Puyou Jia¹, Fei Song¹, Qiaoguang Li^2,*, Haoyu Xia³, Mei Li^1,*, Xugang Shu², Yonghong Zhou¹

Journal of Renewable Materials, Vol.7, No.7, pp. 601-619, 2019, DOI:10.32604/jrm.2019.07011

Abstract Polymers from renewable resources are receiving tremendous attention due to the increasing concerns on the depletion of fossil oils and deteriorated environments. Cardanol, as an abundant and renewable chemical raw material, has been widely used for the production of renewable polymer materials via converting into various of chemical monomers with active functional groups. This comprehensive review deals with various aspects of cardanol as a starting material the preparing various polymer and polymer composites such as benzoxazine resins, phenolic resin, polyurethanes, epoxy resin, vinyl ester polymers, polyamide and cyanate ester resins. The assessment of the future More >

Emanoele Maria Santos Chiromito¹, Eliane Trovatti², Antonio Jose Felix Carvalho^1,*

Journal of Renewable Materials, Vol.7, No.5, pp. 403-413, 2019, DOI:10.32604/jrm.2019.01846

Abstract Despite the great potential of cellulose wood pulp and cellulose nanofibrils as reinforcing filler in thermoplastics, its use is limited due to its tendency to form agglomerates and due to its high hydrophilic character. Here we describe fiberboard composites with high contents of wood pulp or cellulose nanofibrils, and a resin of poly (styrene-methyl-methacrylate-acrylic acid) used as water-based emulsion. Cellulose wood pulp and cellulose nanofibrils were used directly in the form of water suspensions. The method is based on the flocculation of the polymer emulsion followed by agglomeration of a mixture of the polymer emulsion… More >

Qiuren Ou^1,2,*, Peijun Ji², Jun Xiao¹, Ling Wu²

FDMP-Fluid Dynamics & Materials Processing, Vol.15, No.1, pp. 27-37, 2019, DOI:10.32604/fdmp.2019.04787

Abstract The properties of resin transfer molding (RTM) cyanate ester and its T800 grade carbon fiber composites were studied with the rheometer, differential scanning calorimetry (DSC), FT-IR, dynamic mechanical analyzer (DMA), thermal gravimetric analysis (TGA), mechanical property testing, and scanning electron microscopy (SEM). The results showed that the temperature of cyanate ester suitable for RTM process was 70℃. Curing process of the resin was 130℃/2 h+160℃/2 h+200℃/2 h+220℃/4 h. Glass transition temperature and heat decomposition temperature of the cured resin are 289℃ and 415℃, respectively. Mechanical properties of T800/RTM cyanate composites are 13.5% higher than that More >

Edgars Vanags*, Mikelis Kirpluks, Ugis Cabulis and Zuzana Walterova

Journal of Renewable Materials, Vol.6, No.7, pp. 764-771, 2018, DOI:10.7569/JRM.2018.634111

Abstract In this work, free tall oil fatty acids were epoxidized with in-situ generated peroxyacetic acid. Reaction kinetics of epoxidation was investigated by oxirane content and iodine value titrimetric determination, as well as FTIR spectra analysis. A highly functional biobased polyol was synthesized by functionalizing epoxidized tall oil fatty acids with triethanolamine using Montmorillonite K10 as a catalyst. The obtained polyol was analyzed by FTIR and MALDI-TOF MS. The most common chemical and physical characteristics of obtained polyol were determined. More >

Hassen Mohamed Sbihi^1,*, Hamid Shaikh², Lahssen El Blidi², Imed Arbi Nehdi¹, Ubair Abdus Samad², Moufida Romdhani-Younes³, Saud Ibrahim Al-Resayes¹

Journal of Renewable Materials, Vol.6, No.6, pp. 651-661, 2018, DOI:10.7569/JRM.2018.634105

Abstract In this study, different samples of alkyd resins based on Citrullus colocynthis seed oil (CCSO)—which has a high content of linoleic acid—were prepared as a renewable raw material. Short (I), medium (II), and long (III) alkyd resins were synthesized using oil, glycerol, and phthalic anhydride (PA) in different proportions. Prunus mahaleb seed oil (PMSO), which contains conjugated linolenic acid, was blended with CCSO in different proportions to examine the effect of PMSO on the film properties of alkyd resins (IV and V). All synthesized resins were characterized by FTIR and 1H NMR spectroscopic analysis. These More >

Kunal Wazarkar, Anagha Sabnis*

Journal of Renewable Materials, Vol.6, No.4, pp. 438-449, 2018, DOI:10.7569/JRM.2017.634159

Abstract The research work presented in this article deals with the synthesis of cardanol-based polyol and its curing with hexabutoxymethyl melamine (HBMM) for application in coatings. Cardanol-based polyol was prepared via thiol-ene click reaction using thioglycerol. Unsaturation present in the long chain of cardanol was successfully utilized to synthesize polyol via thiol-ene coupling. The reaction was carried out between cardanol and thioglycerol in the presence of Irgacure 184 (photoinitiator) and 1,8-Diazabicyclo[5.4.0]undec-7-ene (catalyst) under UV light for 12 h at 80 °C. After completion of the reaction, one mole of thioglycerol was successfully added across the double More >

M. Asim¹, M. Jawaid^1,2*, M. Nasir³, N. Saba¹

Journal of Renewable Materials, Vol.6, No.4, pp. 383-393, 2018, DOI:10.7569/JRM.2017.634162

Abstract This study deals with the analysis of dynamic mechanical, thermal and flammability properties of treated and untreated pineapple leaf fiber (PALF) and kenaf fiber (KF) phenolic composites. Results indicated that storage modulus was decreased for all composites with increases in temperature and pattern of slopes for all composites, having almost the same values of E' at glass transition temperature (Tg). The peak of the loss modulus of pure phenolic composites was shown to be much less. After the addition of kenaf/PALF, peaks were higher and shifted towards a high temperature. The Tan delta peak height More >

M. Asim¹, M. Jawaid^1,4*, K. Abdan², M.R. Ishak³, O.Y. Alothman^4,5

Journal of Renewable Materials, Vol.6, No.1, pp. 38-46, 2018, DOI:10.7569/JRM.2017.634148

Abstract In this study, pineapple leaf fiber (PALF), kenaf fiber (KF) and PALF/KF/phenolic (PF) composites were fabricated and their mechanical properties were investigated. The mechanical properties (tensile, flexural and impact) of the PALF/KF/PF hybrid composites were investigated and compared with PALF/KF composites. The 3P7K exhibited enhanced tensile strength (46.96 MPa) and modulus (6.84 GPa), flexural strength (84.21 MPa) and modulus (5.81 GPa), and impact strength (5.39 kJ/m2) when compared with the PALF/PF and KF/PF composites. Scanning electron microscopy (SEM) was used to observe the fracture surfaces of the tensile testing samples. The microstructure of the 7P3K More >

F. J. Santiago-Medina¹, A. Pizzi^{1, 2*}, M. C. Basso¹, L. Delmotte³, S. Abdalla²

Journal of Renewable Materials, Vol.5, No.5, pp. 388-399, 2017, DOI:10.7569/JRM.2017.634142

Abstract The reaction of a desulphurized kraft lignin with hexamethylene diamine as a model of a polyamine has been investigated. For this purpose, guaiacol was also used as a lignin model compound and treated under similar conditions. Solid state CP-MAS 13C NMR, FTIR and MALDI-TOF spectroscopy studies revealed that polycondensation compounds leading to resins were obtained by the reaction of the amines with the phenolic and aliphatic hydroxy groups of lignin. Simultaneously a second reaction leading to the formation of ionic bonds between the same groups occurred. These new reactions have been clearly shown to involve More >

Mohamed Ammar¹, Ramzi Khiari^2,3,4*, Mohamed Naceur Belgacem^3,4*, Elimame Elaloui¹

Journal of Renewable Materials, Vol.5, No.2, pp. 116-123, 2017, DOI:10.7569/JRM.2016.634136

Abstract The present study investigated the preparation of biomatrices from Stipa tenacissima L. and its valorization for fiberboard application. Resins were produced by extracting lignin from the Stipa tenacissima L. black liquor by soda process and combining it with glyoxal as crosslinking agent to produce lignin-glyoxal-resin (LGR). The matrix was characterized by several methods, such as FTIR and ATG/ATD, and then mixed with date palm rachis as reinforcing fibers in different proportions of 30 and 50% (w/w with respect to the matrix) to produce biodegradable composite materials. Then, their thermal and mechanical properties were determined, using More >