILPI TIWARI, AKANSHA DIXIT, KM. MEENU

Journal of Polymer Materials, Vol.40, No.1-2, pp. 105-123, 2023, DOI:10.32381/JPM.2023.40.1-2.9

Abstract In this paper, we report the microstructural investigation and influence of H-bonding on the thermal behavior e.g., glass transition (T_g ) and thermal degradation of chiral copolymers of (R)- N-(1-phenyl-ethyl) methacrylamide (R-NPEMAM) and 2-hydroxy ethyl methacrylate (HEMA). The T_g increases with the increase of chiral unit content in the copolymers and then attains optimum at around 25 mole % of chiral content. Thereafter it decreases with the increase of chiral content. The effect of copolymer composition and secondary interaction associated with the Hbonding on the thermal properties of these copolymers was also studied. Secondary interaction, specifically H-bonding has been interpreted… More >

HADIMANI SHIVAKUMAR¹, GURUMURTHY G. D.¹, BOMMEGOWDA K. B.², S. PARAMESHWARA³

Journal of Polymer Materials, Vol.40, No.1-2, pp. 93-103, 2023, DOI:10.32381/JPM.2023.40.1-2.8

Abstract Polymer composites are increasing in demand in energy storage applications including in the electronic as well as electrical industries due to the ease of processing of these materials with associated advantages like light weight, corrosion resistance, and high mechanical strength. In this investigation, efforts are made to enhance the charging and discharging properties of epoxy/carbon fabric composite by the addition of graphene nanoplatelets (GNPs) into the epoxy/ carbon matrix. The performance of the composites with graphene platelets of 0.5 to 5 wt. % in epoxy were characterized and 1wt.% percolation threshold was observed poor performance in gravimetric charge and discharge… More >

CONGHUI XU, ZHEQING GONG, XIAOLONG CHEN, LIJUN CHEN^*

Journal of Polymer Materials, Vol.40, No.1-2, pp. 47-58, 2023, DOI:10.32381/JPM.2023.40.1-2.4

Abstract The self-crosslinking polyacrylate latex was prepared via the semi-continuous seed emulsion polymerization technology that methyl methacrylate(MMA) and butyl acrylate (BA)were used as the main monomers and hexafluorobutyl methacrylate (HFMA) and monobutylitaconate (MBI) were used as the modified monomers and glycidyl methacrylate (GMA) was used as the crosslinked monomer which were emulsified with the environmentally friendly mixed surfactant of the isomeric triethylene (9) ether (E-1309) and the lauryl polyoxyethylene ether sulfosuccinate disodium salt (MES-30). The resultant latex and its film is characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), laser particle sizer, contact angle determinator. The comparison of… More >

Ran Wang¹, Aimin Gong^1,*, Shanqing Shao¹, Baoli Qu², Jing Xu³, Fulai Wang¹, Feipeng Liu^3,*

FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.4, pp. 749-769, 2024, DOI:10.32604/fdmp.2023.042566

Abstract The mechanical properties of cementitious sand and gravel damming material have been experimentally determined by means of microscopic SEM (Scanning Electron Microscopy) image analysis. The results show that the combination of fly ash and water can fill the voids in cemented sand and gravel test blocks because of the presence of hydrated calcium silicate and other substances; thereby, the compactness and mechanical properties of these materials can be greatly improved. For every 10 kg/m³ increase in the amount of cementitious material, the density increases by about 2%, and the water content decreases by 0.2%. The amount of cementitious material used… More > Graphic Abstract