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  • Open Access

    ARTICLE

    Synthesis of Bio-Plasticizer from Soybean Oil and Its Application in Poly(Vinyl Chloride) Films

    Xiao Luo1,*, Hongying Chu2, Mengqi Liu1

    Journal of Renewable Materials, Vol.8, No.10, pp. 1295-1304, 2020, DOI:10.32604/jrm.2020.011026

    Abstract Herein, epoxidized soybean oil methyl ester (ESOM) plasticizer was synthesized for the preparation of plasticized poly(vinyl chloride) (PVC) films by the alcoholysis and epoxidation. The chemical structure of ESOM was investigated by infrared spectrum and 1H nuclear magnetic resonance. The effect of content of ESOM and petroleum based plasticizer di-2-ethylhexyl phthalate (DEHP) on the performance of plasticized PVC films was studied. The result showed that substituting DEHP with ESOM can improve the thermal stability of plasticized PVC films. When the weight ratio of ESOM and PVC is fixed at 1:2, plasticized PVC film presents higher elongation More >

  • Open Access

    ARTICLE

    On the Modeling of Non-Classical Problems Involving Liquid Jets and Films and Related Heat Transfer Processes

    Ivan V. Kazachkov1,2,*

    FDMP-Fluid Dynamics & Materials Processing, Vol.15, No.5, pp. 491-507, 2019, DOI:10.32604/fdmp.2019.06477

    Abstract Non-classical subjects relating to the dynamics of jet and film flow and related heat transfer processes are considered. These problems, which are relevant to several technological applications, cannot completely be addressed in the frame of the canonical Navier-Stokes equations. The first example deals with the formation of a film flow as a result of the hydraulic shock of a vertical jet impinging on a horizontal plane. The effective thickness of the film resulting from the hydraulic shock is much less than the value obtained using the conventional approach (relying on the assumption of smooth flow),… More >

  • Open Access

    ARTICLE

    Sensor Concept Based on Piezoelectric PVDF Films for the Structural Health Monitoring of Fatigue Crack Growth

    Dennis Bäcker1, Andreas Ricoeur2, Meinhard Kuna1

    Structural Durability & Health Monitoring, Vol.7, No.1&2, pp. 1-22, 2011, DOI:10.3970/sdhm.2011.007.001

    Abstract A new sensor concept for monitoring fatigue crack growth in technical structures is presented. It allows the in-situ determination of the position of the crack tip as well as the fracture mechanical quantities. The required data are obtained from a piezoelectric polymer film, which is attached to the surface of the monitored structure. The stress intensity factors and the crack tip position are calculated from electrical potentials obtained from a sensor array by solving the non-linear inverse problem. More >

  • Open Access

    ARTICLE

    The Atomistic Study of Textured Polycrystalline Nanofilms

    I-L. Chang1, W.-C. Ding

    CMES-Computer Modeling in Engineering & Sciences, Vol.68, No.3, pp. 297-312, 2010, DOI:10.3970/cmes.2010.068.297

    Abstract Molecular dynamics method incorporating with parallel computing technique was employed to study the mechanical properties of textured polycrystalline nanofilms with fixed out-of-plane normal direction. The grain size and film thickness effects on both the elastic and plastic properties of the copper nanofilm were examined. It is shown from the simulation that the elastic and plastic properties (i.e., Young’s modulus, Poisson’s ratio, biaxial yield stress, etc) of textured polycrystalline nanofilms depend on the grain size and the film thickness. As the grain size of the nanofilm become larger, the Young’s modulus and biaxial yield stress increase More >

  • Open Access

    ABSTRACT

    Phase-field simulation of domain evolution in ferroelectric thin films with deadlayers

    Yifan Xia, Jie Wang

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.20, No.3, pp. 87-88, 2011, DOI:10.3970/icces.2011.020.087

    Abstract Phase field simulation is an effective way to predict the domain evolution in ferroelectric materials. A phase field model is developed to investigate the domain structures and polarization switching in in ferroelectric thin films with deadlayers. Simulation results show that the deadlayers as well as misfit strain have a significant influence on the domain structures and polarization switching in the ferroelectric thin films. It is found that the simulated switching electric field in ferroelectric thin films decreases with the thickness of the deadlayers increasing. More >

  • Open Access

    ARTICLE

    The Effect of the Process on Mechanical Properties of Polylactic Acid-Date Palm Leaf Fibers Composite Films Produced By Extrusion Blowing

    Fatma Kharrat1, Rania Chaari1, Mohamed Khlif1, Loic Hilliou2, José A. Covas2, Mohamed Haboussi3,*, Hedi Nouri1, Chedly Bradai1

    Journal of Renewable Materials, Vol.7, No.9, pp. 891-901, 2019, DOI:10.32604/jrm.2019.06827

    Abstract Biocomposite films prepared with melt compounding and film blowing have become a new trend in plastic research to deliver more eco-friendly packages. Polylactic acid (PLA) was melt compounded with minimally processed date palm leaf fiber (DPLF) and converted into films by blown film extrusion. The compounding was done in order to enhance the film mechanical properties in one hand, and to decrease the film production cost in the other hand. In this present study, a reference PLA film and films with 1%, 2%, and 5% of DPLF (weight %) were produced with different process parameters.… More >

  • Open Access

    ARTICLE

    Synthesis of a Fully Biobased Polyfunctional Vinyl Oligomer and Their UV Cured Films Prepared via Thiol-ene Coupling

    Changqing Fu1,2, Jiahui Wang1,2, Lie Chen1,2, Liang Shen1,2,*

    Journal of Renewable Materials, Vol.7, No.8, pp. 795-805, 2019, DOI:10.32604/jrm.2019.07503

    Abstract In this paper, a fully bio-based vinyl oligomer with high functionalities was successfully prepared from rapeseed oil by three modification steps: epoxidation of rapeseed oil, solvent-free and catalyst-free ring opening by 10-undecylenic acid followed by esterification with 10-undecenoyl chloride. Then, the renewable polymers were prepared by photo-polymerization of these modified vegetable oils with typical thiol monomers: pentaerythritol tetrakis (3-mercaptopropionate), pentaerythritol tris (3-mercaptopropionate) and 1,2-ethanedithiol. The synthesis of the vinyl oligomer was monitored by nuclear magnetic resonance and Fourier-transform infrared spectroscopy. The average number of the carbon-carbon double bonds of the resulting vinyl oligomer is high… More >

  • Open Access

    ARTICLE

    Influence of Blueberry and Jaboticaba Agroindustrial Residue Particle Size on Color Change of Corn Starch Based Films Submitted to Different pH Values Solutions

    Cláudia Leites Luchese*, Julia Menegotto Frick Pavoni, Jordana Corralo Spada, Isabel Cristina Tessaro

    Journal of Renewable Materials, Vol.7, No.3, pp. 235-243, 2019, DOI:10.32604/jrm.2019.00033

    Abstract Corn starch, glycerol and agroindustrial residues were used to produce films by casting. By-products from juice processing, blueberry and jaboticaba in powder with different particle sizes were added in the filmogenic matrix to evaluate its potential as a colorimetric indicator. Blueberry and jaboticaba peels are commonly discarded although contain high amount of important compounds as anthocyanins. These compounds have the ability to color change after immersion in different pH values, demonstrating its potential for the intelligent packaging development. Analyses were performed in a colorimeter after films immersion in different buffer solutions. Visual color changes were More >

  • Open Access

    ARTICLE

    Conversion of Waste Parasitic Insect (Hylobius abietis L.) into Antioxidative, Antimicrobial and Biodegradable Films

    Murat Kaya1,*, Idris Sargin1, Povilas Mulerčikas2, Jalel Labidi3, Asier M. Salaberria3, Yavuz S. Cakmak1, Sonata Kazlauskaitė2, Demet Erdonmez4, Vykintas Baublys5

    Journal of Renewable Materials, Vol.7, No.3, pp. 215-226, 2019, DOI:10.32604/jrm.2019.00002

    Abstract Hylobius abietis is a plant parasitic insect belonging to the order Coleoptera and which causes severe damages to coniferous forests in Northern and Eastern Europe. This current study is aimed to provide a new viewpoint into the waste of this insect by producing chitosan. Dry insect corpses consisted of 27.9% chitin and 86.2% of the chitin was converted into the chitosan. FT-IR spectra analyses confirmed the purity and the deacetylation degree of the produced chitosan (molecular weight of chitosan; 7.3 kDa). This chitosan exhibited antimicrobial activity against 18 bacterial strains. Further, biodegradable chitosan composite films More >

  • Open Access

    ARTICLE

    Evaluation of Biodegradation in Aqueous Medium of Poly(Hydroxybutyrate-Co-Hydroxyvalerate)/Carbon Nanotubes Films in Respirometric System

    Larissa Stieven Montagna, Isabela CÉSAR Oyama, Rita de CÁSSIA Barbosa Camargo Lamparelli, Ana Paula Silva, THAÍS Larissa do Amaral Montanheiro, Ana Paula Lemes*

    Journal of Renewable Materials, Vol.7, No.2, pp. 117-128, 2019, DOI:10.32604/jrm.2019.00036

    Abstract Biodegradable polymers have been increasingly used for scientific and commercial applications because they are similar to some conventional thermoplastics and exhibit the ability of self-degradation. Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites films with 1 and 2 wt% of carbon nanotubes (CNT) were prepared by solution mixing, followed by solvent evaporation. In this work, PHBV/CNT nanocomposites were submitted to biodegradation in an aqueous medium for 34 days through a respirometric system. Then, the PHBV films were analyzed by the CO2 production and mineralization as a response of a microbial attack, which was monitored by back titration during all the… More >

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