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  • Open Access

    ARTICLE

    Fabrication of Microspherical Catalyst with Hierarchical Porous Structure from Functional Monomers via Low-Temperature Phase-Separation Photopolymerization

    KEMIN WANG, LIFEI HE

    Journal of Polymer Materials, Vol.36, No.3, pp. 253-260, 2019, DOI:10.32381/JPM.2019.36.03.5

    Abstract This study proposes a simple approach for the fabrication of microspherical catalysts with a hierarchical porous structure. The cross-linked porous microspheres with catalytic ability were prepared directly from small-molecular monomers via low-temperature phase-separation photopolymerization of water/oil suspension. The morphology, pore size, chemical structure, and thermal stability of the obtained porous microspheres were characterized by SEM, Mercury Intrusion Porosimetry, FTIR, and TGA. The porous microspheres directly served as an acid catalyst for the condensation reaction of benzaldehyde and ethylene glycol, which exhibited superior catalytic activity and recyclability. The results indicated that such porous microspheres have great potential in the application of… More >

  • Open Access

    ARTICLE

    Effects of PEG200 on the Properties and Performance of PVDF Membranes in the Separation of MethanolWater Mixtures by Pervaporation

    DIPESHKUMAR D. KACHHADIYA, Z.V.P. MURTHY*

    Journal of Polymer Materials, Vol.38, No.1-2, pp. 49-61, 2021, DOI:10.32381/JPM.2021.38.1-2.5

    Abstract The conventional process for methanol-water separation like distillation consumes about 60 % of total energy. As an alternative, researchers have developed a membrane-based separation process for alcohol-water mixtures separation. However, there is a big challenge for researches to separate alcohol-water aqueous mixtures using a polymeric membrane because of swelling. In the present work, the aim is to separate methanol from water by pervaporation using polymeric membranes made up of polyvinylidenefluroide (PVDF) and polyethylene glycol (PEG200) modified PVDF membranes. The membranes were characterized by thermogravimetry analysis (TGA), field emission scanning electron microscopy (FE-SEM), and Fourier-transform infrared spectroscopy (FTIR). A study on… More >

  • Open Access

    ARTICLE

    Separation Characteristics of Surface Modified Polysulfone Ultrafiltration Membrane using Oxidative Catalytic Polymerization of Aniline

    VRINDA GOEL1, RUCHIKA TANWAR1, AJOY KUMAR SAIKIA2, UTTAM KUMAR MANDAL1,*

    Journal of Polymer Materials, Vol.39, No.3-4, pp. 283-305, 2022, DOI:10.32381/JPM.2022.39.3-4.8

    Abstract The commercially available Polysulfone (PSF) membrane surface was modified by solution polymerization of aniline using different oxidation catalysts i.e., FeCl3, CuCl2, and APS. Modified membranes were then characterized with respect to physio-chemical properties like surface chemistry, porosity, wettability, surface roughness, morphology, etc. It was observed that the hydrophilicity/ wettability of membranes was increased upon surface modification by polyaniline which again depended on the nature of the oxidation catalyst used. Membranes developed using FeCl3 and CuCl2 as oxidants exhibit improved permeation, protein rejection, and antifouling properties, whereas decrement was observed in modified membrane performance using APS as an oxidant. Among all… More >

  • Open Access

    ARTICLE

    VOLUME OF FLUID SIMULATION OF BOILING TWO-PHASE FLOW IN A VAPOR-VENTING MICROCHANNEL

    Chen Fang*, Milnes David, Anita Rogacs, Kenneth Goodson

    Frontiers in Heat and Mass Transfer, Vol.1, No.1, pp. 1-11, 2010, DOI:10.5098/hmt.v1.1.3002

    Abstract Vapor-venting microchannel heat exchangers are promising because they address the problems of high pressure drop, flow instability, and local dryout that are common in conventional two-phase microchannel heat sinks. We present a 3D numerical simulation of the vapor-venting process in a rectangular microchannel bounded on one side by a hydrophobic porous membrane for phase-separation. The simulation is based on the volume of fluid (VOF) method together with models for interphase mass transfer and capillary force. Simulation shows the vapor-venting mechanism can effectively mitigate the vapor accumulation issue, reduce the pressure drop, and suppress the local dry-out in the microchannel. Pressure… More >

  • Open Access

    ARTICLE

    FLOW SEPARATION IN FALLING LIQUID FILMS

    Georg F. Dietze, Reinhold Kneer

    Frontiers in Heat and Mass Transfer, Vol.2, No.3, pp. 1-14, 2011, DOI:10.5098/hmt.v2.3.3001

    Abstract Despite the use of liquid films in a wide variety of technical applications involving heat and mass transfer (e.g. nuclear reactors, cooling towers and gas turbines), where they often play an important role, the underlying momentum and heat transport processes within these thin liquid layers remain to be fully elucidated. In particular, this applies to the influence that surface waves, developing due to the film’s natural instability, exert on the mentioned processes. In this context, it has been suggested by several experimental and numerical observations that momentum and heat transfer in the capillary wave region (which precedes large surface waves)… More >

  • Open Access

    ARTICLE

    Hydrogen Permeation Characteristics of Pd-Cu Membrane in Plasma Membrane Reactor

    Muhd Hadi Iskandar Abd Razak*, Motoki Tsuda, Yukio Hayakawa, Shinji Kambara

    Energy Engineering, Vol.121, No.2, pp. 259-272, 2024, DOI:10.32604/ee.2023.043615

    Abstract Hydrogen is an alternative energy source that has the potential to replace fossil fuels. One of the hydrogen applications is as a material for Polymer Electrolyte Membrane Fuel Cells (PEMFC) in fuel cell vehicles. High-purity hydrogen can be obtained using a hydrogen separation membrane to prevent unwanted contaminants from potentially harming the PEMFC components. In this study, we fabricated a plasma membrane reactor and investigated the permeation performance of a hydrogen separation membrane in a plasma membrane reactor utilizing atmospheric pressure plasma. The result showed the hydrogen permeation rate increasing with time as reactor temperature is increased through joule heating.… More >

  • Open Access

    ARTICLE

    Characterization of Flame Retardancy and Oil-Water Separation Capacity of Superhydrophobic Silylated Melamine Sponges

    Yongchun Liu1,*, Ni Qiao2, Yanli Yang3, Yanchun Li1, Chunxiao He1, Siyang Wang1, Chengcheng Liu1, Ruixia Lei1, Wang Li4, Wenwen Gao4

    FDMP-Fluid Dynamics & Materials Processing, Vol.20, No.2, pp. 383-400, 2024, DOI:10.32604/fdmp.2023.041928

    Abstract A silylated melamine sponge (SMS) was prepared by two simple steps, namely, immersion and dehydration of a melamine sponge coated with methyltrichlorosilane. The silylated structure of SMS was characterized by FT-IR (Fourier-transform infrared) spectroscopy, SEM (Scanning electron microscopy) and in terms of water contact angles. Its oil-water absorption and separation capacities were measured by FT-IR and UV-visible spectrophotometry. The experimental results have shown that oligomeric silanol covalently bonds by Si−N onto the surface of melamine sponge skeletons. SMS has shown superhydrophobicity with a water contact angle exceeding 150° ± 1°, a better separation efficiency with regard to diesel oil (by 99.31% (wt/wt%)… More >

  • Open Access

    ARTICLE

    EXPERIMENTAL AND 3D-CFD STUDY ON OPTIMIZATION OF CONTROL VALVE DIAMETER FOR A CONVERGENT VORTEX TUBE

    Seyed Ehsan Rafiee*, M. M. Sadeghiazad

    Frontiers in Heat and Mass Transfer, Vol.7, pp. 1-15, 2016, DOI:10.5098/hmt.7.13

    Abstract The aim of this investigation is study on separation phenomenon inside a special vortex tube affected by structural and physical factors including; throttle diameter, nozzle number and injection pressure as well as the parametric optimization based on separation efficiency using experimental and 3D-CFD methods. The results show that convergent VT with Dth=5.5mm provides 30.01% and 20.04% higher cooling and heating effectiveness compared to basic model. As another result, the higher injection pressure, the higher cooling effectiveness. The cooling effectiveness improves (16.86%) with increase in slot number up to N=4, then decreases. The maximum disagreement between experimental and predicted values is… More >

  • Open Access

    PROCEEDINGS

    The Mechanical Property of 2D Materials and Potential Application in Gas Separation

    Dong Li1,*, Yonggang Zheng1, Hongwu Zhang1, Hongfei Ye1

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.27, No.2, pp. 1-1, 2023, DOI:10.32604/icces.2023.09714

    Abstract The family of 2D transition-metal oxides and dichalcogenides with 1H phase (1H-MX2) has sparked great interest from the perspective of basic physics and applied science. Interestingly, their performances could be further regulated and improved through strain engineering. Effective regulation is founded on a wellunderstood mechanical performance, however, the large number of 1H-MX2 materials has not yet been revealed. Here, a general theoretical model is constructed based on the molecular mechanics, which provides an effective and rapid analytical algorithm for evaluating the mechanical properties of the entire family of 1H-MX2. The validity of the constructed model is verified by molecular dynamics… More >

  • Open Access

    PROCEEDINGS

    Understanding of Airfoil Characteristics at High Mach-Low Reynolds Numbers

    Zhaolin Chen1,*, Xiaohui Wei1, Tianhang Xiao1, Ning Qin2

    The International Conference on Computational & Experimental Engineering and Sciences, Vol.25, No.2, pp. 1-1, 2023, DOI:10.32604/icces.2023.09976

    Abstract A computational study has been conducted on various airfoils to simulate flows at low Reynolds numbers 17,000 and 21,000 with Mach number changes from 0.25 to 0.85 to provide understanding and guidance for Mars rotory wing designs. The computational fluid dynamics tool used in this study is a Reynolds-averaged Navier–Stokes solver with a transition model (k-ω SST γ-Reθ). The airfoils investigated in this study include NACA airfoils (4, 5, and 6% camber), UltraThin airfoils, and thin cambered plates (3% camber, but various maximum camber locations). Airfoils were examined for lift and drag performance as well as surface pressure and flow… More >

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