Joselito Olalo^*

Energy Engineering, Vol.119, No.2, pp. 555-567, 2022, DOI:10.32604/EE.2022.018864

Abstract Unlike plastic, biomass can also be converted and produce high quality of biofuel. Co-pyrolysis of coconut husk (CH) and laminated plastic packaging (LPP) were done in this study. Synergy between these two feedstock was calculated by using thermogravimetric (TGA) and derivative thermogravimetry (DTG) analysis. Different activation energies of the reactions in the co-pyrolysis of CH and LPP were evaluated using the Coats-Redfern method. Results showed an activation energy ranging from 8 to 37 kJ/mol in the different percentage composition of the co-pyrolysis. Also, thermal degradation happens in two-stages in the copyrolysis of CH and LPP, in which CH degrades at… More >

Kaihan Xie¹, Yamin Hu^1,*, Stephen Afonaa-Mensah², Chuan Yuan¹, Bin Cao¹, Shuang Wang^1,*, Qian Wang¹

Journal of Renewable Materials, Vol.10, No.2, pp. 541-560, 2022, DOI:10.32604/jrm.2022.017911

Abstract Use Enteromorpha clathrate as a carbon and nitrogen precursor could obtain the N-doped porous carbon materials by two-step pyrolysis. In this paper, the exogenous nitrogen (urea, melamine) and activating agents (KOH, ZnCl₂) were employed for the production of higher-performance carbon materials from seaweed biomass. SEM, BET, FTIR, XRD, XPS, Raman and ultimate analyses were carried out to investigate the morpho-structural and elemental peculiarities of the carbonaceous materials. Moreover, cyclic voltammetry (CV) , galvanostatic charge-discharge (GCD) and cyclic charge-discharge tests were carried out to examine the electrochemical properties of the samples. The results showed that electrochemical performance of the carbonaceous materials… More > Graphic Abstract

Febrina Dellarose Boer^1,2,3, Jérémy Valette^1,2, Jean-Michel Commandré^1,2, Mériem Fournier^3,4, Marie-France Thévenon^1,2,*

Journal of Renewable Materials, Vol.9, No.1, pp. 97-117, 2021, DOI:10.32604/jrm.2021.013147

Abstract Sugarcane bagasse was pyrolyzed using a laboratory fixed bed reactor to produce char and its by-product (pyrolysis liquid). The pyrolysis experiments were carried out using different temperatures (400°C and 500°C), heating rate (1 °C/min and 10 °C/min), and holding time (30 min and 60 min). Char was characterized according to its thermal properties, while the pyrolysis liquid was tested for its anti-fungal and anti-termite activities. Pyrolysis temperature and heating rate had a significant influence on the char properties and the yield of char and pyrolysis liquid, where a high-quality char and high yield of pyrolysis liquid can be obtained at… More >

Qin Liu^*, Ruliang Zhang

Energy Engineering, Vol.117, No.2, pp. 89-98, 2020, DOI:10.32604/EE.2020.010373

Abstract With the development of urbanization in China, the problem of garbage disposal has become increasingly serious. Among the existing waste treatment technologies, pyrolysis is an emerging treatment technology, which has obvious advantages in terms of reduction and secondary pollution. It has good development prospects. This article first compares the advantages and disadvantages of various existing waste treatment technologies, and proposes an organization method that combines thermogravimetric analysis, kinetic analysis, tube furnace experiments, and domestic waste pyrolysis and low-calorie heat the decomposed gases burn together. Urban garbage is one of the main pollution sources of modern urban environmental pollution in the… More >

Ning Li^1,2, Weiming Yi^1,2, Zhihe Li^1,2,*, Lihong Wang^1,2, Yongjun Li^1,2, Xueyuan Bai^1,2, Mei Jiang^1,2

Journal of Renewable Materials, Vol.8, No.3, pp. 329-346, 2020, DOI:10.32604/jrm.2020.08618

Abstract Bio-oil production via pyrolysis is one of promising technologies for renewable energy production from bio-wastes. However, the complicated biooil is still a challenge for high-valued application and during biomass pyrolysis, the emission of non-cleaned aerosol, the potential emission, namely carbonaceous aerosol (CA) increased the difficulty of the commercial promotion. In this study, Rice husk pyrolysis was performed in a semi-continuous fluidized bed reactor coupled with fractional condensers. The effects of pyrolysis and condensation temperature on the properties of bio-oil and emission of CA were investigated systemically. Results indicated that the in-situ separation of vapors was accomplished via condensers of different… More >

Weiwei Lu^1,*, Yirui Zhang¹, Yixian Yao¹, Yuying Wu¹, Han Y. H. Chen², Hailin Zhang³, Jia Yu⁴, Caiqin Shen⁵, Qi Liu⁶, Honghua Ruan^1,*

Phyton-International Journal of Experimental Botany, Vol.89, No.1, pp. 13-26, 2020, DOI:10.32604/phyton.2020.09125

Abstract The priming effect (PE) induced by biochar provides a basis for evaluating its carbon (C) sequestration potential in soils. A 60 days’ laboratory incubation was conducted, which involved the amendment of biochar (1% of soil mass) produced from rice straw at 300ºC (B300) and 500ºC (B500) to young (Y) and old (O) poplar plantation soils, with the aim of studying the responses of biochar-induced PEs to poplar plantation ages. This incubation included six treatments: Y + CK (control), Y + B300, Y + B500, O + CK, O + B300, and O + B500. Carbon dioxide (CO₂) emissions were significantly… More >

Mehul Barde^1,2, Yusuf Celikbag³, Brian Via³, Sushil Adhikari⁴, Maria L. Auad^1,2,*

Journal of Renewable Materials, Vol.6, No.7, pp. 724-736, 2018, DOI:10.32604/JRM.2018.00116

Abstract Bio-based phenol-formaldehyde polymer (BioNovolac) was developed by reacting molar excess of bio-oil/phenol with formaldehyde in acidic medium. Glycidyl 3,5-diglycidoxybenzoate (GDGB), was prepared by direct glycidylation of α-resorcylic acid (RA), a naturally occurring phenolic monomer. GDGB was crosslinked in the presence of BioNovolac by anionic polymerization. Fourier transform infrared spectroscopy (FTIR) confirmed the formation of semi-interpenetrating polymer networks. The glass transition temperature and moduli of bio-based crosslinked systems were observed to increase with increasing GDGB content. Active chain density and mass retention measured by dynamic mechanical analysis (DMA) and Soxhlet extraction, respectively, indicated a high crosslink density of the cured networks.… More >

Shadia J Ikhmayies¹, Naseem M. Abu El-Haija², Riyad N. Ahmad-Bitar³

FDMP-Fluid Dynamics & Materials Processing, Vol.6, No.2, pp. 219-232, 2010, DOI:10.3970/fdmp.2010.006.219

Abstract Large area and highly uniform polycrystalline ZnO thin films have been produced by a spray pyrolysis (SP) technique resorting to a customized system (spraying) on glass substrates at temperature Ts= 450℃. This study deals with the related investigation about the influence of heat treatment (in nitrogen atmosphere) on the resulting properties (electrical, optical and structural) of such films. Properties are analyzed by means of I-V plots, transmittance curves, X-Ray diffractograms (XRD) and scanning electron microscope (SEM) micrographs. Results show that the resistivity of the films decreases from about 200W.cm for the as-deposited films to about 95W.cm for annealed films. XRD… More >

ShadiaJ. Ikhmayies¹, Naseem M. Abu El-Haija¹, Riyad N. Ahmad-Bitar¹

FDMP-Fluid Dynamics & Materials Processing, Vol.6, No.2, pp. 165-178, 2010, DOI:10.3970/fdmp.2010.006.165

Abstract Undoped polycrystalline ZnO thin films were produced on glass substrates at a substrate temperature Ts= 450 C by the spray pyrolysis (SP) technique. The films were characterized by analyzing their I-V curves, transmittance, X-ray diffractograms (XRD) and their scanning electron microscope (SEM) images. The I-V plots are all linear and the resistivity was found to be about 200W.cm. The transmittance in the visible and near infrared regions is as high as 85% which is suitable for solar cell applications. The absorption coefficient which is deduced from the transmittance measurements is continuously increasing with the photon's energy and it rapidly increases… More >

Weijie Li¹, Haiming Huang^1,2, Bangcheng Ai³, Ye Tian¹

CMC-Computers, Materials & Continua, Vol.43, No.3, pp. 175-196, 2014, DOI:10.3970/cmc.2014.043.175

Abstract Physical and mathematical models are the key to analyze thermal behavior of charring materials in the thermal protection system of reentry vehicles subjected to aerodynamic heating. To explore the thermal behavior of charring ablator, we developed and compared two models (pyrolysis interface model and pyrolysis layer model) with pyrolysis and surface recession. Taking AVCOAT composites as an example, its nonlinear thermal behavior, which are caused by temperature dependent thermal properties, moving interfaces and moving boundary, were simulated using the calculation codes written respectively on the basis of the pyrolysis layer model and the pyrolysis interface model. Numerical results indicate that… More >