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  • Open Access

    ARTICLE

    Microwave–Induced Thermo-Responsive Shape Memory Polyurethane/MWCNTs Composites and Improved their Shape Memory and Mechanical Properties

    KRISHAN KUMAR PATEL, RAJESH PUROHIT

    Journal of Polymer Materials, Vol.36, No.1, pp. 23-37, 2019, DOI:10.32381/JPM.2019.36.01.3

    Abstract Microwave (MV)-induced thermo-responsive shape memory thermoplastic polyurethane (SMTPU)/ MWCNT composites were prepared in micro-compounder. Composites containing different amount of multiwall Carbon nanotube (MWCNT) varying from 0 to 1.5 phr in SMTPU matrix were prepared. Maximum stretching strength, recovery force and tensile strength for 1.5 CNTPU (1.5 phr MWCNT in SMTPU matrix) was increased by 120%, 100% and 24% respectively as compared to SMTPU. MV-induced shape memory is a novel approach for fast, clean and remote heating during operation. MWCNT is strong absorber of microwave irradiation so that SMTPU/ MWCNTs nanocomposites successfully triggered by microwave. More >

  • Open Access

    ARTICLE

    Improved Corrosion Resistance of Carbon Reinforced Aluminium Laminates in Atmospheric Environment: Role of Environment Friendly Jute Fibre/ Alumina nano Coating

    M. VASUMATHI1,a,*, VELA MURALI2,b, S. RASHIA BEGUM1,c, N. RAJENDRAN2,d

    Journal of Polymer Materials, Vol.36, No.1, pp. 1-11, 2019, DOI:10.32381/JPM.2019.36.01.1

    Abstract In the Fibre Metal Laminate (FML), Carbon Reinforced Aluminium laminate (CARALL), aluminium is placed next to carbon fibres. The potential difference between the aluminium and carbon is larger, leads to galvanic corrosion, which tries to bring down the durability of the FML. To bring down the effect of corrosion, a material layer is introduced between fibres and aluminium so as to separate them thus lowering the possibility of occurrence of corrosion. Another approach is to coat the surfaces of aluminium with different proportions of aluminium oxide nano particles prior to fabrication of the FML. For both the cases, corrosion rates… More >

  • Open Access

    ARTICLE

    Synthesis of Novel Nanocomposite Based on Carboxymethylcellulose (CMC), Kaolin and Urea Fertilizer for Controlled Release

    NALINI SHARMA1,*, AJAY SINGH2, RAJ KUMAR DUTTA3

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 1-15, 2020, DOI:10.32381/JPM.2020.37.1-2.1

    Abstract Controlled Release fertilizers (CRFs) are new generation agrochemicals which aid in decreasing environmental pollution. In the present study, novel CRF beads are synthesized by the technique of sol-gel polymerization. CMC polymer at various concentrations was used as a matrix and kaolin was used as a binder to enhance mechanical properties of the beads. The study also reveals the incorporation of Kaolin at different concentrations and optimization of the same. Fe3+ was used as a cross-linker to obtain spherical beads. Also, a study was done to optimize the cross linking time and concentration of cross linking solution. The usage of polymers… More >

  • Open Access

    ARTICLE

    Nanotitanium Dioxide Reinforced High Performance PEI/Silicone Rubber Composites: Mechanical, Thermal and Morphological Characteristics

    R.M. MISHRAA, R. VIJAYVARGIYAA, K.N. PANDEYA, J.S.P. RAIB

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 179-188, 2020, DOI:10.32381/JPM.2020.37.3-4.5

    Abstract The present investigation is targeted to prepare nanocomposites based on binary blends of polyetherimide (PEI)-silicone rubber incorporated with varied loadings of nanotitanium dioxide particles. Nanocomposites have been prepared by melt blending process using twin screw extruder. Thermal properties of the developed nanocomposites have been investigated with the help of thermogravimetric analyzer (TGA) and dynamic mechanical analyzer (DMA). Scanning electron microscopy (SEM) is used to analyze the morphological properties of the nanocomposites. Mechanical properties (tensile strength, tensile modulus, elongation at break, impact strength) of the nanocomposites have been evaluated by universal testing machine (UTM). Mechanical testing results reveal that there is… More >

  • Open Access

    ARTICLE

    Synergistic Effect of Nano-α-Al2O3 Particles on Mechanical Properties of Glass-fibre reinforced Epoxy Hybrid Composites

    ANIL KUMAR VEERAPANENI1, CHANDRASEKAR KUPPAN2,*, MURTHY CHAVALI3,*

    Journal of Polymer Materials, Vol.37, No.3-4, pp. 121-130, 2020, DOI:10.32381/JPM.2020.37.3-4.1

    Abstract The mechanical properties of hybrid nanocomposites made of epoxy/glass fibre dispersed with nano-α-Al2 O3 powder at different weight percentages were studied.The effect of nano-α- Al2O3 size and wt% on mechanical properties like tensile, flexural, interlaminar shear stress and hardness enhanced because of their higher surface area and interfacial polymer-metal interaction. The nanoparticle embedded laminates have shown improvement in flexural strength,and hardness when compared to laminate without nano-α-Al2 O3. The properties varied with the loading and size of the nanoparticles. The tensile strength was highest for 0.5 wt% of 200nm nano-α-Al2O3, which is 167.80 N/m2.The highest flexural strength was observed for… More >

  • Open Access

    ARTICLE

    Structural, Thermal, Optical, Mechanical and Morphological Properties of ABS/RGO with DBDPE Nanocomposites

    İBRAHIM KARTERIa,b,*, MUSTAFA ÖZYEŞILDAĞb

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 167-177, 2021, DOI:10.32381/JPM.2021.38.1-2.13

    Abstract This study aims to provide a comprehensive account of chemically reduced graphene oxide (RGO) and decabromodiphenyl ethane (DBDPE) filled acrylonitrile-butadiene-styrene (ABS) multifunctional filaments for fused deposition modeling (FDM) applications. ABS/RGO with DBDPE nanocomposites (ABS-GDM) were fabricated by single-screw extrusion at a diameter of 1.75 mm. The proportion of RGO and DBDPE for the ABS-GDM filaments was set to 0.75 wt%. The properties of the ABS-GDM were determined using optical, mechanical, thermal, and morphological characteristics (using scanning electron microscopy). A three-dimensional (3D) model was successfully printed using the developed ABS-GDM filaments for FDM 3D printing. These ABS-GDM have the potential to… More >

  • Open Access

    ARTICLE

    Flammabilty and Mechanical Performance of MWCNT Incorporated Cyante Ester/Carbon Fiber Composites

    JITENDRA. S. TATE1,2,*, HARISH KALLAGUNTA1,2, ANDREW ALVAREZ1

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 101-120, 2021, DOI:10.32381/JPM.2021.38.1-2.9

    Abstract The exponential growth in composites and their increased use in military, aerospace, energy, and automotive industry is driven by their high performance and light weight. High performance thermosetting polymers such as cyanate ester have received considerable attention due to its ability of volatile-free curing. It also offers advantages such as excellent radiation shielding, high thermal stability, and hydrophobicity with lots of potential for enhanced mechanical strength. This research article discusses the results of effects of multiwalled carbon nanotubes (MWCNT) at predetermined loading levels of 0.5wt%, 1wt% and 1.5wt% on mechanical, thermal and flammability properties of cyanate ester modified carbon fiber… More >

  • Open Access

    ARTICLE

    Effect of N,N-Dimethylacetamide/lithium chloride modified microcrystalline cellulose (MCC) on the processing behaviour and properties of celluloserubber (NBR and EPDM) composites

    LAVANYA, R1, NATCHIMUTHU, N2,*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 89-100, 2021, DOI:10.32381/JPM.2021.38.1-2.8

    Abstract Rubber composites of nitrile (NBR) and Ethylene-Propylene-Diene (EPDM) containing unmodified and modified microcrystalline cellulose(MCC) are evaluated for their processing behaviour. The used modified MCC (T-MCC) was treated by N,N-dimethylacetamide/lithium chloride (DMAc/ LiCl).ATR-FTIR spectra of NBR-MCC composites have indicated N-H stretching and bending vibrations and confirmed interactions between nitrile rubber and MCC. AFM studies have indicated that the average roughness of NBR-T-MCC was significantly reduced when compared to that of NBR-untreated MCC. Important processing parameters such as scorch time and cure time are found to decrease significantly for both NBR and EPDM composites withT-MCC. Mechanical properties of these composites are found… More >

  • Open Access

    ARTICLE

    Glass/Biofibers/Epoxy Methacrylate of Bisphenol-C Sandwich Composites: Comparative Mechanical and Electrical Properties and Chemical Resistance

    RITESH D. BHATT, JIGNESH P. PATEL, P. H. PARSANIA*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 71-87, 2021, DOI:10.32381/JPM.2021.38.1-2.7

    Abstract Glass/Biofibers/Epoxy methacrylate of bisphenol-C (G/BF/EBCMAS) sandwich composites was prepared by compression molding. G/BF/EBCMAS showed good mechanical and good to excellent electrical properties and excellent chemical resistance. Studied properties are compared with EBCMAS and G/EBCMAS. In comparison with G/EBCMAS, G/BF/EBCMAS showed considerable decline of tensile strength (18-63.4%), flexural strength (18.8-38.7%), flexural modulus (12.8-50.7%), Izod impact strength (17.4-43.5%), Barcol hardness (2.1-16.7%) and dielectric strength (23.8-76.8%) except flexural strength of G/BM/EBCMAS. G/WC/EBCMAS (96.7%), G/B/EBCMAS (79.2%), G/GN/EBCMAS (83.3%) and G/RH/EBCMAS (97.9%) showed decline of volume resistivity, whereas other sandwich composites showed 1150-58233% improvement. The decrease in mechanical properties and dielectric strength of G/BF/EBCMAS sandwich… More >

  • Open Access

    ARTICLE

    4-dimensional Printing of Multi-material, Multi-shape Changing Shape Memory Polymer Composites

    MANIKANDAN.N1,*, RAJESH.P.K1

    Journal of Polymer Materials, Vol.38, No.3-4, pp. 327-336, 2021, DOI:10.32381/JPM.2021.38.3-4.12

    Abstract In this research, a new method to fabricate multi-material, multi-shape changing polymer composites is proposed. The method aims to reduce the number of thermomechanical programming steps involved in achieving shape change in a shape memory polymer (SMP) composite structure by including the programming steps directly into the printing process. After a single step of mechanical deformation and thermal loading, the SMP fibers can be activated sequentially to control the shape change. Composite strip samples were fabricated using a Stratasys Objet 260 multimaterial printer. Two polymer inks VeroPureWhite and Agilus30 were used as primary materials. The composite strip consists of fiber… More >

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