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  • Open Access

    ARTICLE

    Enhancing Hydrocarbon-Rich Bio-Oil Production via Catalytic Pyrolysis Fortified with Microorganism Pretreatment

    Jiapeng Wang1, Bo Zhang1,*, Haoqiang Cheng1, Zhixiang Xu2

    Journal of Renewable Materials, Vol.11, No.10, pp. 3595-3612, 2023, DOI:10.32604/jrm.2023.030005 - 10 August 2023

    Abstract A new method of pretreatment of corn straw with Phanerochaete chrysosporium combined with pyrolysis was proposed to improve the quality of bio-oil. The characterization results demonstrated that microbial pretreatment was an effective method to decrease the lignin, which can achieve a maximum removal rate of 44.19%. Due to the destruction of biomass structure, the content of alkali metal and alkaline earth metal is reduced. Meanwhile, the depolymerized biomass structure created better pyrolysis conditions to promote the pyrolysis efficiency, increase the average decomposition rate of pyrolysis and reduce the residue. In fast pyrolysis, because of the enrichment… More > Graphic Abstract

    Enhancing Hydrocarbon-Rich Bio-Oil Production via Catalytic Pyrolysis Fortified with Microorganism Pretreatment

  • Open Access

    ARTICLE

    Spatio-Temporal Characteristics of Heat Transfer of Methanation in Fluidized Bed for Pyrolysis and Gasification Syngas of Organic Solid Waste

    Danyang Shao1, Xiaojia Wang1,*, Delu Chen1, Fengxia An1,2

    Journal of Renewable Materials, Vol.11, No.10, pp. 3659-3680, 2023, DOI:10.32604/jrm.2023.029220 - 10 August 2023

    Abstract Methanation is an effective way to efficiently utilize product gas generated from the pyrolysis and gasification of organic solid wastes. To deeply study the heat transfer and mass transfer mechanisms in the reactor, a successful three-dimensional comprehensive model has been established. Multiphase flow behavior and heat transfer mechanisms were investigated under reference working conditions. Temperature is determined by the heat release of the reaction and the heat transfer of the gas-solid flow. The maximum temperature can reach 951 K where the catalyst gathers. In the simulation, changes in the gas inlet velocity and catalyst flow… More >

  • Open Access

    ARTICLE

    Catalytic Pyrolysis of Soybean Oil with CaO/Bio-Char Based Catalyst to Produce High Quality Biofuel

    Lujiang Xu, Geliang Xie, Xianjun Zhou, Yucheng Liu, Zhen Fang*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3107-3118, 2022, DOI:10.32604/jrm.2022.020691 - 14 July 2022

    Abstract In this paper, CaO/bio-char was synthesized by directly co-pyrolysis of Ca(OH)2 and rice straw, and used as catalyst to catalytic pyrolysis of soybean oil to produce high quality biofuel. In this co-pyrolysis process, CaO particles has been successfully embedded on the bio-char surface. During the catalytic pyrolysis process, CaO/bio-char showed a good catalytic performance on the deoxygenation of soybean oil. Pyrolysis temperature affected the pyrolysis reactions and pyrolytic products distributions dramatically, higher pyrolysis temperature lead to seriously cracking reactions, lower bio-oil yield and higher gases yield, and lower pyrolysis temperature lead to higher bio-oil yield with More > Graphic Abstract

    Catalytic Pyrolysis of Soybean Oil with CaO/Bio-Char Based Catalyst to Produce High Quality Biofuel

  • Open Access

    ARTICLE

    Preparation of Kenaf Biochar and Its Adsorption Properties for Methylene Blue

    Xin Wan1,2,#, Zhigang Xia3,4,#, Xiaoli Yang1,2, Chengfeng Zhou2, Yuanming Zhang1,2, Haoxi Ben1,2, Guangting Han1,2, Wei Jiang1,2,*

    Journal of Renewable Materials, Vol.10, No.12, pp. 3391-3404, 2022, DOI:10.32604/jrm.2022.021102 - 14 July 2022

    Abstract The toxic dyestuffs from printing and dyeing wastewater have caused serious damages to the ecological environment, thus exploring effective methods to remove them having become a key topic. Here, a series of biochar samples were synthesized form kenaf to adsorb methylene blue (MB), which was acted as the dye representative for the test of adsorption capacity due to the presence of abundant double bond and aromatic heterocyclic ring. By tuning the raw materials and pyrolysis temperature, a super adsorption capacity about 164.21 mg·g–1 was obtained over the biochar that pyrolyzed at 700°C with the kenaf fiber… More >

  • Open Access

    ARTICLE

    Effect of Active Zeolite in the Pyrolysis of Polypropylene and Low Density Polyethylene Types of Plastic Waste

    Aman Santoso1,*, Amirotus Sholikhah1, Sumari Sumari1, Muhammad Roy Asrori1, Anugrah Ricky Wijaya1, Rini Retnosari1,2, Ihsan Budi Rachman1,3

    Journal of Renewable Materials, Vol.10, No.11, pp. 2781-2789, 2022, DOI:10.32604/jrm.2022.021401 - 29 June 2022

    Abstract Plastic is a basic need for humans, but it has also caused big problems for the environment. Then, the purpose of this study was to determine the effect of the type of plastic and the addition of a zeolite catalyst on the oil yield from the pyrolysis of plastic waste. The research stages were natural zeolite activation, pyrolysis reactor settings, pyrolysis of plastic waste (PP and LDPE types), and characterization. The results showed that the used natural zeolite had a mordenite phase and activated natural zeolite had a higher Si/Al ratio than the inactivated one.… More > Graphic Abstract

    Effect of Active Zeolite in the Pyrolysis of Polypropylene and Low Density Polyethylene Types of Plastic Waste

  • Open Access

    ARTICLE

    Desorption Behavior and Thermogravimetric Analysis of Bio-Hardeners

    Benoit Ndiwe1,2,3, Antonio Pizzi4,*, Hubert Chapuis5, Noel Konai6, Lionel Karga7, Pierre Girods4, Raidandi Danwe6,8

    Journal of Renewable Materials, Vol.10, No.8, pp. 2015-2027, 2022, DOI:10.32604/jrm.2022.019891 - 25 April 2022

    Abstract In this work, the thermal degradation and drying of bio-hardeners are investigated. Four bio-hardeners based on exudates of Senegalia senegal, Vachellia nilotica, Vachellia seyal, and Acacia Siebteriana were analyzed by FTIR and thermogravimetric analysis, and a desorption study was also conducted. The analysis by infrared spectroscopy indicates the existence of oligomers of different types all giving 5-hydroxy-2-hydroxymethylfuran and 2, 5-dihydroxymethylfuran which are then the real hardening molecules. The pyrolysis of these extracts reveals three main regions of mass loss, a first region is located between 25°C and 110°C reflecting the loss of water from the adhesive and the formation More > Graphic Abstract

    Desorption Behavior and Thermogravimetric Analysis of Bio-Hardeners

  • Open Access

    ARTICLE

    Stepwise Pyrolysis by LBCR Downstream to Enhance of Gasoline Fraction of Liquid Fuel from MMSW

    Indra Mamad Gandidi1,2,*, Edy Suryadi3, Efri Mardawati3, Dwi Rustam Kendarto3, Nugroho Agung Pambudi4,*

    Energy Engineering, Vol.119, No.3, pp. 1169-1178, 2022, DOI:10.32604/ee.2022.018821 - 31 March 2022

    Abstract Pyrolysis is one of the thermal cracking methods to convert hydrocarbon to liquid fuel. The quantity and quality of the process are dependent on several condition including temperature, reaction time, catalyst, and the type of reactor. Meanwhile, a gasoline fraction was maximum product to be considered in the pyrolisis process. Therefore, this study aims to increase the gasoline fraction in liquid fuel using stepwise pyrolysis with a long bed catalytic reactor downstream (LBCR). The LBCR downstream was equipped with the top and bottom outlet and the fed source was mixed municipal solid waste (MMSW). The… More >

  • Open Access

    ARTICLE

    Thermogravimetric and Synergy Analysis of the Co-Pyrolysis of Coconut Husk and Laminated Plastic Packaging for Biofuel Production

    Joselito Olalo*

    Energy Engineering, Vol.119, No.2, pp. 555-567, 2022, DOI:10.32604/EE.2022.018864 - 24 January 2022

    Abstract Unlike plastic, biomass can also be converted and produce high quality of biofuel. Co-pyrolysis of coconut husk (CH) and laminated plastic packaging (LPP) were done in this study. Synergy between these two feedstock was calculated by using thermogravimetric (TGA) and derivative thermogravimetry (DTG) analysis. Different activation energies of the reactions in the co-pyrolysis of CH and LPP were evaluated using the Coats-Redfern method. Results showed an activation energy ranging from 8 to 37 kJ/mol in the different percentage composition of the co-pyrolysis. Also, thermal degradation happens in two-stages in the copyrolysis of CH and LPP, More >

  • Open Access

    ARTICLE

    Study on Preparation of Nitrogen-Doped Hierarchically Porous and High-Performance Carbon Materials from Seaweed Biomass

    Kaihan Xie1, Yamin Hu1,*, Stephen Afonaa-Mensah2, Chuan Yuan1, Bin Cao1, Shuang Wang1,*, Qian Wang1

    Journal of Renewable Materials, Vol.10, No.2, pp. 541-560, 2022, DOI:10.32604/jrm.2022.017911 - 30 August 2021

    Abstract Use Enteromorpha clathrate as a carbon and nitrogen precursor could obtain the N-doped porous carbon materials by two-step pyrolysis. In this paper, the exogenous nitrogen (urea, melamine) and activating agents (KOH, ZnCl2) were employed for the production of higher-performance carbon materials from seaweed biomass. SEM, BET, FTIR, XRD, XPS, Raman and ultimate analyses were carried out to investigate the morpho-structural and elemental peculiarities of the carbonaceous materials. Moreover, cyclic voltammetry (CV) , galvanostatic charge-discharge (GCD) and cyclic charge-discharge tests were carried out to examine the electrochemical properties of the samples. The results showed that electrochemical performance of… More > Graphic Abstract

    Study on Preparation of Nitrogen-Doped Hierarchically Porous and High-Performance Carbon Materials from Seaweed Biomass

  • Open Access

    ARTICLE

    Slow Pyrolysis of Sugarcane Bagasse for the Production of Char and the Potential of Its By-Product for Wood Protection

    Febrina Dellarose Boer1,2,3, Jérémy Valette1,2, Jean-Michel Commandré1,2, Mériem Fournier3,4, Marie-France Thévenon1,2,*

    Journal of Renewable Materials, Vol.9, No.1, pp. 97-117, 2021, DOI:10.32604/jrm.2021.013147 - 30 November 2020

    Abstract Sugarcane bagasse was pyrolyzed using a laboratory fixed bed reactor to produce char and its by-product (pyrolysis liquid). The pyrolysis experiments were carried out using different temperatures (400°C and 500°C), heating rate (1 °C/min and 10 °C/min), and holding time (30 min and 60 min). Char was characterized according to its thermal properties, while the pyrolysis liquid was tested for its anti-fungal and anti-termite activities. Pyrolysis temperature and heating rate had a significant influence on the char properties and the yield of char and pyrolysis liquid, where a high-quality char and high yield of pyrolysis… More >

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