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  • Open Access

    ARTICLE

    Photoresponsive Multilayer Films of Chitosan and an Azopolymer

    Raquel Fernández*, Connie Ocando, Susana C. M. Fernandes, Arantxa Eceiza, Agnieszka Tercjak

    Journal of Renewable Materials, Vol.3, No.1, pp. 49-55, 2015, DOI:10.7569/JRM.2014.634134

    Abstract The main goal of this work was the development of photoactive multilayer fi lms. Taking into account that chitosan is a biodegradable, biocompatible, nontoxic, and antibacterial biopolymer, the fabrication of chitosanbased multilayer fi lms can be an interesting pathway to obtain biopolymer-based fi lms in which properties can be combined with a light-responsive material, such as an azobenzene-containing polymer. In particular, the layer-by-layer technique was used for the fabrication of the optically active fi lms consisting of alternating layers of chitosan and an azopolymer. The infl uence of the pH and the number of bilayers More >

  • Open Access

    ARTICLE

    Surface, Thermal and Antimicrobial Release Properties of Plasma-Treated Zein Films

    S.K. Pankaj1, C. Bueno-Ferrer1, N.N. Misra1, L. O’Neill2, A. Jiménez3, P. Bourke1, P.J. Cullen1,4,*

    Journal of Renewable Materials, Vol.2, No.1, pp. 77-84, 2014, DOI:10.7569/JRM.2013.634129

    Abstract The effects of dielectric barrier discharge plasma treatment on zein fi lm containing thymol as an active ingredient were evaluated. The plasma discharge was optically characterized to identify the reactive species. A signifi cant increase in the fi lm roughness (p < 0.05) was observed due to the etching effect of DBD plasma, which was correlated with the increase in the diffusion rate of thymol in the food simulant. The diffusion of thymol from the zein fi lm was measured in aqueous solution. The kinetics of thymol release followed the Fick’s law of diffusion as More >

  • Open Access

    ARTICLE

    Material Properties and Molecular Aspects of Highly Acetylated Starch-Based Films

    Kristine Koch1,*, Daniel Johansson2, Kalle Johansson3, Karin Svegmark4

    Journal of Renewable Materials, Vol.2, No.2, pp. 134-144, 2014, DOI:10.7569/JRM.2014.634110

    Abstract Properties of starch triacetate fi lms from different botanical origins were evaluated. Tensile and barrier properties, glass transition temperatures and moisture uptake were measured, and the molecular structure was characterised. High-amylose starches were good fi lm formers, normal potato starch formed continuous but brittle fi lms and potato amylopectin formed very brittle fi lms even after plasticisation. Barley amylopectin did not form continuous fi lms. Different plasticisers were studied and diacetin was shown to perform better than the standard plasticiser triacetin. All fi lms were water resistant, and the best fi lms gave water vapour More >

  • Open Access

    ARTICLE

    Effective Surface Susceptibility Models for Periodic Metafilms Within the Dipole Approximation Technique

    A.I. Dimitriadis1, N.V. Kantartzis1 and T.D. Tsiboukis1

    CMC-Computers, Materials & Continua, Vol.39, No.3, pp. 231-265, 2014, DOI:10.3970/cmc.2014.039.231

    Abstract The most important surface susceptibility models for the electromagnetic characterization of periodic metafilms, based on the dipole approximation method, are systematically analyzed in this paper. Specifically, two well-known techniques, which lead to a set of local effective surface parameters, are investigated along with a new dynamic non-local modeling algorithm. The latter formulation is properly expanded, in order to be applicable for any arbitrary periodic metafilm, irrespective of its way of excitation. The featured schemes are then directly compared toward their ability to efficiently predict the reflection and transmission properties of several lossless and lossy metafilms. More >

  • Open Access

    ARTICLE

    Rupture and Instability of Soft Films due to Moisture Vaporization in Microelectronic Devices

    Linsen Zhu1, Jiang Zhou2, Xuejun Fan2

    CMC-Computers, Materials & Continua, Vol.39, No.2, pp. 113-134, 2014, DOI:10.3970/cmc.2014.039.113

    Abstract In this paper, a damage mechanics-based continuum theory is developed for the coupled analysis of moisture vaporization, moisture absorption and desorption, heat conduction, and mechanical stress for a reflow process in microelectronic devices. The extremely compliant film has been used in wafer level lamination process. Such a soft film experiences cohesive rupture subjected to moisture absorption during reflow. The numerical simulation results have demonstrated that vapor pressure due to moisture vaporization is the dominant driving force for the failures. The correlation between the vapor pressure evolution and the film rupture observed from the experiments have… More >

  • Open Access

    ARTICLE

    Comparison of EHD-Driven Instability of Thick and Thin Liquid Films by a Transverse Electric Field

    Payam Sharifi1, Asghar Esmaeeli2

    FDMP-Fluid Dynamics & Materials Processing, Vol.9, No.4, pp. 389-418, 2013, DOI:10.3970/fdmp.2013.009.389

    Abstract This study aims to explore the effect of liquid film thickness on the electrohydrodynamic-driven instability of the interface separating two horizontal immiscible liquid layers. The fluids are confined between two electrodes and the light and less conducting liquid is overlaid on the heavy and more conducting one. Direct Numerical Simulations (DNSs) are performed using a front tracking/finite difference scheme in conjunction with Taylor-Melcher leaky dielectric model. For the range of physical parameters used here, it is shown that for a moderately thick lower liquid layer, the interface instability leads to formation of several liquid columns… More >

  • Open Access

    ARTICLE

    Effects of High Magnetic Field on the Structure and Magnetic Properties of Molecular Beam Vapor Deposited Fe60Ni40 Thin Films

    Yongze Cao1, Guojian Li1, Qiang Wang1,2, Xiaoguang Wang3, Jiaojiao Du1, Jicheng He1

    CMC-Computers, Materials & Continua, Vol.37, No.3, pp. 195-203, 2013, DOI:10.3970/cmc.2013.037.195

    Abstract The Fe60Ni40 (in atomic %) polycrystalline thin films with 90 nm thickness were prepared on 200 °C quartz substrate by using molecular beam vapor deposition method. The influence of 0 T and 6 T magnetic fields on the structural evolution and magnetic properties of thin films was studied by using EDXS, XRD, AFM and VSM. In this study, only α phase was formed in both thin films. It was found that the application of a 6 T magnetic field obviously decreases the RMS of surface roughness and the grain size. For the magnetic properties of the More >

  • Open Access

    ARTICLE

    Effects of High Magnetic Field and Post-Annealing on the Evaporated Ni/Si (100) Thin Films

    Jiaojiao Du1, Guojian Li1, Qiang Wang1,2, Yongze Cao1, Jicheng He1, Yonghui Ma1

    CMC-Computers, Materials & Continua, Vol.34, No.2, pp. 117-129, 2013, DOI:10.3970/cmc.2013.034.117

    Abstract The effects of high magnetic field and post-annealing on the structural, electrical and magnetic properties of the evaporated Ni films were investigated and compared. The in-situ application of a 6 T magnetic field during evaporation or post-annealing at 200°C did not change the crystal structures of the films. However, the magnetic field makes the films exhibit the smallest grain size and the lowest surface roughness. Crystallinity was improved for both the 6 T films and the annealed films. This leads to the enhancement of saturation magnetization (Ms). The value of Ms for the 0 T More >

  • Open Access

    ARTICLE

    HEAT TRANSFER IN METAL FILMS IRRADIATED BY COMBINED NANOSECOND LASER PULSE AND FEMTOSECOND PULSE TRAIN

    Yunpeng Ren, J. K. Chen*, Yuwen Zhang

    Frontiers in Heat and Mass Transfer, Vol.3, No.2, pp. 1-7, 2012, DOI:10.5098/hmt.v3.2.3001

    Abstract Heat transfer in a copper film irradiated by a femtosecond (fs) laser pulse train and by an integrated dual laser beam of a nanosecond pulse with a fspulse train was studied using the semi-classical two-temperature model. The critical point model with three Lorentzian terms was employed to characterize transient optical properties for the laser energy deposition. The effects of pulse number and separation time on the thermal response were investigated. The results showed that with the same total energy in a fs-pulse train, more pulses for shorter separation time, e.g., 1 ps, and fewer pulses More >

  • Open Access

    ARTICLE

    High Magnetic Field Annealing Dependent the Morphology and Microstructure of Nanocrystalline Co/Ni Bilayered Films

    Donggang Li1,2, Alexandra Levesque2, Qiang Wang1,3,2, Agnieszka Franczak2, Chun Wu1, Jean-Paul Chopart2, Jicheng He1

    CMC-Computers, Materials & Continua, Vol.30, No.3, pp. 207-218, 2012, DOI:10.3970/cmc.2012.030.207

    Abstract Co/Ni bilayered films were prepared on ITO glass by electrodeposition assisted with a magnetic field up to 0.5T aligned parallel to the electrode surface. The effect of a high magnetic field annealing up to 12T on morphology and microstructure of the post-deposited films was investigated by field emission scanning electronic microscopy (FE-SEM), X-ray diffraction (XRD) and atomic force microscopy (AFM). Grain shape and grain boundary in the Co/Ni morphology were modified dramatically when the high magnetic field was applied during the annealing process. Magnetic anisotropy appeared in the films due to the preferential orientation of More >

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