RAJKUMAR SINGH RAWAT^1,2, MEENU TALWAR^1,*, RAJENDRA KUMAR DIWAN², AJAY KUMAR TYAGI¹

Journal of Polymer Materials, Vol.38, No.3-4, pp. 281-294, 2021, DOI:10.32381/JPM.2021.38.3-4.9

Abstract In the present paper,boron based diluent was synthesized and incorporated in to a Ultraviolet (UV) radiation curable epoxy coating composition comprising of phosphorus based initiator (Trimethylbenzoyl diphenyl phosphine oxide) for enhancing its flame retardant property. The boron based diluent was synthesized by thermal polymerization technique. The presence of boron and phosphorus on the coating surface was confirmed by Energy Dispersive X-Ray (EDX) and X-ray photoelectron spectroscopy (XPS) techniques and functionality was determination by Fourier Transform Infra-Red (FTIR) and proton/boron NMR spectroscopy technique. The flame retardency property of the coating composition was confirmed by determining limiting More >

Liping Yu¹, Zhongyou Luo¹, Lifen Li¹, Xuedong Xi^2,3, Zhigang Wu^1,2,*, Bengang Zhang^4,*

Journal of Renewable Materials, Vol.9, No.12, pp. 2143-2157, 2021, DOI:10.32604/jrm.2021.016092 - 22 June 2021

Abstract A flame retardant composition was prepared by using phosphoguanidine, guanidine sulfamate, disodium octaborate tetrahydrate and dodecyl dimethyl benzyl ammonium chloride. Veneers were immersed in such flame retardant mixture to prepare plywood. The combustion characteristics and thermal stability of plywood were assessed using a cone calorimeter and TG. Results showed that: (1) High concentration and loading of flame retardant were beneficial for the fire resistance of the plywood. (2) The limiting oxygen index (LOI) and residual mass of plywood processed using the flame retardant was increased by 87.52% and 58.66% compared to those of the untreated… More >

Qionglin Luo¹, Mingliang Wang², Hui Zhang¹, Yuejun Ouyang¹, Hongwei Lin¹, You Shu^1,*, Shengpei Su^1,2,*

Journal of Renewable Materials, Vol.9, No.12, pp. 2067-2076, 2021, DOI:10.32604/jrm.2021.016255 - 22 June 2021

Abstract Poly(L-lactic acid) (PLLA) is a thermoplastic material with complete degradability, high biocompatibility and excellent mechanical properties. It can replace petroleum-based polymers are currently being used in the fields of packaging, agriculture, textiles, medical and so on. However, PLLA’s extremely flammability greatly limits its wider application. An bio-based flame retardant L-APP/PLLA composites was prepared by melt blending of the L-APP and PLLA. The morphology, impact properties, thermal properties and flame retardant properties of composites were investigated by field emission scanning electron microscope (SEM), impact tester, differential scanning calorimeter (DSC), thermogravimetric analyzer (TGA), limiting oxygen indexer (LOI)… More > Graphic Abstract

You Shu^1,2, Qionglin Luo², Hongwei Lin^2,*, Yuejun Ouyang², Xiaomin Zhang^1,2, Liping Sheng¹, Shengpei Su^1,2,*

Journal of Renewable Materials, Vol.9, No.5, pp. 909-921, 2021, DOI:10.32604/jrm.2021.014216 - 20 February 2021

Abstract Polyvinyl alcohol (PVA) has been widely used in the fields of medical, food and packaging due to its excellent biocompatibility, good fiber-forming and film-forming properties. However, the high flammability of PVA has greatly limited its wider applications. The flame-retardant PVA was prepared by melt blending of a bio-based flame retardant (prepared from lignin, phosphoric acid and carbamide) with thermoplastic PVA (TPVA). The chemical structure, morphology, thermal properties, mechanical properties, fire property and fluidity of this flame retardant PVA were investigated by Fourier transform infrared spectrometer(FTIR), field emission scanning electron microscope(SEM), thermogravimetric analyzer(TGA), impact tester, universal… More >

Zehui Ju¹, Qian He¹, Tianyi Zhan¹, Haiyang Zhang^1,*, Lin Sun¹, Lu Hong¹, Xinyi Shi², Xiaoning Lu^1,*

Journal of Renewable Materials, Vol.7, No.11, pp. 1077-1091, 2019, DOI:10.32604/jrm.2019.07525 - 14 July 2021

Abstract In this study, steam exploded peanut shell fibers (SE-PSFs) were utilized to fabricate with rigid polyurethane foam (RPUF) in order to improve sound absorption performance and hydrothermal weather resistance. Optimized method of SE treatment, RPUF preparation and flame retardant treatment were selected to prepare SE-PSF/RPUF composites in this experiment. Physical and mechanical properties including density, water absorption capacity, thickness swelling rate, compressive strength, thermal conductivity and average sound absorption coefficient of SE-PSF/RPUF were investigated and compared with the control (PRUF). The results showed that the density, water absorption capacity, thickness swelling rate and thermal conductivity More >

Fouad LAOUTID^1,*, Valeriia KARASEVA¹, Lucie COSTES^{1, 2}, Sylvain BROHEZ², Rosica MINCHEVA¹, Philippe DUBOIS¹

Journal of Renewable Materials, Vol.6, No.6, pp. 559-572, 2018, DOI:10.32604/JRM.2018.00004

Abstract In this study, tannic acid (TA) was investigated as flame retardant agent for PLA. Different strategies to modify its thermal degradation pathway have been explored in order to improve its charring effect. The first one consists in combining TA with organomodified montmorillonite (oMMT), and enables limiting the thermo-oxidative degradation of TA and promoting the formation of an effective char layer. Flame-retardant (FR) behavior of PLA-based composition has been found to be positively impacted by this combination since a reduction of the peak of Heat Release Rate (PHRR), more important than the value recorded when oMMT More >

Mfiso Emmanuel Mngomezulu¹, Adriaan Stephanus Luyt², Steve Anthony Chapple³, Maya Jacob John^3,4*

Journal of Renewable Materials, Vol.6, No.1, pp. 26-37, 2018, DOI:10.7569/JRM.2017.634140

Abstract This work reports on the effect of commercial expandable graphite (EG) on the flammability and thermal decomposition properties of PLA-starch blend. The PLA-starch/EG composites were prepared by melt-mixing and their thermal stability, volatile pyrolysis products and flammability characteristics were investigated. The char residues of the composites, after combustion in a cone calorimeter, were analyzed with environmental scanning electron microscopy (ESEM). The thermal decomposition stability of the composites improved in the presence of EG. However, the char content was less than expected as per the combination of the wt% EG added into PLA-starch and the %… More >