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  • Open Access

    ARTICLE

    Unveiling Ionic Conductivity and Ion Transport Properties in Polyvinyl Alcohol-Based Gel Polymer Electrolytes with Quaternary Ammonium Iodide

    M. F. Aziz1,2,*, A. A. Rahim1, A. R. M. Rais1,2,*

    Journal of Polymer Materials, Vol.42, No.4, pp. 1097-1109, 2025, DOI:10.32604/jpm.2025.071129 - 26 December 2025

    Abstract To study the behavior of structural dynamics, ionic conductivity and ion transport properties, the gel polymer electrolytes (GPEs) was developed using polyvinyl alcohol in combination with potassium iodide, dimethyl sulfoxide, ethylene carbonate, propylene carbonate and tetra-N-propylammonium iodide (C12H28IN), The GPEs were synthesized via a solution mixing technique, systematically varying the tetra-N-propylammonium iodide concentration to optimize ionic transport properties. The gel polymer electrolytes (GPEs) preparation was initially dissolving the potassium iodide and tetra-N-propylammonium iodide in a measured combination of ethylene carbonate, propylene carbonate, and dimethyl sulfoxide within a glass container. Subsequently, polyvinyl alcohol (PVA) was introduced into… More >

  • Open Access

    ARTICLE

    Innovative Biobased Composites from Oil Palm Trunk: Enhancing Mechanical and Flame-Retardant Properties through Optimized Additive Treatments

    Madihan Yusof1,2,3,*, Muhamad Saiful Sulaiman1,3, Ros Syazmini Mohd Ghani1,3,4, Sofiyah Mohd Razali1,5

    Journal of Renewable Materials, Vol.13, No.10, pp. 2059-2075, 2025, DOI:10.32604/jrm.2025.02025-0101 - 22 October 2025

    Abstract This study investigates the development of an oil palm trunk (OPT) high-performance flame-retardant composite derived from an inexpensive and sustainable biomass source, processed using sodium chloride (NaCl) as a low-cost flame retardant, polyvinyl alcohol (PVA) as an adhesive, and calcium carbonate (CaCO3) as an additive. The work aims to address the inherent flammability of OPT and to enhance its mechanical performance, dimensional stability, and fire resistance in an environmentally friendly and cost-effective manner. Results indicate that a 10% NaCl treatment optimally improves the performance of the composite, increasing bending strength (MOR) from 5.95 to 12.61 MPa… More > Graphic Abstract

    Innovative Biobased Composites from Oil Palm Trunk: Enhancing Mechanical and Flame-Retardant Properties through Optimized Additive Treatments

  • Open Access

    ARTICLE

    Influence of LiCF3SO3 on the Conductivity and Other Characteristics of Methylcellulose/PVA Blend-Based Electrolytes

    Nurrul Asyiqin Shamsuri1, Zamil Khairuddin2, Muhamad Hafiz Hamsan3, Norhana Abdul Halim4, Mohd Fakhrul Zamani Kadir1,5, Muhammad Fadhlullah Shukur6,7,*

    Journal of Polymer Materials, Vol.42, No.3, pp. 729-742, 2025, DOI:10.32604/jpm.2025.069060 - 30 September 2025

    Abstract Polymeric materials have emerged as a promising alternative to electrolytic solutions in energy storage applications. However, high crystallinity and poor ionic conductivity are the main barriers restricting their daily application. In this study, we propose a polymer electrolyte system consisting of methylcellulose-polyvinyl alcohol (MC-PVA) blend as host material and lithium trifluoromethanesulfonate (LiCF3SO3) as dopant, which was prepared using the solution-casting method. The electrochemical impedance spectroscopy (EIS) analysis revealed a maximum conductivity of 5.42 × 10−6 S cm−1 with 40 wt.% LiCF3SO3. The key findings demonstrated that the variation in the dielectric loss (εi) and dielectric constant (εr) was… More >

  • Open Access

    ARTICLE

    Sustainable Removal of Cu2+ and Pb2+ Ions via Adsorption Using Polyvinyl Alcohol/Neem Leaf Extract/Chitosan (From Shrimp Shells) Composite Films

    Deepti Rekha Sahoo, Trinath Biswal*

    Journal of Polymer Materials, Vol.42, No.3, pp. 811-835, 2025, DOI:10.32604/jpm.2025.067022 - 30 September 2025

    Abstract The purpose of this research work is to determine the removal efficiency of Cu2+ and Pb2+ ions using polyvinyl alcohol/neem leaf extract/chitosan (PVA/NLE/CS) composite films as adsorbent materials from an aqueous medium, with respect to pH, contact time, and adsorbent dosage. The synthesized composite material was characterized using Fourier Transform Infrared (FTIR) spectroscopy, thermogravimetric analysis-Derivative Thermogravimetry (TGA-DTG), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy-Energy Dispersive X-ray Spectroscopy (SEM-EDX). The antibacterial activity and swelling response of the material were studied using suitable methodologies. The FTIR study confirmed the interactions among PVA, chitosan, and… More >

  • Open Access

    ARTICLE

    Boosting Structural and Dielectric Properties of Polyvinyl Alcohol/Starch/Carboxymethyl Cellulose Films with Iron-Doped Carbon Quantum Dots for Advanced Applications

    Lekaa K. Abdul Karem1, Badriah Saad Al-Farhan2, Ghada M. G. Eldin3, Samir Kamel4, Ahmed M. Khalil5,*

    Journal of Renewable Materials, Vol.13, No.7, pp. 1459-1473, 2025, DOI:10.32604/jrm.2025.02025-0046 - 22 July 2025

    Abstract In this study, the casting process is used to fabricate modified polyvinyl alcohol (PVA), starch (S), and carboxymethyl cellulose (CMC) polymer blend films (PVA/S/CMC) loaded with various concentrations of iron-doped carbon quantum dots (Fe-CQDs) and denoted as (PVA/S/CMC@Fe-CQDs). A one-step microwave strategy was employed as a facile method to prepare Fe-CQDs. Through a series of characterization techniques, fourier-transform infrared (FTIR) spectroscopy, x-ray diffraction (XRD) analysis, and scanning electron microscopy (SEM) have been used to show the successful integration of Fe-CQDs into the PVA/S/CMC matrix. Loading the synthesized Fe-CQDs to the polymeric matrix significantly enhanced the… More > Graphic Abstract

    Boosting Structural and Dielectric Properties of Polyvinyl Alcohol/Starch/Carboxymethyl Cellulose Films with Iron-Doped Carbon Quantum Dots for Advanced Applications

  • Open Access

    ARTICLE

    Immittance Response Alginate-Polyvinyl Alcohol Bio-Polymer Blend Electrolytes Doped with Ammonium Iodide

    M. A. H. Nizam1, A. F. Fuzlin1,2, A. S. Samsudin1,2,*

    Journal of Polymer Materials, Vol.42, No.1, pp. 173-185, 2025, DOI:10.32604/jpm.2025.059244 - 27 March 2025

    Abstract This work explores the dielectric and electrochemical properties of solid biopolymer blend electrolytes (SBEs) based on a combination of alginate and polyvinyl alcohol (PVA), doped with varying concentrations of ammonium iodide (NH4I). The SBEs were synthesized using the solution casting method, and their ac conductivity exhibited an optimal value of 1.01 × 10−5 S · cm−1 at 25 wt.% NH4I. Detailed dielectric and modulus spectroscopy analyses revealed distinctive trends in relation to NH4I concentration, suggesting complex dielectric relaxation behavior. The universal power law (UPL) analysis identified the Small Polaron Hopping (SPH) mechanism as the dominant conduction process in More >

  • Open Access

    ARTICLE

    Graphite/Polyvinyl Alcohol Hydrogels with Fluoride and Iodine Deionization for Solar-Driven Interfacial Evaporation

    Ziyang Qiu1,2, Hanjun Yang1,2,*

    Journal of Polymer Materials, Vol.41, No.4, pp. 329-340, 2024, DOI:10.32604/jpm.2024.057953 - 16 December 2024

    Abstract Hydrogels are emerging as promising candidates for solar-driven interfacial evaporation in water purification. Our research introduces a graphite polyvinyl alcohol hydrogel (GPVA) evaporator designed as a photothermal conversion interface, showcasing high performance with an evaporation rate of 2.43 kg m−2 h−1 and an efficiency of 91.9% under solar irradiance of 1 kW m−2. The layered graphite structure of the GPVA hydrogel enhances its ion and dye adsorption capabilities, effectively removing fluoride, iodine, and other contaminants from water. In cyclic evaporation tests, the GPVA hydrogel evaporator demonstrated remarkable stability and long-term durability, maintaining an evaporation rate of 2.43 More >

  • Open Access

    ARTICLE

    Bio-Nanocomposites Based on Polyvinyl Alcohol and Fuller Earth Nanoclay: Preparation, Properties and Its Application in Food Packaging

    Yvonne Achieng Ouma1, Supriti Sundari Nayak1, Smrutirekha Mishra2, Harekrishna Panigrahi1,*

    Journal of Polymer Materials, Vol.41, No.4, pp. 281-297, 2024, DOI:10.32604/jpm.2024.056470 - 16 December 2024

    Abstract Fuller earth (FE) nanoclay is a naturally occurring mineral with a high surface area, is highly abundant, and has a low purchasing cost, making it an excellent candidate for nanocomposite production. The study highlights the novelty of using FE nanoclay in combination with polyvinyl alcohol (PVA) to create a bio-nanocomposite that meets the need for sustainable packaging solutions, underscoring its potential to reduce environmental impact while maintaining product quality in food packaging applications. The solvent casting process, a reliable way to evenly disperse nanofillers in polymer matrices, has been employed in this work to incorporate… More >

  • Open Access

    ARTICLE

    Characterization of new hybrid composites of PVA-Fe2O3-CdZnS

    K. A. Mohammeda,*, N. H. J. Al Hasanb, L. R. Al-Ameerc, D. S. Abdul-Zahrad, Y. D. Dwivedie, K. H. Salemf, M. K. Agarwalg, R. S. Zabibahh, M. A. Alkhafajii

    Chalcogenide Letters, Vol.20, No.8, pp. 599-608, 2023, DOI:10.15251/CL.2023.208.599

    Abstract This study examined the properties of polyvinyl alcohol (PVA) as a matrix composite, specifically focusing on the characterization techniques of UV-Visible spectroscopy, X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDX). The investigation centered around a novel hybrid structure composed of CdZnS nanoparticles implanted within a composite matrix of PVA and Fe2O3. The analysis of microstructure data provided evidence of the influence of CdZnS nanoparticles on the structural characteristics of PVA–Fe2O3. The composites that were synthesized exhibited significant absorption peaks at wavelengths of 233 nm and 234 nm for PVA-Fe2O3 and PVA-Fe2O3-CdZnS, respectively. More >

  • Open Access

    ARTICLE

    Characteristic of Fresh and Harden Properties of Polyvinyl Alcohol Fibre Reinforced Alkali Activated Composite

    Yiguang Wang1,2, Zhe Zhang1, Xun Zhang1,*

    Journal of Renewable Materials, Vol.11, No.3, pp. 1321-1337, 2023, DOI:10.32604/jrm.2022.023266 - 31 October 2022

    Abstract Fibre can enhance the mechanical properties of cement-based composites, but fibre also degrades their workability. However, the quantitative effects of fiber content and length-diameter ratio on alkali-activated materials are still unclear. Various aspect ratio, volume fraction of polyvinyl alcohol fibre (PVAF), and various water-binder ratio were employed to prepare a total of 26 groups of fibre reinforced alkali-activated composite (FRAAC). The influence of PVAF fibre factor (product of fiber volume fraction and length-diameter ratio) on flowability, compactness, strength, and crack fractal dimension of FRAAC was researched. The influence of water-binder ratio on the plastic viscosity… More >

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