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  • Open Access

    ARTICLE

    Two-Step Preparation of Hierarchical Porous Carbon Materials Derived from Tannin for Use as an Electrode Material for Supercapacitors

    Jianping Deng1, Qianqian Zhang1, Yuling Lan1, Lingcong Luo1, Zimin Dai1, Zhonghang Lin1, Zhixin Lu1, Jiancheng Yuan1, Yiqi Fu1, Lu Luo2,*, Weigang Zhao1,*

    Journal of Renewable Materials, Vol.11, No.6, pp. 2631-2646, 2023, DOI:10.32604/jrm.2023.027163

    Abstract The development and utilization of biomass and agroforestry processing byproducts for high-value applications have been an important topic in the field of renewable materials research. Based on this, a two-step microwave hydrothermal pre-carbonization and KOH activation method was proposed to synthesize tannin-based activated carbons with a high specific surface area, hierarchical pore structure, and good electrochemical performance. The microstructure, texture properties, and physicochemical characteristics were investigated. The results show that the prepared tannin-based activated carbons presented a hierarchical pore structure (micro- and mesopores) with a specific surface area as high as 997.46 m3 g−1 . The electrochemical analysis shows that… More > Graphic Abstract

    Two-Step Preparation of Hierarchical Porous Carbon Materials Derived from Tannin for Use as an Electrode Material for Supercapacitors

  • Open Access

    ARTICLE

    Controlled-Release of Plant Volatiles: New Composite Materials of Porous Carbon-Citral and Their Fungicidal Activity against Exobasidium vexans

    Yaoguo Liu1, Yao Chen2, Huifang Liu2, Wei Chen1, Zhiwei Lei2, Chiyu Ma2, Jie Yin1, Wen Yang2,*

    Journal of Renewable Materials, Vol.11, No.2, pp. 811-823, 2023, DOI:10.32604/jrm.2022.022594

    Abstract Citral (Eo) exhibits excellent fungicidal activities. However, it is difficult to maintain long-term fungicidal activity due to its strong volatility. Herein, a controlled-release strategy by using biomass-derived porous carbon (BC) was developed to overcome the drawback of Eo. New composite materials were prepared by loading Eo on tea stem porous carbon (BC@Eo), and their controlled-release fungicidal activity against Exobasidium vexans was assessed. BC with a large specific surface area of 1001.6 m2/g and mesoporous structure was fabricated through carbonization temperature of 700°C. The BC@Eo materials were characterized using Fourier-transform infrared spectroscopy and X-ray powder diffraction. The results suggested that chemical… More > Graphic Abstract

    Controlled-Release of Plant Volatiles: New Composite Materials of Porous Carbon-Citral and Their Fungicidal Activity against <i>Exobasidium vexans</i>

  • Open Access

    ARTICLE

    Study on Preparation of Nitrogen-Doped Hierarchically Porous and High-Performance Carbon Materials from Seaweed Biomass

    Kaihan Xie1, Yamin Hu1,*, Stephen Afonaa-Mensah2, Chuan Yuan1, Bin Cao1, Shuang Wang1,*, Qian Wang1

    Journal of Renewable Materials, Vol.10, No.2, pp. 541-560, 2022, DOI:10.32604/jrm.2022.017911

    Abstract Use Enteromorpha clathrate as a carbon and nitrogen precursor could obtain the N-doped porous carbon materials by two-step pyrolysis. In this paper, the exogenous nitrogen (urea, melamine) and activating agents (KOH, ZnCl2) were employed for the production of higher-performance carbon materials from seaweed biomass. SEM, BET, FTIR, XRD, XPS, Raman and ultimate analyses were carried out to investigate the morpho-structural and elemental peculiarities of the carbonaceous materials. Moreover, cyclic voltammetry (CV) , galvanostatic charge-discharge (GCD) and cyclic charge-discharge tests were carried out to examine the electrochemical properties of the samples. The results showed that electrochemical performance of the carbonaceous materials… More > Graphic Abstract

    Study on Preparation of Nitrogen-Doped Hierarchically Porous and High-Performance Carbon Materials from Seaweed Biomass

  • Open Access

    ARTICLE

    Novel Magnetically Interconnected Micro/Macroporous Structure of Monolithic Porous Carbon Adsorbent Derived from Sodium Alginate and Wasted Black Liquor and Its Adsorption Performance**

    Parichart Onsri1, Decha Dechtrirat2,3,4, Patcharakamon Nooeaid5, Apiluck Eiad-ua6, Pongsaton Amornpitoksuk1,7, Supanna Techasakul4, Ahmad Taufiq8, Laemthong Chuenchom1,7,*

    Journal of Renewable Materials, Vol.9, No.6, pp. 1059-1074, 2021, DOI:10.32604/jrm.2021.013362

    Abstract The novel and facile preparation of magnetically interconnected micro/ macroporous structure of monolithic porous carbon adsorbent (MPCA) were designed and presented herein. The synthesis was achieved via conventional freeze-drying and pyrolysis processes. In this study, sodium alginate and wasted black liquor were employed as starting precursors. Sodium alginate acts as a template of materials, whereas black liquor, the wasted product from the paper industry with plentiful of lignin content and alkaline solution, played an essential role in the reinforcement and activation of porosity for the resulting materials. Moreover, both the precursors were well dissolved in Fe3+ solution, providing a simple… More >

  • Open Access

    REVIEW

    Utilization of Nanomaterials as Anode Modifiers for Improving Microbial Fuel Cells Performance

    Nishit Savla1, Raksha Anand2, Soumya Pandit2,*, Ram Prasad3,*

    Journal of Renewable Materials, Vol.8, No.12, pp. 1581-1605, 2020, DOI:10.32604/jrm.2020.011803

    Abstract Microbial fuel cells (MFCs) are an attractive innovation at the nexus of energy and water security for the future. MFC utilizes electrochemically active microorganisms to oxidize biodegradable substrates and generate bioelectricity in a single step. The material of the anode plays a vital role in increasing the MFC’s power output. The anode in MFC can be upgraded using nanomaterials providing benefits of exceptional physicochemical properties. The nanomaterials in anode gives a high surface area, improved electron transfer promotes electroactive biofilm. Enhanced power output in terms of Direct current (DC) can be obtained as the consequence of improved microbe-electrode interaction. However,… More >

  • Open Access

    ARTICLE

    Classification and Optimization Model of Mesoporous Carbons Pore Structure and Adsorption Properties Based on Support Vector Machine

    Zhen Yang1, Xingsheng Gu2, Xiaoyi Liang1,3

    CMES-Computer Modeling in Engineering & Sciences, Vol.74, No.3&4, pp. 161-182, 2011, DOI:10.3970/cmes.2011.074.161

    Abstract Mesoporous carbons are synthesized by organic-organic self-assembly of triblock copolymer F127 and a new type of carbon precursor as resorcinol-furfural oligomers. Some factors will impact the mesoporous carbons pore structure and properties were studied. The main factors, such as the ratio of triblock copolymer F127 and oligomers, degree of polymerizstry of resorcinol-furfural oligomers, the ratio of resorcinol-furfural oligomers - F/R, and their mutual relations were identified. Aimed at balancing the complex characteristic of mesoporous structure and adsorption properties, a classification and optimization model based on support vector machine is developed. The optimal operation conditions of Barret-Joyner-Halenda (BJH) adsorption cumulative volume… More >

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