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  • Open Access

    A Highly Water-Resistant Soy-Based Bioadhesive with 1,4-Butanediol Diglycidyl Ether and its Application on Plywood

    Kun Li, Xiaona Li, Jing Luo, Jingjing Li, Qiang Gao*, Jianzhang Li*

    Journal of Renewable Materials, Vol.5, Suppl.1, pp. 31-38, 2017, DOI:10.7569/JRM.2017.634131

    Abstract The objective of this study was to use soybean meal and 1,4-butanediol diglycidyl ether (BDDE) to develop a highly water-resistant, soy-based bioadhesive for plywood fabrication. The physical properties and performance characteristics of the resulting adhesive, including solid content, viscosity, water resistance, crystallinity, fracture morphology, thermal behavior, and cracks, were evaluated. The proposed adhesive was compared against the traditional soy adhesive with polyamidoamine-epichlorohydrin (PAE). Results showed that adding 8 g of BDDE into the adhesive formulation improved the solid content up to 32.83% and reduced the viscosity to 27340 mPa·s. The wet shear strength of plywood More >

  • Open Access

    ARTICLE

    Chitosan-g-PMMA/Kaolin Bionanocomposites for Use in Bioadhesive Bone-Cement Implants

    Arun Kumar Pradhan1,2*, Prafulla Kumar Sahoo1, Pradeep Kumar Rana2

    Journal of Renewable Materials, Vol.5, No.5, pp. 371-379, 2017, DOI:10.7569/JRM.2017.634129

    Abstract Chitosan grafted with poly(methyl-methacrylate) (PMMA) and adsorbed with kaolin functionalized as bioadhesive was prepared via emulsion polymerization technique and physiochemically characterized as a bone-graft substitute. The so prepared grafted bioactive bone cement (BBC) bionanocomposites (BNCs), chitosan-g-PMMA/kaolin, was characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) analysis, field-emission scanning electron microscopy (FESEM) and thermogravimetric analysis (TGA). The water uptake, retention ability and the nanosize particle arrangement in the polymeric BBC-BNCs were studied along with the mechanical and biodegradation properties. These preliminary investigations of the BNCs will open the door for their use in bioadhesive More >

  • Open Access

    ARTICLE

    Natural Additive for Reducing Formaldehyde Emissions in Urea-Formaldehyde Resins

    Flávio Pereira1, João Pereira2, Nádia Paiva3, João Ferra3, Jorge Manuel Martins1,4, Fernão D. Magalhães1, and Luísa Carvalho1,4*

    Journal of Renewable Materials, Vol.4, No.1, pp. 41-46, 2016, DOI:10.7569/JRM.2015.634128

    Abstract This work studies the use of soy protein as a natural formaldehyde scavenger in wood particleboard production. The protein is incorporated in two forms: a) as a powder, during the blending process of wood particles with urea-formaldehyde binder resin, and b) as an aqueous solution, added at different times during resin synthesis. Analysis of variance (ANOVA) was used to evaluate the signifi cance level of two effects (amount of added soy and time of addition) on internal bond strength, thickness swelling, and formaldehyde content of the resulting panels. The results showed that soy protein can More >

  • Open Access

    RESIDENT’S CORNER

    Ureteral obstruction following partial nephrectomy: can it be caused by fibrin glue?

    Timothy D. Lyon, Katherine M. Theisen, Kevin J. Rycyna, Ronald M. Benoit

    Canadian Journal of Urology, Vol.22, No.1, pp. 7674-7676, 2015

    Abstract Fibrin sealants are widely used during partial nephrectomy, however reports regarding the potential complications associated with their use are limited. We present the case of a 67-year-old male who developed delayed ureteral obstruction without hydronephrosis following partial nephrectomy in a solitary kidney. We hypothesize that the obstruction and absence of hydronephrosis were caused by extrinsic compression and subsequent inflammation due to the fibrin glue. Our report underscores the importance of a high index of suspicion for obstruction when acute kidney injury occurs following partial nephrectomy when fibrin glue is used, even in the absence of More >

  • Open Access

    ARTICLE

    Valorization of Tunisian Pomegranate Peel Tannins in Green Adhesives Formulation

    Houda Saad1,2,*, Antonio Pizzi3,4, Bertrand Charrier2, Naceur Ayed1, Karsten Rode5, Fatima Charrier - El Bouhtoury2

    Journal of Renewable Materials, Vol.3, No.1, pp. 34-43, 2015, DOI:10.7569/JRM.2014.634130

    Abstract The possible use of Tunisian pomegranate tannins in wood adhesive formulation was studied for the fi rst time. Colorimetric tests, Fourier transformed infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR) and matrix-assisted laser desorption/ionization time-of-fl ight (MALDI-TOF) mass spectrometry were used to examine pomegranate tannins. Analysis showed that pomegranate peels are rich in hydrolyzable tannins. The Stiasny number tests showed the low reactivity of pomegranate tannin extract to formaldehyde and thus the diffi culty of using it in wood adhesive formulation. Thermomechanical analysis (TMA) and strength analysis of pomegranate tannin/hexamine-based resin showed weak bonding properties. More >

  • Open Access

    ARTICLE

    Bond Strength of Biodegradable Gelatin-Based Wood Adhesives

    D.N. Dorr, S.D. Frazier, K.M. Hess, L.S. Traeger, W.V. Srubar III*

    Journal of Renewable Materials, Vol.3, No.3, pp. 195-204, 2015, DOI:10.7569/JRM.2015.634108

    Abstract A study of the potential for gelatin-based derivatives to serve as biorenewable, biodegradable adhesives for wood and engineered wood products is presented in this article. The effect of gelatin-to-water weight percent on the mechanical, specifically ultimate breaking (bond) strength, and thermal properties was investigated using tensile testing and differential scanning calorimetry, respectively. The breaking strengths of the gelatin-based adhesives were characterized and compared to four commercially available wood adhesives. The effect of 1–5% tannin addition on the mechanical, thermal, and moisture absorption behavior of the gelatin-based adhesives was also investigated. Results show that the gelatin-based More >

  • Open Access

    ARTICLE

    Formaldehyde-Free Wood Composites from Soybean Protein Adhesive

    Richard C. Ferguson, Sharathkumar K. Mendon, James W. Rawlins*, Shelby F. Thames

    Journal of Renewable Materials, Vol.2, No.3, pp. 166-172, 2014, DOI:10.7569/JRM.2013.634133

    Abstract Commercial particleboards are currently synthesized by blending wood furnish with formaldehyde-based resins and curing them under a combination of heat and pressure. Particleboards manufactured with urea-formaldehyde resin are known to liberate formaldehyde during their service lives. Formaldehyde’s carcinogenicity has prompted the search for environmentally-friendly resins for wood composite manufacture. Soybean protein-based adhesives have been developed as a renewable and formaldehyde-free replacement for urea-formaldehyde resins. Particleboards processed using the soybean protein adhesive matched or exceeded performance criteria of M-2-grade commercial particleboards when evaluated as per American National Standards Institute (ANSI) specifi cations. More >

  • Open Access

    ARTICLE

    Comparison between a Cohesive Zone Model and a Continuum Damage Model in Predicting Mode-I Fracture Behavior of Adhesively Bonded Joints

    K.I. Tserpes1, A.S. Koumpias1

    CMES-Computer Modeling in Engineering & Sciences, Vol.83, No.2, pp. 169-182, 2012, DOI:10.32604/cmes.2012.083.169

    Abstract In this work, a comparison between a cohesive zone model and a continuum damage model in predicting the mode-I fracture behavior of adhesively bonded joints is performed on the basis of reliability and applicability. The cohesive zone model (CZM) is based on an exponential traction law characterizing the behavior of the interface elements. The continuum damage model (CDM) is based on the stiffness degradation of adhesive elements imposed by a damage parameter. Both models have been implemented by means of a 3D finite element model. Mode-I fracture behavior of the bonded joints was characterized using… More >

  • Open Access

    ARTICLE

    Study on Shear Test of New Style Automotive Structural Adhesive using Digital Image Correlation Method

    Bin Li1, Guo-biao Yang1, Qi-rong Zhu2, Fan Ni2

    CMC-Computers, Materials & Continua, Vol.21, No.2, pp. 107-118, 2011, DOI:10.3970/cmc.2011.021.107

    Abstract In this paper, digital image correlation method (DICM) is employed to measure the shear behavior of the spot welding specimens and the ones using adhesive under quasi-static lap shear testing. The images of the specimens' surfaces are captured in real-time by CCD and corresponding computer system. DICM is subsequently used to obtained strain by correlating the images captured before and after deformation. Then, both force-displacement curves and stress-strain curves of the specimens including the cracking load are obtained. The results and analysis show that the mechanical properties of specimens using adhesive compared with the spot More >

  • Open Access

    ARTICLE

    Analysis of a Crack in a Thin Adhesive Layer between Orthotropic Materials: An Application to Composite Interlaminar Fracture Toughness Test

    L. Távara1, V. Manticˇ 1, E. Graciani1, J. Cañas1, F. París1

    CMES-Computer Modeling in Engineering & Sciences, Vol.58, No.3, pp. 247-270, 2010, DOI:10.3970/cmes.2010.058.247

    Abstract The problem of a crack in a thin adhesive layer is considered. The adherents may have orthotropic elastic behavior which allows composite laminates to be modeled. In the present work a linear elastic-brittle constitutive law of the thin adhesive layer, called weak interface model, is adopted, allowing an easy modeling of crack propagation along it. In this law, the normal and tangential stresses across the undamaged interface are proportional to the relative normal and tangential displacements, respectively. Interface crack propagation is modeled by successive breaking of the springs used to discretize the weak interface. An… More >

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