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  • Open Access

    ARTICLE

    Biodegradable and Biocompatible Polyvinyl alcohol/ Silk Fibroin-Based Composite with Improved Strength

    XINGMIN XU1, QINGQING SUN2, AIRONG XU2, XINBAO GUO2

    Journal of Polymer Materials, Vol.39, No.1-2, pp. 167-181, 2022, DOI:10.32381/JPM.2022.39.1-2.11

    Abstract Silk fibroin (SF) with renewability, biocompatibility and biodegradability shows potential application in various fields including biomedicine, tissue engineering, and wearable electronic devices. Herein, SF is used to exert effective reinforcement of polyvinyl alcohol (PVA) composite film to further improve its practicability. As such, PVA/SF composite films were prepared for the first time using a facile approach. The films were characterized to investigate possible interaction of PVA with SF. Meanwhile, systematic investigations have also been completed to explore the influences of PVA/SF mass ratio on the mechanical properties (tensile strength, elongation at break), biodegradability and biocompatibility, the morphology, crystallinity, chemical structure… More >

  • Open Access

    ARTICLE

    Characteristic of Fresh and Harden Properties of Polyvinyl Alcohol Fibre Reinforced Alkali Activated Composite

    Yiguang Wang1,2, Zhe Zhang1, Xun Zhang1,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1321-1337, 2023, DOI:10.32604/jrm.2022.023266

    Abstract Fibre can enhance the mechanical properties of cement-based composites, but fibre also degrades their workability. However, the quantitative effects of fiber content and length-diameter ratio on alkali-activated materials are still unclear. Various aspect ratio, volume fraction of polyvinyl alcohol fibre (PVAF), and various water-binder ratio were employed to prepare a total of 26 groups of fibre reinforced alkali-activated composite (FRAAC). The influence of PVAF fibre factor (product of fiber volume fraction and length-diameter ratio) on flowability, compactness, strength, and crack fractal dimension of FRAAC was researched. The influence of water-binder ratio on the plastic viscosity of FRAAC was more significant… More >

  • Open Access

    ARTICLE

    Preparation of Film Based on Polyvinyl Alcohol Modified by Alkaline Starch and Lignin Fiber

    Yunxia Zhou1, Hisham Essawy2, Ai Liu1, Chenyu Yang1, Defa Hou1, Xiaojian Zhou1,*, Guanben Du1, Jun Zhang1,*

    Journal of Renewable Materials, Vol.11, No.2, pp. 837-852, 2023, DOI:10.32604/jrm.2022.022792

    Abstract This study presents an easily prepared film based on alkaline starch-polyvinyl alcohol hybrid and lignin fiber as an additive (SPL film). The SPL film was prepared under acidic conditions through a polycondensation reaction of PVA and a mixture incorporating alkaline starch and lignin fiber from agriculture or forest source. The examination using scanning electron microscopy (SEM) showed that the surface of SPL film was smooth and the lignin fiber had good compatibility within the film hybrid. Electrospray ionization mass spectroscopy (ESI-MS) and fourier transform infrared (FTIR) investigations indicated that alkaline starch and lignin fiber reacted with PVA under acidic conditions… More > Graphic Abstract

    Preparation of Film Based on Polyvinyl Alcohol Modified by Alkaline Starch and Lignin Fiber

  • Open Access

    ARTICLE

    Synthesis and Characterization of Hydrogels Based on Potato Starch/Poly(vinyl Alcohol)/N,N′-Methylenebisacrylamide

    Diego David Pinzón-Moreno*, Eder Clidio Vicuña-Galindo, José Vulfrano González-Fernández, José Luis Soto-Gonzales, María Verónica Carranza-Oropeza*

    Journal of Renewable Materials, Vol.10, No.8, pp. 2179-2201, 2022, DOI:10.32604/jrm.2022.019793

    Abstract Several hydrogels were synthesized by free-radical polymerization in an aqueous medium based on potato starch (PS), poly(vinyl alcohol) (PVA), and N,N′-Methylenebisacrylamide (MBAm), being possible to study these hydrogels as a function of the proportion of components incorporated. In this way, the products generated from the synthesis were characterized by swelling and deswelling kinetics, the first swelling being verified with Schott and statistical models, allowing to contrast the proximity between the experimental and theoretical behavior. Additionally, water retention in soil (R%), spectroscopy (FTIR), morphological (SEM), and thermal (TGA and DSC) analysis allowing to know the intrinsic characteristics of the material, increasing… More >

  • Open Access

    ARTICLE

    Laboratory Evaluation of Fiber-Modified Asphalt Mixtures Incorporating Steel Slag Aggregates

    Adham Mohammed Alnadish1,*, Mohamad Yusri Aman1, Herda Yati Binti Katman2, Mohd Rasdan Ibrahim3

    CMC-Computers, Materials & Continua, Vol.70, No.3, pp. 5967-5990, 2022, DOI:10.32604/cmc.2022.017387

    Abstract Vigorous and continued efforts by researchers and engineers have contributed towards maintaining environmental sustainability through the utilization of waste materials in civil engineering applications as an alternative to natural sources. In this study, granite aggregates in asphaltic mixes were replaced by electric arc furnace (EAF) steel slag aggregates with different proportions to identify the best combination in terms of superior performance. Asphalt mixtures showing the best performance were further reinforced with polyvinyl alcohol (PVA), acrylic, and polyester fibers at the dosages of 0.05%, 0.15%, and 0.3% by weight of the aggregates. The performance tests of this study were resilient modulus,… More >

  • Open Access

    ARTICLE

    Assisted Compatibility, and Balanced Regulation of the Mechanical, Thermal, and Antioxidant Activity of Polyvinyl Alcohol-Chinese Bayberry Tannin Extract Films Using Different Di-Aldehydes as Cross-Linkers

    Jingjing Liao1,2, Jinxing Li2, Fuxian Yang2, Yan Zhu2, Hongyan Wang3, Guanben Du1,2,*, Hisham Essawy4, Xiaojian Zhou2,*

    Journal of Renewable Materials, Vol.10, No.2, pp. 359-372, 2022, DOI:10.32604/jrm.2021.016335

    Abstract Polyvinyl alcohol (PVA)-based films containing Chinese bayberry tannin (BT) were prepared by cross-linking using glyoxal, glutaraldehyde and dialdehyde starch, individually. The presence of cross-linkers was evident to promote the transparency and decrease the moisture content of PVA/BT films, while the water solubility stayed almost unchanged in the cross-linked PVA/BT films. All cross-linkers provided promotion of the water vapor permeability, mechanical property and thermal stability of PVA/BT films. The best water vapor barrier capacity was found in case of glutaraldehyde cross-linked PVA/BT film, while the highest tensile strength was encountered in case of glyoxal cross-linked PVA/BT films, compared with the uncross-linked… More > Graphic Abstract

    Assisted Compatibility, and Balanced Regulation of the Mechanical, Thermal, and Antioxidant Activity of Polyvinyl Alcohol-Chinese Bayberry Tannin Extract Films Using Different Di-Aldehydes as Cross-Linkers

  • Open Access

    ARTICLE

    Development of Antioxidant Packaging Film Based on Chinese Bayberry Tannin Extract and Polyvinyl Alcohol

    Jingjing Liao1,2, Jinxing Li2, Hongyan Wang3, Yan Zhu2, Hisham Essawy4, Guanben Du1,2,*, Xiaojian Zhou2,*

    Journal of Renewable Materials, Vol.10, No.1, pp. 19-31, 2022, DOI:10.32604/jrm.2021.016152

    Abstract The current work explores the potential use of commercial Chinese bayberry tannin (BT) to develop antioxidant PVA-based films using solvent casting process for packaging applications. The effect of BT concentration on opacity, water resistance and antioxidant capacity of resulting films was investigated. Properties like tensile strength, thermal behavior, and morphological aspects were also characterized. The experimental results showed that PVA/BT films formed with uniformly brown color and generally good transparency, offering good antioxidant ability. The PVA film containing BT presented slightly higher water resistance according to the results of moisture content and water vapor permeability, especially at low BT content… More > Graphic Abstract

    Development of Antioxidant Packaging Film Based on Chinese Bayberry Tannin Extract and Polyvinyl Alcohol

  • Open Access

    ARTICLE

    Green Synthesis of Silver Nanoparticles Using Plectranthus Amboinicus Leaf Extract for Preparation of CMC/PVA Nanocomposite Film

    Nguyen Thi Thanh Thuy1,*, Le Hoang Huy1, Truong Thuy Vy1, Nguyen Thi Thanh Tam2, Bien Thi Lan Thanh1, Nguyen Thi My Lan3

    Journal of Renewable Materials, Vol.9, No.8, pp. 1393-1411, 2021, DOI:10.32604/jrm.2021.015772

    Abstract In the present study, the biogenic silver nanoparticles have been synthesized using aqueous leaf extract of Plectranthus amboinicus (PA), which acted as both reducing and stabilizing agents. The PA synthesized silver nanoparticles were blended with carboxymethyl cellulose/polyvinyl alcohol (CMC/PVA) biocomposite. The prepared AgNPs as well as the biogenic AgNPs incorporated CMC/PVA films were investigated using UV-visible spectrophotometry, Fourier-transform infrared spectroscopy (FT-IR), dynamic light scattering (DLS), scanning electron microscope (SEM), and X–ray diffraction (XRD). The DLS results showed that biogenic AgNPs had the average particle size of 65.70 nm with polydispersity index of 0.44. The surface plasmon resonance of AgNPs, which… More > Graphic Abstract

    Green Synthesis of Silver Nanoparticles Using <i>Plectranthus Amboinicus</i> Leaf Extract for Preparation of CMC/PVA Nanocomposite Film

  • Open Access

    ARTICLE

    Preparation and Properties of Bio-Based Flame Retardant Polyvinyl Alcohol

    You Shu1,2, Qionglin Luo2, Hongwei Lin2,*, Yuejun Ouyang2, Xiaomin Zhang1,2, Liping Sheng1, Shengpei Su1,2,*

    Journal of Renewable Materials, Vol.9, No.5, pp. 909-921, 2021, DOI:10.32604/jrm.2021.014216

    Abstract Polyvinyl alcohol (PVA) has been widely used in the fields of medical, food and packaging due to its excellent biocompatibility, good fiber-forming and film-forming properties. However, the high flammability of PVA has greatly limited its wider applications. The flame-retardant PVA was prepared by melt blending of a bio-based flame retardant (prepared from lignin, phosphoric acid and carbamide) with thermoplastic PVA (TPVA). The chemical structure, morphology, thermal properties, mechanical properties, fire property and fluidity of this flame retardant PVA were investigated by Fourier transform infrared spectrometer(FTIR), field emission scanning electron microscope(SEM), thermogravimetric analyzer(TGA), impact tester, universal testing machine, horizontal-vertical burning tester,… More >

  • Open Access

    ARTICLE

    Effect of Y-Methacryloxypropyltrimethoxysilane (MPS) and Tetraethoxysilane (TEOS) Towards Preparation of Oil Absorbent Foams from Polyvinyl Alcohol (PVA) Reinforced with Microfibrillated Cellulose (MFC)

    Dzun Noraini Jimat*, Sharifah Shahira Syed Putra, Parveen Jamal, Wan Mohd Fazli Wan Nawawi, Mohammed Saedi Jami

    Journal of Renewable Materials, Vol.8, No.7, pp. 739-757, 2020, DOI:10.32604/jrm.2020.010357

    Abstract Increasing usage of foams in various industry sectors had causing serious disposal problems once it reaches the end of its life-cycle. Herein, PVA-MFC foam was prepared by freeze-drying using polyvinyl alcohol (PVA) and microfibrillated cellulose (MFC) as a reinforced material from sugarcane bagasse (SCB). In this study, the PVA-MFC foam was chemically silylated with Y-methacryloxypropyltrimethoxysilane (MPS) and tetraethoxysilane (TEOS). The wetting ability and mechanical strength of the silylated 2,20PVA-MFC foam was greatly enhanced compared with unmodified 2,20PVA-MFC foam. The silane chemicals (MPS and TEOS) had been confirmed grafted on 2,20PVA-MFC foam due to the presence of Si-C and Si-O-C stretching… More >

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