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  • Open Access

    ARTICLE

    Preparation and Properties of Vegetable-Oil-Based Thioether Polyol and Ethyl Cellulose Supramolecular Composite Films

    Ruyu Yan1,2,3,4, Jian Fang1,*, Xiaohua Yang2,3,4,5,6, Na Yao2,3,4,5,6, Mei Li2,3,4,5,6, Yuan Nie2,3,4,5,6, Tianxiang Deng2,3,4,5,6, Haiyang Ding2,3,4,5,6, Lina Xu2,3,4,5,6, Shouhai Li2,3,4,5,6,*

    Journal of Renewable Materials, Vol.11, No.4, pp. 1937-1950, 2023, DOI:10.32604/jrm.2023.025126

    Abstract Ethyl cellulose (EC), an important biomass-based material, has excellent film-forming properties. Nevertheless, the high interchain hydrogen bond interaction leads to a high glass transition temperature of EC, which makes it too brittle to be used widely. The hydroxyl group on EC can form a supramolecular system in the form of a non-covalent bond with an effective plasticizer. In this study, an important vegetable-oil-based derivative named dimer fatty acid was used to prepare a novel special plasticizer for EC. Dimer-fatty-acid-based thioether polyol (DATP) was synthesized and used to modify ethyl cellulose films. The supramolecular composite films… More > Graphic Abstract

    Preparation and Properties of Vegetable-Oil-Based Thioether Polyol and Ethyl Cellulose Supramolecular Composite Films

  • Open Access

    ARTICLE

    Pulse Laser Deposition of HfO2 Nanoporous-Like Structure, Physical Properties for Device Fabrication

    Shams B. Ali1, Sarmad Fawzi Hamza Alhasan1, Evan T. Salim2,*, Forat H. Alsultany3, Omar S. Dahham4,5

    Journal of Renewable Materials, Vol.10, No.11, pp. 2819-2834, 2022, DOI:10.32604/jrm.2022.021609

    Abstract The pulsed laser deposition (PLD) technology was used to effectively create conductive nano and micro hafnium oxide with great purity and transparency for (HfO2) nanofilms. In many optoelectronics devices and their applications, the presence of a high dielectric substance like a nano HfO2, between the metal contacts and the substrates was critical. We used the Pulsed Laser Deposition method to fabricate an Al/HfO2/p-Si Schottky barrier diode where the nanostructured HfO2 films as an intermediate layer and varied substrate temperatures. The optical result reveals a high degree of transparency (93%). The optical bandgap of deposited HfO2 films was observed… More >

  • Open Access

    ARTICLE

    Assisted Compatibility, and Balanced Regulation of the Mechanical, Thermal, and Antioxidant Activity of Polyvinyl Alcohol-Chinese Bayberry Tannin Extract Films Using Different Di-Aldehydes as Cross-Linkers

    Jingjing Liao1,2, Jinxing Li2, Fuxian Yang2, Yan Zhu2, Hongyan Wang3, Guanben Du1,2,*, Hisham Essawy4, Xiaojian Zhou2,*

    Journal of Renewable Materials, Vol.10, No.2, pp. 359-372, 2022, DOI:10.32604/jrm.2021.016335

    Abstract Polyvinyl alcohol (PVA)-based films containing Chinese bayberry tannin (BT) were prepared by cross-linking using glyoxal, glutaraldehyde and dialdehyde starch, individually. The presence of cross-linkers was evident to promote the transparency and decrease the moisture content of PVA/BT films, while the water solubility stayed almost unchanged in the cross-linked PVA/BT films. All cross-linkers provided promotion of the water vapor permeability, mechanical property and thermal stability of PVA/BT films. The best water vapor barrier capacity was found in case of glutaraldehyde cross-linked PVA/BT film, while the highest tensile strength was encountered in case of glyoxal cross-linked PVA/BT More > Graphic Abstract

    Assisted Compatibility, and Balanced Regulation of the Mechanical, Thermal, and Antioxidant Activity of Polyvinyl Alcohol-Chinese Bayberry Tannin Extract Films Using Different Di-Aldehydes as Cross-Linkers

  • Open Access

    ARTICLE

    Development of Chitosan-based Films Containing Hypericum perforatum L. and Citrus limon L. as Potential Wound Dressing Materials

    DENIZ AKIN SAHBAZ1,*, BETUL TURP KAYA2

    Journal of Polymer Materials, Vol.38, No.3-4, pp. 247-256, 2021, DOI:10.32381/JPM.2021.38.3-4.6

    Abstract The objective of this study is to develop chitosan-based films containing Hypericum perforatum L. and/or Citrus limon L. oils and to investigate their suitability as novel wound dressing materials. The morphology of the chitosan-based films were observed by means of employing the scanning electron microscopy (SEM) and the chemical structure characterization was performed via Fourier Transform Infrared Spectroscopy (FTIR). Hypericum perforatum L. and/or Citrus limon L. were successfully incorporated to the chitosan films. Antibacterial, swelling, and mechanical properties of these films were investigated. The antibacterial property was enhanced by incorporating Hypericum perforatum L. and Citrus More >

  • Open Access

    ARTICLE

    Synthesis and characterization of polymeric responsive CMC/Pectin hydrogel films loaded with Tamarix aphylla extract as potential wound dressings

    BARKAT ALI KHAN1, FAZAL KARIM1, MUHAMMAD KHALID KHAN1,*, FAHEEM HAIDER1, SADIQULLAH KHAN2

    BIOCELL, Vol.45, No.5, pp. 1273-1285, 2021, DOI:10.32604/biocell.2021.015323

    Abstract The fourth most predominant overwhelming type of trauma is burn injuries worldwide. Ideal wound healing dressings help in the wound healing process in a lower time with less pain. Commonly used dry wound dressing, like absorbent gauze or absorbent cotton, possess limited therapeutic effects and require repeated use, which further exaggerates patients’ suffering. In contrast, hydrogels films present a promising alternative to improve healing by guaranteeing a moisture balance at the wound site. The aim of the current study was to synthesize Tamarix aphylla (T. aphylla) extract-loaded hydrogel film with Na-CMC and pectin and to study their… More >

  • Open Access

    ARTICLE

    Nanofibrillation of Bacterial Cellulose Using High-Pressure Homogenization and Its Films Characteristics

    Heru Suryanto1,2,*, Muhamad Muhajir1, Bili Darnanto Susilo1, Yanuar Rohmat Aji Pradana1, Husni Wahyu Wijaya2,3, Abu Saad Ansari4, Uun Yanuhar5

    Journal of Renewable Materials, Vol.9, No.10, pp. 1717-1728, 2021, DOI:10.32604/jrm.2021.015312

    Abstract The microstructure of bacterial cellulose nanofibers (BCNs) film affects its characteristic. One of several means to engineer the microstructure is by changing the BCNs size and fiber distribution through a high-pressure homogenizer (HPH) process. This research aimed to find out the effects of repetition cycles on HPH process towards BCNs film characteristics. To prepare BCNs films, a pellicle from the fermentation of pineapple peels waste with Acetobacter xylinum (A. xylinum) was extracted, followed by crushing the pellicle with a high-speed blender, thereafter, homogenized using HPH at 150 bar pressure with variations of 5, 10, 15, and 20… More >

  • Open Access

    ARTICLE

    Physical Properties of SiC Nanostructure for Optoelectronics Applications

    Mayyadah H. Mohsin1, Najwan H. Numan2, Evan T. Salim1,*, Makram A. Fakhri2,*

    Journal of Renewable Materials, Vol.9, No.9, pp. 1519-1530, 2021, DOI:10.32604/jrm.2021.015465

    Abstract A SiC nanofilms have been deposited and investigated on quartz and silicon substrates using pulsed laser deposition technique with the 300 pulses of Nd: YAG laser at two different laser wavelengths of 1064 nm and 532 nm. The structural, morphological, and optical properties of the deposited nanostructure SiC were prepared and characterized as a function of the wavelengths of the used laser. The structural result shows four different pecks at (111), (200), (220), and (311) planes related to Nano SiC. The transmission result presents that the optical energy gap value for the SiC nanostructure is More > Graphic Abstract

    Physical Properties of SiC Nanostructure for Optoelectronics Applications

  • Open Access

    ARTICLE

    Hydrogenated Amorphous Carbon Films from Palmyra Sugar

    Budhi Priyanto1,2,*, Retno Asih1, Irma Septi Ardiani1, Anna Zakiyatul Laila1, Khoirotun Nadiyyah1, Bima Romadhon3, Sarayut Tunmee4, Hideki Nakajima4, Triwikantoro1, Yoyok Cahyono1, Darminto1,*

    Journal of Renewable Materials, Vol.9, No.6, pp. 1087-1098, 2021, DOI:10.32604/jrm.2021.014466

    Abstract A simple, highly reproducible, and environmentally friendly method is a considered approach in generating renewable energy materials. Here, hydrogenated amorphous carbon (a-C) films have been successfully prepared from palmyra liquid sugar, employing spin-coating and spraying methods. Compared with the former method, the latter shows a significance in producing a better homogeneity in particle size and film thickness. The obtained films have a thickness of approximately 1000 to 100 nm and contain an sp2 hexagonal structure (~70%) and sp3 tetrahedral configuration (~30%) of carbons. The introduction of boron (B) and nitrogen (N) as dopants has created the local More > Graphic Abstract

    Hydrogenated Amorphous Carbon Films from Palmyra Sugar

  • Open Access

    ARTICLE

    Melt Extrusion of Environmentally Friendly Poly(L-lactic acid)/Sodium Metabisulfite Films for Antimicrobial Packaging Applications

    Norma M. P. Machado1, Gustavo C. Melo1, Matheus F. Camargo1, Giulianna G. Feijó1, Bruna M. S. Putton2, Clarice Steffens2, Rogerio L. Cansian2, Luiz A. Pessan1, Francys K. V. Moreira1,*

    Journal of Renewable Materials, Vol.9, No.2, pp. 337-349, 2021, DOI:10.32604/jrm.2021.011081

    Abstract Food packaging materials compounded with antimicrobial additives can substantially diminish the incidence of foodborne diseases. Here, poly(L-lactic acid) (PLA) films containing sodium metabisulfite (NaM) were produced by melt extrusion as an attempt to develop a new biodegradable material with antimicrobial properties for packaging. Life cycle assessment (LCA) simulations revealed that the environmental footprints of the PLA film did not change upon NaM addition, and that NaM is more eco-friendly than silver nanoparticles. The PLA/NaM films with NaM content varying from 0.5 to 5.0 wt.% were characterized by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and… More >

  • Open Access

    ARTICLE

    Preparation of Corn Cellulose Films with Controllable Mechanical Property by Using Switchable CO2 /DBU/ DMSO System

    BAOHAI PAN1,2, JUNCHENG HUANG1, LAI CHEN2, FEI LIU1,*, CHEN JING, HAINING NA1,*, JIN ZHU1

    Journal of Polymer Materials, Vol.37, No.1-2, pp. 17-27, 2020, DOI:10.32381/JPM.2020.37.1-2.2

    Abstract A switchable CO2 /1,8-diazabicyclo[5.4.0]undec-7-ene (DBU)/dimethyl sulfoxide (DMSO) solvent system is applied to prepare corn cellulose film with controllable mechanical property. By use of the switchable CO2 /DBU/DMSO system, a rather simple process concerning reacted dissolution and heated precipitation controlled by addition and releasing of CO2 respectively, to prepare corn cellulose film, is formed. Results exhibit the degree of dissolution of corn cellulose is easily controlled just by adjusting the feeding amount of DBU in the switchable solvent system. Accordingly, some undissolved part of corn cellulose with relative high crystallinity can be appropriately retained to contribute to the More >

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