Dinesh Balgude, Anagha Sabnis^*

Journal of Renewable Materials, Vol.2, No.3, pp. 235-245, 2014, DOI:10.7569/JRM.2014.634115

Abstract Renewable resource-based hybrid crosslinker was successfully synthesized via sol-gel technology. The synthesis involved malenization of Cashew Nut Shell Liquid (CNSL) followed by its silane modifi cation and subsequent hydrolysis and condensation with tetraethyl orthosilicate (TEOS). The synthesized crosslinker was characterized by spectroscopic analysis (FT-IR, ¹ H-NMR, ¹³C-NMR and ²⁹Si-NMR) for structural elucidation. The crosslinker was further formulated in a conventional stoving system. Fully-cured coatings were obtained after stoving at 120°C for ½ hr and were then evaluated for physical, mechanical, chemical, optical, accelerated weathering, electrochemical and morphological properties. The incorporation of hybrid crosslinker in a conventional stoving system was observed… More >

Zhengyang Li¹, Wei Guo^1,*, Yueyang Hu¹, Xiao Wang¹, Binbin Qian², Cuifeng Jiang¹

Journal of Renewable Materials, Vol.10, No.11, pp. 2921-2935, 2022, DOI:10.32604/jrm.2022.019258

Abstract Ternesite (4CaO·2SiO₂·CaSO₄)-Ye’elimite (3CaO·3Al₂O₃·CaSO₄) (simplified as TY) cement clinker was successfully prepared from steel slag at 1200°C in this study. XRD, TG/DSC and SEM were used to analyze the mineral composition and hydration products of the TY clinker. The sintering process and hydration mechanism of the TY clinker were investigated. Results show that a large amount of ternesite and ye’elimite have been formed at 1200°C, while ternesite has not been decomposed. Clinker minerals include ternesite, ye’elimite, gypsum and a small amount of iron phase. Iron phase from steel slag can promote the formation of liquid phase with the presence of gypsum… More >

Jingjing Liao^1,2, Jinxing Li², Fuxian Yang², Yan Zhu², Hongyan Wang³, Guanben Du^1,2,*, Hisham Essawy⁴, Xiaojian Zhou^2,*

Journal of Renewable Materials, Vol.10, No.2, pp. 359-372, 2022, DOI:10.32604/jrm.2021.016335

Abstract Polyvinyl alcohol (PVA)-based films containing Chinese bayberry tannin (BT) were prepared by cross-linking using glyoxal, glutaraldehyde and dialdehyde starch, individually. The presence of cross-linkers was evident to promote the transparency and decrease the moisture content of PVA/BT films, while the water solubility stayed almost unchanged in the cross-linked PVA/BT films. All cross-linkers provided promotion of the water vapor permeability, mechanical property and thermal stability of PVA/BT films. The best water vapor barrier capacity was found in case of glutaraldehyde cross-linked PVA/BT film, while the highest tensile strength was encountered in case of glyoxal cross-linked PVA/BT films, compared with the uncross-linked… More > Graphic Abstract

Yanrong Zhao^1,2,3,#, Ping Chen^1,4,*,#, Shifeng Wang⁵, Yaxiong Ji^3,4, Yuanhao Wang^3,4,*, Bolin Wu^1,2, Rongjin Liu¹

Journal of Renewable Materials, Vol.8, No.11, pp. 1531-1541, 2020, DOI:10.32604/jrm.2020.011462

Abstract Bayer red mud (BRM) is a kind of industrial solid waste characterized by huge volume and high alkalinity. Its disposal generates serious environmental pollution and occupies a large number of farmland. The utilization and recycling of BRM is currently a crucial issue and needs to be addressed as soon as possible. The chemical composition of BRM is similar to cement clinker. In this study, the feasibility of preparing Belite-ferroaluminate clinker (BFAC) with different BRM was explored. The physical properties, mechanics performance, radioactivity levels and trace harmful metals leaching were measured. XRD, BEI and EDS were used to characterize the mineral… More >

Xiaoliang Zhao^1,#, Yuting Wang^1,#, Xiuying Pu¹, Jianzhong Ma¹, Feifan Leng¹, Yonggang Wang¹, Yanling Wang¹, Shuhong Yang¹, Fen Ran², Weijie Zhang^1,*

Journal of Renewable Materials, Vol.7, No.12, pp. 1321-1332, 2019, DOI:10.32604/jrm.2019.07757

Abstract A series of the Guiqi polysaccharides/chitosan/alginate composite hydrogel microspheres (GPcM) with different particle sizes were prepared with Guiqi polysaccharides (GP), chitosan (CS) and sodium alginate (Alg). The optimum preparation process was also determined by single factor and orthogonal experiment analysis. The GPcM were characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), drug loading efficiency test (LE), encapsulation efficiency test (EE) and in vitro release study. The results showed that the Guiqi polysaccharides chitosan hydrogel (GPCH) and sodium alginate hydrogel (SAH) formed a crossover system in GPcM. The GPcM have a uniform particle size ranging from 395.1μm to… More >

Qi Dang¹, Chun-Gong Li¹, Xin-Xin Jin¹, Ya-Jin Zhao¹, Xiang Wang^1,*

Molecular & Cellular Biomechanics, Vol.16, Suppl.2, pp. 146-146, 2019, DOI:10.32604/mcb.2019.07074

Abstract Endotoxin is a a very powerful and toxic inflammatory stimulator usually leading to the sepsis occurred. In order to remove endotoxin better through hemoperfusion, it is a pretty choice to increase the length of molecular linker on adsorbents. In this study, we chose the heparin as a molecular linker because of its being anticoagulant linear polysaccharide. Heparin as a linker was covalently immobilized on the chloromethylated polystyrene microspheres (Ps) and then connected with L-phenylalanine (Phe) forming the Ps-Hep-Phe structure to adsorbed endotoxin better. The property of microspheres was characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, zeta potential and… More >

Kunal Wazarkar, Anagha Sabnis*

Journal of Renewable Materials, Vol.6, No.4, pp. 438-449, 2018, DOI:10.7569/JRM.2017.634159

Abstract The research work presented in this article deals with the synthesis of cardanol-based polyol and its curing with hexabutoxymethyl melamine (HBMM) for application in coatings. Cardanol-based polyol was prepared via thiol-ene click reaction using thioglycerol. Unsaturation present in the long chain of cardanol was successfully utilized to synthesize polyol via thiol-ene coupling. The reaction was carried out between cardanol and thioglycerol in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) under UV light for 12 h at 80 °C. After completion of the reaction, one mole of thioglycerol was successfully added across the double bond of a fatty chain… More >