Marion Thébault¹, Ya Li¹, Christopher Beuc¹, Stephan Frömel-Frybort^1,2, Edith-Martha Zikulnig-Rusch¹, Larysa Kutuzova³, Andreas Kandelbauer^3,*

Journal of Renewable Materials, Vol.8, No.10, pp. 1181-1198, 2020, DOI:10.32604/jrm.2020.09755 - 31 August 2020

Abstract High Pressure Laminates (HPL) panels consist of stacks of self-gluing paper sheets soaked with phenol-formaldehyde (PF) resins. An important requirement for such PFs is that they must rapidly penetrate and saturate the paper pores. Partially substituting phenol with bio-based phenolic chemicals like lignin changes the physico-chemical properties of the resin and affects its ability to penetrate the paper. In this study, PF formulations containing different proportions of lignosulfonate and kraft lignin were used to prepare paper-based laminates. The penetration of a Kraft paper sheet was characterized by a recently introduced, new device measuring the conductivity… More >

Jinxing Li¹, Jun Zhang^1,*, Yunxia Zhou¹, Zhaoling Zhou¹, Hisham Essawy², Xiaojian Zhou^1,*, Guanben Du¹

Journal of Renewable Materials, Vol.8, No.9, pp. 1019-1032, 2020, DOI:10.32604/jrm.2020.012374 - 03 August 2020

Abstract Simple bio-based abrasive grinding wheel based on thermosetting resin matrix was developed starting with condensed tannin and furfuryl alcohol, which are mainly derived from forest and agricultural products like tree barks, wheat and crops. Fourier transform infrared spectra (FTIR) signified the acidic conditions are quiet efficient for the reaction of furfuryl alcohol, urea and glyoxal all together and the -CH₂-NH- and -CH₂-O-CH(OH)- groups are predominating in cross-linking of the tannin-furfuryl alcohol-urea-glyoxal (TFUG) resin. The strengthening contribution of the tannin was also confirmed by the preservation of its distinct crystallinity using X-ray diffraction (XRD). Differential scanning calorimetry… More >

Jiangbo Li^1,2, Lielin Wang^1,2,*, Hua Xie^1,2, Xiaoyu Li^1,2, Zhiqiang Feng^1,2, Wenxiu Zhang^1,2

Energy Engineering, Vol.117, No.3, pp. 129-142, 2020, DOI:10.32604/EE.2020.010336 - 10 July 2020

Abstract This study introduced a significantly effective approach called the microwave-enhanced Fenton method to degrade spent radioactive cation exchange resin. Compared with the Fenton (99% after 180 min) and photo-Fenton (90% after 198 min) reactions, this unique microwave-enhanced Fenton reaction has the highest degradation rate for spent radioactive cation exchange resin degradation (98.55% after 60 min). Carbon dioxide, sulfate and small molecular compounds were produced in the degradation of cation exchange resin, as determined by XRD and FT-IR. A model for the microwave-enhanced Fenton degradation mechanism of cation exchange resin was constructed. Microwaves were implemented to More >

Xiaofu Wang^1,*, Xiong Zhang¹, Yan He², Chunming Lian³

Journal of Renewable Materials, Vol.8, No.8, pp. 947-968, 2020, DOI:10.32604/jrm.2020.011327 - 10 July 2020

Abstract In order to solve the problem of urban surface runoff, it is necessary to study permeable brick deeply. Tensile test and DMA test were used to study the binder material of permeable brick, and a material with the best mechanical properties was selected as the binder of resin based permeable brick; The permeable brick with single gradation and continuous gradation and porosity of 0.1–0.5 gradient is constructed by 3D modeling method. The particle composition and the seepage simulation results of permeable brick under different design parameters were analyzed; A resin-based permeable brick with micro-pores was… More >

A. A. Mazlan¹, M. T. H. Sultan^1,2,3,*, S. N. A. Safri², N. Saba², A. U. M. Shah², M. Jawaid²

Journal of Renewable Materials, Vol.8, No.7, pp. 833-843, 2020, DOI:10.32604/jrm.2020.08724 - 01 June 2020

Abstract The present paper deals with the effect of loading different pineapple leaf fibre (PALF) length (short, mixed and long fibres) and their reinforcement for the fabrication of vinyl ester (VE) composites. Performance of PALF/VE composites was investigated through three-point bending flexural testing and viscoelastic (dynamic) mechanical properties through dynamic mechanical analysis (DMA). DMA results revealed that the long PALF/VE composites displayed better mechanical, damping factor and dynamic properties as compared to the short and mixed PALF/VE composites. The flexural strength and modulus of long PALF/VE composites were 113.5 MPa and 14.3 GPa, respectively. The storage More >

Marion Thébault¹, Larysa Kutuzova², Sandra Jury¹, Iris Eicher¹, Edith-Martha Zikulnig-Rusch¹, Andreas Kandelbauer^2,*

Journal of Renewable Materials, Vol.8, No.6, pp. 603-630, 2020, DOI:10.32604/jrm.2020.09616 - 12 May 2020

Abstract Here, the effects of substituting portions of fossil-based phenol in phenol formaldehyde resin by renewable lignin from two different sources are investigated using a factorial screening experimental design. Among the resins consumed by the wood-based industry, phenolics are one of the most important types used for impregnation, coating or gluing purposes. They are prepared by condensing phenol with formaldehyde (PF). One major use of PF is as matrix polymer for decorative laminates in exterior cladding and wet-room applications. Important requirements for such PFs are favorable flow properties (low viscosity), rapid curing behavior (high reactivity) and… More >

JIANGBO WANG^*

Journal of Polymer Materials, Vol.36, No.4, pp. 381-389, 2019, DOI:10.32381/JPM.2019.36.04.7

Abstract In this study, a novel flame retardant polyvinylphenylsilsesquioxane (PVP) was added into epoxy resin (EP) to prepare EP/PVP (FREP) composites. The results of cone calorimeter measurement showed that in comparison with virgin EP, the peak heat release rate (PHRR) and total heat release (THR) of FREP were reduced by 27.3% and 10.4%, respectively. Moreover, the thermal degradation behavior of FREP was studied by the Kissinger and Ozawa-Flynn-Wall methods. The results suggested that the addition of PVP greatly enhanced the thermal stability of EP in the final stage, which could be attributed to that the branched More >

JALPA V. CHOPDA, DHARMESH B. SANKHAVARA, JIGNESH P. PATEL, P. H. PARSANIA^*

Journal of Polymer Materials, Vol.36, No.1, pp. 101-109, 2019, DOI:10.32381/JPM.2019.36.01.8

Abstract The epoxy resin (EMBHBC) of (2E,6E)-bis (4-hydroxybenzylidene)-4-methyl cyclohexanone (MBHBC) was synthesized by condensing 0.5 mol MBHBC and 2.5 mol epichlorohydrin in 500 mL isopropyl alcohol as a solvent and 1.0 mol NaOH in 50 mL water as a catalyst at 80°C for 3 h. The structure of EMBHBC was supported by UV-Vis, FTIR, ¹ HNMR and ¹³CNMR spectroscopic techniques. Molecular weights and molecular weight distribution of EMBHBC were determined by gel permeation chromatography. DSC thermogram of EMBHC showed one endothermic transition (95.9°C) and two exothermic transitions (317.7°C and 382.2°C) due to melting and decomposition transitions, respectively. More >

DHARMESH B. SANKHAVARA, JALPA CHOPDA, JIGNESH P. PATEL, P. H. PARSANIA^*

Journal of Polymer Materials, Vol.36, No.1, pp. 13-21, 2019, DOI:10.32381/JPM.2019.36.01.2

Abstract Chalcone based epoxy resin (EBHBC) of (2E, 6E)- bis(4-hydroxybenzylidene) cyclohexanone (BHBC) was synthesized by condensing 0.5 mol BHBC and 2.5 mol epichlorohydrin in 500 mL isopropanol as a solvent and 1.0 mol NaOH in 50 mL water as a catalyst at 80o C. The structure of EBHBC is supported by spectral techniques. Molecular weights and molecular weight distribution of EBHBC were determined by gel permeation chromatography. DSC thermogram of EBHC showed one endothermic transition (146.1°C) and two endothermic transitions (253.52°C and 397.34°C) due to melting, some physical change and decomposition transitions, respectively. EBHBC is thermally More >

Jie Xu^1,3, Jiayao Yang¹, Peng Lin², Xiaohuan Liu^1,*, Jinjie Zhang¹, Shenyuan Fu^1,*, Yuxun Tang^2,*

Journal of Renewable Materials, Vol.7, No.12, pp. 1333-1346, 2019, DOI:10.32604/jrm.2019.07905

Abstract It is essential to design economic and efficient tougheners to prepare high-performance epoxy resin; however, this has remained a huge challenge. Herein, an eco-friendly, low-cost, and facile-fabricated bio-based hyperbranched toughener, carboxylic acid-functionalized tannic acid (CATA), was successfully prepared and applicated to the preparation of solvent-free epoxy resins. The mechanical performance, morphology, structural characterization, and thermal characterization of toughened epoxy resin system were studied. The toughened epoxy resin system with only 1.0wt% CATA reached the highest impact strength, 111% higher than the neat epoxy resin system. Notably, the tensile strength and elongation at break of toughened More >