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  • Open Access

    ARTICLE

    Polyurethane Composites Synthesized Using Natural Oil-Based Polyols and Sisal Fibers

    S. Michałowski1, M. A. Mosiewicki2*, M. Kuran´ska1, M. I. Aranguren2, A. Prociak1

    Journal of Renewable Materials, Vol.6, No.4, pp. 426-437, 2018, DOI:10.7569/JRM.2017.634163

    Abstract Elastomeric polyurethanes were prepared from a reference polyurethane system modified with biobased polyols synthesized using rapeseed or palm oils. The reference material was modified by replacement of the commercial polyol by 10% of biopolyols and also by addition of sisal fibers up to 5 wt%. The higher functionality of the biopolyols increased the crosslinking density of the networks and this was reflected by an increase in hardness and a decrease in water absorption. The effect of the sisal fibers mainly improved the mechanical and thermomechanical properties of the system with rapeseed oil because of good More >

  • Open Access

    ARTICLE

    Effect of Fiber Loadings and Treatment on Dynamic Mechanical, Thermal and Flammability Properties of Pineapple Leaf Fiber and Kenaf Phenolic Composites

    M. Asim1, M. Jawaid1,2*, M. Nasir3, N. Saba1

    Journal of Renewable Materials, Vol.6, No.4, pp. 383-393, 2018, DOI:10.7569/JRM.2017.634162

    Abstract This study deals with the analysis of dynamic mechanical, thermal and flammability properties of treated and untreated pineapple leaf fiber (PALF) and kenaf fiber (KF) phenolic composites. Results indicated that storage modulus was decreased for all composites with increases in temperature and pattern of slopes for all composites, having almost the same values of E' at glass transition temperature (Tg). The peak of the loss modulus of pure phenolic composites was shown to be much less. After the addition of kenaf/PALF, peaks were higher and shifted towards a high temperature. The Tan delta peak height More >

  • Open Access

    ARTICLE

    Tuning Intermolecular Interaction Between Lignin and Carbon Nanotubes in Fiber Composites – A Combined Experimental and Ab-InitioModeling Study

    Jan Badorrek1,2, Michael Walter3,4,*, Marie-Pierre Laborie1,2,*

    Journal of Renewable Materials, Vol.6, No.3, pp. 325-335, 2018, DOI:10.7569/JRM.2017.634183

    Abstract Doping lignin with carbon nanotubes is a promising strategy for cost-effective high-performance carbon fibers. We investigate the intermolecular interaction potential of CNT and organosolv lignin with two main approaches. Experimentally, oxidized purified multiwalled carbon nanotubes (MWCNTs) and beech organosolv lignins and derivatives are analyzed with their Hansen solubility parameters (HSPs) to assess their mutual compatibility. Theoretically, dispersion-corrected density functional theory simulations of the interaction between model molecules and single-walled carbon nanotubes reveal the source of interactions. We find that oxidation enables and enhances the interaction between carbon nanotubes and organosolv lignin experimentally, which is in More >

  • Open Access

    ARTICLE

    The Effects of Accelerated Photooxidation on Molecular Weight and Thermal and Mechanical Properties of PHBV/Cloisite 30B Bionanocomposites

    Kahina Iggui1,2,*,†, Mustapha Kaci2, Nicolas Le Moigne1, Anne Bergeret1

    Journal of Renewable Materials, Vol.6, No.3, pp. 288-298, 2018, DOI:10.7569/JRM.2017.634184

    Abstract The effects of accelerated photooxidation on the molecular weight and thermal and mechanical properties of Cast PHBV and PHBV/Cloisite 30B (3 wt%) bionanocomposites are investigated herein. Through size exclusion chromatography (SEC) analysis, a significant decrease in both weight and number average molecular weights was observed for all irradiated samples over time, resulting from the chain scission mechanism. Differential scanning calorimetry (DSC) data indicated a decrease in degree of crystallinity and melting temperature after UV exposure, with the appearance of double melting peaks related to the changes in the crystal structure of PHBV. Thermal stability, tensile More >

  • Open Access

    ARTICLE

    Influence of Sugarcane Bagasse Fiber Size on Biodegradable Composites of Thermoplastic Starch

    Bruno Henrique dos Santos, Karen de Souza do Prado, Asaph Armando Jacinto, Márcia Aparecida da Silva Spinacé*

    Journal of Renewable Materials, Vol.6, No.2, pp. 176-182, 2018, DOI:10.7569/JRM.2018.634101

    Abstract Although thermoplastic starch (TPS) is biodegradable, its low mechanical resistance limits its wide application. Sugarcane bagasse (SB) fibers can be used as reinforcement in TPS matrix composites, but the influence of fiber size on the properties of the composite is still unknown. In this study, TPS composites reinforced with SB short fibers of four sizes were processed and characterized in order to analyze the influence of fiber size on the mechanical properties of the TPS/SB composite. It was observed that the interaction between fiber and matrix was good and optimized when the fibers are sifted More >

  • Open Access

    ARTICLE

    The Role of Bamboo Nanoparticles in Kenaf Fiber Reinforced Unsaturated Polyester Composites

    Enih Rosamah1, Abdul Khalil H.P.S.2*, S.W. Yap2, Chaturbhuj K. Saurabh2, Paridah M. Tahir3, Rudi Dungani4, Abdulwahab F. Owolabi2

    Journal of Renewable Materials, Vol.6, No.1, pp. 75-86, 2018, DOI:10.7569/JRM.2017.634152

    Abstract In this study, bamboo nanoparticles in concentration ranges from 0–5% were incorporated along with woven/nonwoven kenaf fiber mat into unsaturated polyester and the developed composites were further characterized. Bamboo chips were subjected to ball milling process for the synthesis of nanoparticles with a particle size of 52.92 nm. The effect that the incorporation of nanoparticles had on various properties of reinforced composites was further observed. Due to the high surface area of nanoparticles, incorporation of 3% of nanofillers contributed towards strong bonding and better wettability with matrix, thus resulting in excellent mechanical properties and thermal More >

  • Open Access

    ARTICLE

    Effect of Hybridization on the Mechanical Properties of Pineapple Leaf Fiber/Kenaf Phenolic Hybrid Composites

    M. Asim1, M. Jawaid1,4*, K. Abdan2, M.R. Ishak3, O.Y. Alothman4,5

    Journal of Renewable Materials, Vol.6, No.1, pp. 38-46, 2018, DOI:10.7569/JRM.2017.634148

    Abstract In this study, pineapple leaf fiber (PALF), kenaf fiber (KF) and PALF/KF/phenolic (PF) composites were fabricated and their mechanical properties were investigated. The mechanical properties (tensile, flexural and impact) of the PALF/KF/PF hybrid composites were investigated and compared with PALF/KF composites. The 3P7K exhibited enhanced tensile strength (46.96 MPa) and modulus (6.84 GPa), flexural strength (84.21 MPa) and modulus (5.81 GPa), and impact strength (5.39 kJ/m2) when compared with the PALF/PF and KF/PF composites. Scanning electron microscopy (SEM) was used to observe the fracture surfaces of the tensile testing samples. The microstructure of the 7P3K More >

  • Open Access

    ARTICLE

    Poly(lactic acid)-starch/Expandable Graphite (PLA-starch/EG) Flame Retardant Composites

    Mfiso Emmanuel Mngomezulu1, Adriaan Stephanus Luyt2, Steve Anthony Chapple3, Maya Jacob John3,4*

    Journal of Renewable Materials, Vol.6, No.1, pp. 26-37, 2018, DOI:10.7569/JRM.2017.634140

    Abstract This work reports on the effect of commercial expandable graphite (EG) on the flammability and thermal decomposition properties of PLA-starch blend. The PLA-starch/EG composites were prepared by melt-mixing and their thermal stability, volatile pyrolysis products and flammability characteristics were investigated. The char residues of the composites, after combustion in a cone calorimeter, were analyzed with environmental scanning electron microscopy (ESEM). The thermal decomposition stability of the composites improved in the presence of EG. However, the char content was less than expected as per the combination of the wt% EG added into PLA-starch and the %… More >

  • Open Access

    ARTICLE

    Delamination Identification for FRP Composites with Emphasis on Frequency-Based Vibration Monitoring-A Review

    Mengyue He1, Zhifang Zhang1,*, Karthik Ram Ramakrishnan2

    Structural Durability & Health Monitoring, Vol.12, No.4, pp. 213-256, 2018, DOI:10.32604/sdhm.2018.05122

    Abstract Fibre reinforced polymer (FRP) composite laminates are now commonly used in many structural applications, especially in the aerospace industry, where margins of safety are kept low in order to minimise weight. Timely detection and assessment of damage (in particular delaminations) in composite laminates are therefore critical, as they can cause loss of structural integrity affecting the safe operation of the composite structures. The current trend is towards implementation of structural health monitoring (SHM) systems which can monitor the structures in situ without down time. In this paper, first, the current available SHM techniques for delamination… More >

  • Open Access

    ARTICLE

    Recent Developments About IPMCs (Ionic Polymer-Metal) Composites: A Review of Performances for Different Conditions

    Wenqi Zhang1, Yunqing Gu1,*, Jiegang Mou1

    FDMP-Fluid Dynamics & Materials Processing, Vol.14, No.4, pp. 243-258, 2018, DOI:10.32604/fdmp.2018.03836

    Abstract It is of great significance for the production of micro robots and new sensors to develop actuators with “muscle” properties. As a kind of electroactive polymers (EAPs), IPMC (ionic polymer-metal composite) can exhibit significant deformation for very low electrical excitation. These composites, known as the “artificial muscle”, can be regarded as intelligent bionic materials. With regard to the mechanism of deformation of IPMC, a large number of experimental studies have proved that the variety of electrodes and water contents relating to IPMC have great influence on its electro-mechanical and mechanical properties. Recent research results about… More >

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