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  • Open Access

    ARTICLE

    Thermal-Mechanical Characterization of Polyurethane Rigid Foams: Effect of Modifying Bio-Polyol Content in Isocyanate Prepolymers

    Luis Daniel Mora-Murillo1, Felipe Orozco-Gutierrez2, José Vega-Baudrit2, Rodolfo Jesús González-Paz2*

    Journal of Renewable Materials, Vol.5, No.3-4, pp. 220-230, 2017, DOI:10.7569/JRM.2017.634112

    Abstract Nowadays, green polyurethane (PU) foams are mostly synthesized by replacing an amount of petrochemical polyol with biobased polyol. Here we report five different families of isocyanate prepolymer formulations that were prepared with biobased sources and the correlation between the structure of chains and the properties of the produced PU foam. Foam behavior in tension, torsion, compression, shape memory tests and physical properties were studied by dynamic mechanical thermal analysis (DMTA); interactions in the polymer chains were analyzed by Fourier transform infrared spectroscopy (FTIR); and thermal analysis was performed by thermogravimetry (TGA) and differential scanning calorimetry (DSC). The results showed that… More >

  • Open Access

    ARTICLE

    New Closed- and Open-Cell, Aldehyde-Free Protein Foams

    María Cecilia Basso1*, Antonio Pizzi1,2

    Journal of Renewable Materials, Vol.5, No.1, pp. 48-53, 2017, DOI:10.7569/JRM.2016.634124

    Abstract New aldehyde-free and isocyanate-free biofoams have been obtained by reacting albumin chicken egg white and dimethyl carbonate (DMC). The optimized formulations yielded lightweight foams whose densities were evaluated as 0.016–0.16 g/cm3. Mechanical resistance was 0.023–0.34 MPa and residual pH nearly neutral. The new foams presented up to 57% of closed cells as measured by helium pycnometry and good thermal insulation. These new natural foams are environmentally friendly materials and show very promising properties. More >

  • Open Access

    ARTICLE

    Isocyanate-Free Polyurethanes by Coreaction of Condensed Tannins with Aminated Tannins

    M. Thébault1,2, A. Pizzi13*, F.J. Santiago-Medina1, F.M. Al-Marzouki3, S. Abdalla3

    Journal of Renewable Materials, Vol.5, No.1, pp. 21-29, 2017, DOI:10.7569/JRM.2016.634116

    Abstract Isocyanate-free polyurethane resins biosourced to a very high percentage level were prepared by the reaction of aminated mimosa tannin extract with commercial mimosa tannin extract prereacted with dimethyl carbonate. The reaction took place with ease at ambient temperature. Indications were that the polyurethanes obtained formed a hard film when cured at a temperature higher than 100 °C. Furthermore, the carbohydrate fraction of the tannin extract also appeared to be carbonated and reacted to generate isocyanate-free polyurethane linkages with the aminated tannins. This indicated that not only the polyphenolic fraction of the tannin extract, but also its other major component, can… More >

  • Open Access

    ARTICLE

    Influence of Isocyanate Index on Selected Properties of Flexible Polyurethane Foams Modified with Various Bio-Components

    Aleksander Prociak*, Elźbieta Malewska, Szymon Bąk

    Journal of Renewable Materials, Vol.4, No.1, pp. 78-85, 2016, DOI:10.7569/JRM.2015.634129

    Abstract In this article, the results of the foaming process analysis of fl exible polyurethane with different isocyanate indexes are presented. Two types of flexible polyurethane foams (FPURF) were obtained: (1) by using petrochemical components and a rapeseed-oil-based polyol (used in the amount of 20 wt%), (2) by using petrochemical components and cellulose as a natural fi ller in the amount of 3 php (per hundred parts of polyol). The characteristic parameters of the foaming process, such as the foam’s growth velocity, the core temperature and dielectric polarization, were measured using a Foamat device. Moreover, the following properties of flexible polyurethane… More >

  • Open Access

    ARTICLE

    Alteration of Viscoelastic Properties is Associated with a Change in Cytoskeleton Components of Ageing Chondrocytes from Rabbit Knee Articular Cartilage

    Wangping Duan, Lei Wei, Juntao Zhang, Yongzhuang Hao, Chunjiang Li, Hao Li, Qi Li, Quanyou Zhang, Weiyi Chen, Xiaochun Wei∗,§

    Molecular & Cellular Biomechanics, Vol.8, No.4, pp. 253-274, 2011, DOI:10.3970/mcb.2011.008.253

    Abstract The cytoskeleton network is believed to play an important role in the biomechanical properties of the chondrocyte. Ours and other laboratories have demonstrated that chondrocytes exhibit a viscoelastic solid creep behavior in vitro and that viscoelastic properties decrease in osteoarthritic chondrocytes. In this study, we aimed to understand whether the alteration of viscoelastic properties is associated with changes in cytoskeleton components of ageing chondrocytes from rabbit knee articular cartilage. Three age groups were used for this study: young (2-months-old, N=23), adult (8-months-old, N=23), and old (31-months-old, N=23) rabbit groups. Cartilage structure and proteoglycan and type II collagen content were determined… More >

  • Open Access

    ARTICLE

    Mechanical Stretch-Induced Changes in Cell Morphology and mRNA Expression of Tendon/Ligament-Associated Genes in Rat Bone-Marrow Mesenchymal Stem Cells

    Guanbin Song∗,†,‡, Qing Luo*, Baiyao Xu*, Yang Ju

    Molecular & Cellular Biomechanics, Vol.7, No.3, pp. 165-174, 2010, DOI:10.3970/mcb.2010.007.165

    Abstract It has been demonstrated that mechanical stimulation plays a vital role in regulating the proliferation and differentiation of stem cells. However, little is known about the effects of mechanical stress on tendon/ligament development from mesenchymal stem cells (MSCs). Here, using a custom-made cell-stretching device, we studied the effects of mechanical stretching on the cell morphology and mRNA expression of several key genes modulating tendon/ligament genesis. We demonstrate that bone-marrow-derived rat MSCs (rMSCs), when subjected to cyclic uniaxial stretching, express obvious detectable mRNAs for tenascin C and scleraxis, a unique maker of tendon/ligament formation, and significantly increased levels of type I… More >

  • Open Access

    ARTICLE

    Kinetics Analysis of Binding between Melanoma Cells and Neutrophils

    Meghan H. Hoskins*, Cheng Dong∗,†

    Molecular & Cellular Biomechanics, Vol.3, No.2, pp. 79-88, 2006, DOI:10.3970/mcb.2006.003.079

    Abstract It has been determined previously that polymorphonuclear leukocytes, or PMNs, can facilitate melanoma cell extravasation through the endothelium under shear conditions [1,2]. The interactions between melanoma cells and PMNs are mediated by the β2-integrins expressed by PMNs and intercellular adhesion molecules (ICAM-1) expressed on melanoma cells. In this study, the kinetics of these interactions was studied using a parallel plate flow chamber. The dissociation rates were calculated under low force conditions for ICAM-1 interactions with both β2-integrins, LFA-1 (CD11a/CD18) and Mac-1 (CD11b/CD18), together and separately by using functional blocking antibodies on PMNs. The kinetics of PMNs stimulated with IL-8 was… More >

  • Open Access

    ARTICLE

    Forced Dissociation of Selectin-ligand Complexes Using Steered Molecular Dynamics Simulation

    Shouqin Lü1, Mian Long1,2

    Molecular & Cellular Biomechanics, Vol.2, No.4, pp. 161-178, 2005, DOI:10.3970/mcb.2005.002.161

    Abstract Selectin-ligand interactions are crucial to such biological processes as inflammatory cascade or tumor metastasis. How transient formation and dissociation of selectin-ligand bonds in blood flow are coupled to molecular conformation at atomic level, however, has not been well understood. In this study, steered molecular dynamics (SMD) simulations were used to elucidate the intramolecular and intermolecular conformational evolutions involved in forced dissociation of three selectin-ligand systems: the construct consisting of P-selectin lectin (Lec) and epidermal growth factor (EGF)-like domains (P-LE) interacting with synthesized sulfoglycopeptide or SGP-3, P-LE with sialyl Lewis X (sLeX), and E-LE with sLeX. SMD simulations were based on… More >

  • Open Access

    ARTICLE

    Network Embedding-Based Anomalous Density Searching for Multi-Group Collaborative Fraudsters Detection in Social Media

    Chengzhang Zhu1, 2, Wentao Zhao2, *, Qian Li1, Pan Li2, Qiaobo Da3

    CMC-Computers, Materials & Continua, Vol.60, No.1, pp. 317-333, 2019, DOI:10.32604/cmc.2019.05677

    Abstract Detecting collaborative fraudsters who manipulate opinions in social media is becoming extremely important in order to provide reliable information, in which, however, the diversity in different groups of collaborative fraudsters presents a significant challenge to existing collaborative fraudsters detection methods. These methods often detect collaborative fraudsters as the largest group of users who have the strongest relation with each other in the social media, consequently overlooking the other groups of fraudsters that are with strong user relation yet small group size. This paper introduces a novel network embedding-based framework NEST and its instance BEST to address this issue. NEST detects… More >

  • Open Access

    ARTICLE

    Personalized Privacy Protecting Model in Mobile Social Network

    Pingshui Wang1,*, Zecheng Wang1, Tao Chen1,2, Qinjuan Ma1

    CMC-Computers, Materials & Continua, Vol.59, No.2, pp. 533-546, 2019, DOI:10.32604/cmc.2019.05570

    Abstract With the rapid development of the new generation of information technology, the analysis of mobile social network big data is getting deeper and deeper. At the same time, the risk of privacy disclosure in social network is also very obvious. In this paper, we summarize the main access control model in mobile social network, analyze their contribution and point out their disadvantages. On this basis, a practical privacy policy is defined through authorization model supporting personalized privacy preferences. Experiments have been conducted on synthetic data sets. The result shows that the proposed privacy protecting model could improve the security of… More >

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