A. A. Mansour^a, H. A. Salman^b, S. A. Abdul Wahab^c, N. F. Habubi^c, S. S. Chiad^d,*, Z. S. A. Mosa^c, Y. H. Kadhim^d

Chalcogenide Letters, Vol.21, No.3, pp. 275-284, 2024, DOI:10.15251/CL.2024.213.275

Abstract To grow SnS films, the spray pyrolysis deposition (SPD) process is applied. The films were deposited at various substrate temperatures (S_T) of 400, 450, and 500 degrees Celsius for two hours. Through XRD analysis, the impact of ST on the structure was investigated. Peak (113) crystallite sizes were 13.16, 21.48, and 38.87 nm, respectively, at base temperatures of (400, 450, and 500) ℃. The effect of ST on the structure was examined using XRD analysis. A predominat Peak at (113) plane. The crystallite sizes at base temperatures of (400, 450, and 500) ℃ were 13.16, 21.48, More >

W. H. Albanda^a, M. H. Saeed^a, M. Z. Abdullah^b, M. H. Al-Timimi^c,*

Chalcogenide Letters, Vol.21, No.5, pp. 439-447, 2024, DOI:10.15251/CL.2024.215.439

Abstract In this study, CdS: MgO films were synthesized using the chemical spray pyrolysis method, varying the film thickness. X-ray diffraction (XRD) analysis confirmed the polycrystalline nature of the films, with an observed increase in average crystallite size corresponding to thicker films, and The films' surface morphology indicates an absence of crystal defects such as holes and voids . The investigation of energy gap and optical parameters revealed a dependency on film thickness, with the energy gap shifting from 2.412 eV for a thickness of 150 nm to 2.354 eV for a thickness of 750 nm. More >

M. Sudha^a,*, A. B. Madhan^b, M. Revathi^c, N. Thangaraj^d

Chalcogenide Letters, Vol.21, No.9, pp. 757-764, 2024, DOI:10.15251/CL.2024.219.757

Abstract An inexpensive spray pyrolysis process has been used to create thin layer of tin disulphide. The concentration, flow rate, and nozzle to substrate distance were tuned as deposition parameters to produce high-quality thin films. Temperature is varied in the range 200˚C to 350˚C. Through physical research, properties such as the structural, electrical and optical were examined. The films generated are SnS2 with a hexagonal structure, as revealed by X-ray diffraction. EDAX analysis confirms SnS2 thin films. Scanning electron microscopy indicated uniform stacking and material adherence to the glass substrate. A 2.22 eV straight band gap More >

M. Sudha^a,*, A. B. Madhan^b, M. Revathi^c

Chalcogenide Letters, Vol.21, No.10, pp. 841-845, 2024, DOI:10.15251/CL.2024.2110.841

Abstract Zinc sulfide thin films were prepared using the economical spray pyrolysis process. A thin film of exceptional quality with a temperature difference of 300 °C to 400 °C is produced by optimizing variables such as concentration, flow rate, and nozzle to substrate distance. These films' optical characteristics and structure were examined. The deposited thin films displayed a direct and allowed transition, as indicated by the optical transmittance spectra. XRD analysis confirmed that the deposited thin films were polycrystalline with a cubic phase. This film can be used in solar cell applications since the band gap More >

L. Bouras^a, A. Beggas^a,*, D. Sahnoune^b, M. Ghougali^a, R. Ferhat^a

Chalcogenide Letters, Vol.21, No.11, pp. 917-926, 2024, DOI:10.15251/CL.2024.2111.917

Abstract The present study intends to provide the impact of nitric acid on the structural and optical characteristics of thin films of ZnO. The latter was grown on substrates of glass via spray pyrolysis with 400°C, using Zinc acetate aqueous solution acidified by different amounts of nitric acid to obtain a pH ranging from 6.8 to 2.9. The film properties were analyzed as a function of pH. In the light of the XRD analysis, all the films have a preferential direction along the (002) plane. Depending on pH conditions, the crystal size increased from 32.38 to More >

M. Temiz^a,*, S. Çelik^b

Chalcogenide Letters, Vol.21, No.11, pp. 867-872, 2024, DOI:10.15251/CL.2024.2111.867

Abstract Ternary thin films have garnered significant attention due to their adjustable band gap characteristics, making them suitable for many applications. In this research, we examined the structural and optical characteristics of PbZnS thin films fabricated onto glass substrates employing the spray pyrolysis techniuqe. The films were fabricated at different temperatures ranging from 300 to 400°C. X-ray diffraction (XRD) analysis indicated that all films displayed a cubic structure with a preferred orientation along the (200) plane. From the analysis of XRD peaks, it was observed that the crystal structure initially improved with increasing temperature but then More >

Kristine Meile^1,*, Martins Romanovskis^1,2, Thomas Nicol³, Neil Hindle³, Aivars Zhurinsh¹

Journal of Renewable Materials, Vol.12, No.12, pp. 2135-2152, 2024, DOI:10.32604/jrm.2024.056775 - 20 December 2024

Abstract Fast pyrolysis of pre-treated birch wood in a super-heated steam environment produces a condensate rich in anhydrosugars. With the objective to obtain several product streams from this condensate, the possibility of extracting additional chemical species is explored, thus promoting the development of a pyrolysis-based biorefinery. In this work, the extraction and recovery of pyrolytic phenols from birch wood pyrolysis condensate was studied using ion exchange resins. With an aim to achieve effective phenol recovery, while obtaining high purity levoglucosan, basic ion exchange resins, both in OH⁻ and Cl⁻ form, as well as polystyrene-divinyl resins without functional… More > Graphic Abstract

Indra Mamad Gandidi^1,2,*, Sukarni Sukarni^3,4, Avita Ayu Permanasari³, Purnami Purnami⁵, Tuan Amran Tuan Abdullah⁶, Anwar Johari⁶, Nugroho Agung Pambudi^7,*

Energy Engineering, Vol.121, No.12, pp. 3635-3648, 2024, DOI:10.32604/ee.2024.054943 - 22 November 2024

Abstract The use of catalysts has significantly enhanced the yield and quality of in-situ pyrolysis products. However, there is a lack of understanding regarding pyrolysis approaches that utilize several low-cost natural catalysts (LCC) and their placement within the reactor. Therefore, this study aims to examine the effects of various LCC on the in-situ pyrolysis of spirulina platensis microalgae (SPM) and investigate the impact of different types of catalysts. We employed LCC such as zeolite, dolomite, kaolin, and activated carbon, with both layered and uniformly mixed LCC-SPM placements. Each experiment was conducted at a constant temperature of 500°C… More > Graphic Abstract

Guizhou Liu^1,2, Chunze Yan^1,2,*, Yusheng Shi^1,2

The International Conference on Computational & Experimental Engineering and Sciences, Vol.30, No.4, pp. 1-1, 2024, DOI:10.32604/icces.2024.013340

Abstract High-volume-fraction SiC/Al (HVF-SiC/Al) have a wide range of applications in aerospace, optics, automotive and electronic packaging. However, because the hardness, brittleness and wear resistance increase with the increase in the volume fraction, it is difficult for traditional methods such as machining, to process HVF-SiC/Al composites to complex components. Therefore, in this paper, a novel method of the hybrid additive manufacturing is proposed to fabricate HVF-SiC/Al parts with complex structures. The effect of polymer infiltration and pyrolysis (PIP) on microstructure and properties of HVF-SiC/Al composites is investigated. The results show that the mechanical properties of the… More >

Apip Amrullah¹, Widya Fatriasari², Novia Amalia Sholeha³, Edy Hartulistiyoso⁴, Obie Farobie^4,*

Journal of Renewable Materials, Vol.12, No.6, pp. 1087-1102, 2024, DOI:10.32604/jrm.2024.050201 - 02 August 2024

Abstract The escalating demand for energy coupled with environmental concerns necessitates exploring sustainable alternatives to fossil fuels. The study explores the viability of using large ocean-based seaweeds as a source of third-generation biomass, specifically focusing on their conversion to biofuel via the process of pyrolysis. Sargassum plagiophyllum and Ulva lactuca represent prevalent forms of macroalgae, posing significant discharge challenges for coastal regions globally. However, the exploration of their potential for bio-oil generation via pyrolysis remains limited. This study investigates the pyrolysis process of S. plagiophyllum and U. lactuca for biofuel production, aiming to provide valuable insights into their utilization and… More > Graphic Abstract