JIANGBO WANG^*

Journal of Polymer Materials, Vol.36, No.4, pp. 381-389, 2019, DOI:10.32381/JPM.2019.36.04.7

Abstract In this study, a novel flame retardant polyvinylphenylsilsesquioxane (PVP) was added into epoxy resin (EP) to prepare EP/PVP (FREP) composites. The results of cone calorimeter measurement showed that in comparison with virgin EP, the peak heat release rate (PHRR) and total heat release (THR) of FREP were reduced by 27.3% and 10.4%, respectively. Moreover, the thermal degradation behavior of FREP was studied by the Kissinger and Ozawa-Flynn-Wall methods. The results suggested that the addition of PVP greatly enhanced the thermal stability of EP in the final stage, which could be attributed to that the branched More >

JALPA V. CHOPDA, DHARMESH B. SANKHAVARA, JIGNESH P. PATEL, P. H. PARSANIA^*

Journal of Polymer Materials, Vol.36, No.1, pp. 101-109, 2019, DOI:10.32381/JPM.2019.36.01.8

Abstract The epoxy resin (EMBHBC) of (2E,6E)-bis (4-hydroxybenzylidene)-4-methyl cyclohexanone (MBHBC) was synthesized by condensing 0.5 mol MBHBC and 2.5 mol epichlorohydrin in 500 mL isopropyl alcohol as a solvent and 1.0 mol NaOH in 50 mL water as a catalyst at 80°C for 3 h. The structure of EMBHBC was supported by UV-Vis, FTIR, ¹ HNMR and ¹³CNMR spectroscopic techniques. Molecular weights and molecular weight distribution of EMBHBC were determined by gel permeation chromatography. DSC thermogram of EMBHC showed one endothermic transition (95.9°C) and two exothermic transitions (317.7°C and 382.2°C) due to melting and decomposition transitions, respectively. More >

DHARMESH B. SANKHAVARA, JALPA CHOPDA, JIGNESH P. PATEL, P. H. PARSANIA^*

Journal of Polymer Materials, Vol.36, No.1, pp. 13-21, 2019, DOI:10.32381/JPM.2019.36.01.2

Abstract Chalcone based epoxy resin (EBHBC) of (2E, 6E)- bis(4-hydroxybenzylidene) cyclohexanone (BHBC) was synthesized by condensing 0.5 mol BHBC and 2.5 mol epichlorohydrin in 500 mL isopropanol as a solvent and 1.0 mol NaOH in 50 mL water as a catalyst at 80o C. The structure of EBHBC is supported by spectral techniques. Molecular weights and molecular weight distribution of EBHBC were determined by gel permeation chromatography. DSC thermogram of EBHC showed one endothermic transition (146.1°C) and two endothermic transitions (253.52°C and 397.34°C) due to melting, some physical change and decomposition transitions, respectively. EBHBC is thermally More >

Jie Xu^1,3, Jiayao Yang¹, Peng Lin², Xiaohuan Liu^1,*, Jinjie Zhang¹, Shenyuan Fu^1,*, Yuxun Tang^2,*

Journal of Renewable Materials, Vol.7, No.12, pp. 1333-1346, 2019, DOI:10.32604/jrm.2019.07905

Abstract It is essential to design economic and efficient tougheners to prepare high-performance epoxy resin; however, this has remained a huge challenge. Herein, an eco-friendly, low-cost, and facile-fabricated bio-based hyperbranched toughener, carboxylic acid-functionalized tannic acid (CATA), was successfully prepared and applicated to the preparation of solvent-free epoxy resins. The mechanical performance, morphology, structural characterization, and thermal characterization of toughened epoxy resin system were studied. The toughened epoxy resin system with only 1.0wt% CATA reached the highest impact strength, 111% higher than the neat epoxy resin system. Notably, the tensile strength and elongation at break of toughened More >

Mahdi Soltanmohammadi¹, Vahid Monfared^2,*

Sound & Vibration, Vol.53, No.5, pp. 177-198, 2019, DOI:10.32604/sv.2019.05811

Abstract Dry-Type Cast Resin Distribution Transformers (CRT) is the secondgeneration of air-cooled distribution transformers where oil is replaced by resin for electrical insulation. CRT transformers may installed indoor adjacent to or near residential areas since they are clean and safe comparing to the conventional transformers. But, as it is obvious, noise discrepancy is intrinsically accompanied with all types of transformers and is inevitable for CRT transformers too. Minimization of noise level caused by such these transformers has biological and ergonomic importance. As it is known the core of transformers is the main source of the noise… More >

Puyou Jia¹, Fei Song¹, Qiaoguang Li^2,*, Haoyu Xia³, Mei Li^1,*, Xugang Shu², Yonghong Zhou¹

Journal of Renewable Materials, Vol.7, No.7, pp. 601-619, 2019, DOI:10.32604/jrm.2019.07011

Abstract Polymers from renewable resources are receiving tremendous attention due to the increasing concerns on the depletion of fossil oils and deteriorated environments. Cardanol, as an abundant and renewable chemical raw material, has been widely used for the production of renewable polymer materials via converting into various of chemical monomers with active functional groups. This comprehensive review deals with various aspects of cardanol as a starting material the preparing various polymer and polymer composites such as benzoxazine resins, phenolic resin, polyurethanes, epoxy resin, vinyl ester polymers, polyamide and cyanate ester resins. The assessment of the future More >

Emanoele Maria Santos Chiromito¹, Eliane Trovatti², Antonio Jose Felix Carvalho^1,*

Journal of Renewable Materials, Vol.7, No.5, pp. 403-413, 2019, DOI:10.32604/jrm.2019.01846

Abstract Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics, its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character. Here we describe fiberboard composites with high contents of wood pulp or cellulose nanofibrils, and a resin of poly (styrene-methyl-methacrylate-acrylic acid) used as water-based emulsion. Cellulose wood pulp and cellulose nanofibrils were used directly in the form of water suspensions. The method is based on the flocculation of the polymer emulsion followed by agglomeration of a mixture of the polymer emulsion… More >

Qiuren Ou^1,2,*, Peijun Ji², Jun Xiao¹, Ling Wu²

FDMP-Fluid Dynamics & Materials Processing, Vol.15, No.1, pp. 27-37, 2019, DOI:10.32604/fdmp.2019.04787

Abstract The properties of resin transfer molding (RTM) cyanate ester and its T800 grade carbon fiber composites were studied with the rheometer, differential scanning calorimetry (DSC), FT-IR, dynamic mechanical analyzer (DMA), thermal gravimetric analysis (TGA), mechanical property testing, and scanning electron microscopy (SEM). The results showed that the temperature of cyanate ester suitable for RTM process was 70℃. Curing process of the resin was 130℃/2 h+160℃/2 h+200℃/2 h+220℃/4 h. Glass transition temperature and heat decomposition temperature of the cured resin are 289℃ and 415℃, respectively. Mechanical properties of T800/RTM cyanate composites are 13.5% higher than that More >

Edgars Vanags*, Mikelis Kirpluks, Ugis Cabulis and Zuzana Walterova

Journal of Renewable Materials, Vol.6, No.7, pp. 764-771, 2018, DOI:10.7569/JRM.2018.634111

Abstract In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined. More >

Hassen Mohamed Sbihi^1,*, Hamid Shaikh², Lahssen El Blidi², Imed Arbi Nehdi¹, Ubair Abdus Samad², Moufida Romdhani-Younes³, Saud Ibrahim Al-Resayes¹

Journal of Renewable Materials, Vol.6, No.6, pp. 651-661, 2018, DOI:10.7569/JRM.2018.634105

Abstract In this study, different samples of alkyd resins based on Citrullus colocynthis seed oil (CCSO)—which has a high content of linoleic acid—were prepared as a renewable raw material. Short (I), medium (II), and long (III) alkyd resins were synthesized using oil, glycerol, and phthalic anhydride (PA) in different proportions. Prunus mahaleb seed oil (PMSO), which contains conjugated linolenic acid, was blended with CCSO in different proportions to examine the effect of PMSO on the film properties of alkyd resins (IV and V). All synthesized resins were characterized by FTIR and 1H NMR spectroscopic analysis. These More >